• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.6C
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• pp.267-274
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• 2012

The conventional approach to evaluate the contaminant transport in soils adopts the macro-scale implementation while the pore configuration and network is a dominant factor to determine the fate of contaminant. However, the observation of fate and transport at pore scale may not be readily approachable because of the computational expenses to solve Navier-Stokes equation. We herein present the 2D Lattice-Boltzmann method that enables to assess the local fluid velocity and density efficiently for the case of single phase and multi-components. The solute fate spatio-temperal space is explicitly determined by the advection of fluid flow. Two different types of idealized pore space provides the path of fluid. Also, solute transport, the velocity field and average concentration of solute are computed in steady state. Results show that the pore geometry such as tortuosity mainly affect the solute fate. It highlights the significance of the pore configuration and shape in granular soils and rock discontinuity in spite of the equivalent porosity.

• Journal of the Korean GEO-environmental Society
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• v.7 no.3
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• pp.43-54
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• 2006

In this paper, the uniaxial, triaxial compression tests and consolidation tests on the clay sample substituted initial pore water for pollutant were performed to evaluate the change in geotechnical properties of the contaminated clay. The contaminant transport analysis on embankment type landfill using the MT3D model was also performed to evaluate the extent of transport and diffusion. There was tendency that strength, compressibility and permeability has increased with the increase in the concentration of NaCl solution. The increase in the strength and compressibility of sample saturated with leachate was higher than samples saturated with NaCl solution, but in the permeability coefficient was lower. As the result of contaminant transport analysis, the predicted concentration was in high with the increase in the initial concentration of $Cl^-$ ion and increased in a non-linear form. The transportation distance calculated with use of regression equation between the distance from contaminant source and the concentration of $Cl^-$ ion was increased with the increase in the initial concentration.

• Journal of the Korean Society of Groundwater Environment
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• v.1 no.2
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• pp.105-112
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• 1994

To investigate the migration behavior of contaminants in rocks. adsorption and diffusion experiments for Sr as a sorbing contaminant and for Cr-EDTA as a non-sorbing contaminant were carried out on granitic rocks. The Sr adsorption on separated minerals and crushed rocks tends to slightly increase with increasing pH. It also greatly decreases with the increase of ionic strength in NaCl solution. Among separated minerals, biotite and sericite have adsorbed much more amount of Sr than other rock-forming minerals, such as quartz, plagioclase, and potassic feldspar, because the specific surfaces and cation exchange capacities of phyllosilicates are generally much greater than those of the other rock-forming minerals. The intrinsic diffusion coefficients of Cr-EBTA for granitic rocks differ little from those of Sr. This indicates that they are independent of water-rock interactions. Experimental data show that the intrinsic diffusion coefficients are positively correlated with the porosities of the rocks. They are close to the theoretically predicted values, especially in pre-steady state diffusion region, with the increase of rock sample thickness.

• Journal of Korea Water Resources Association
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• v.37 no.11
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• pp.889-896
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• 2004

The fractal advection-diffusion equation (ADE) is a generalization of the classical AdE in which the second-order derivative is replaced with a fractal order derivative. While the fractal ADE have been analyzed with a stochastic process In the Fourier and Laplace space so far, in this study a fractal ADE for describing solute transport in rivers is derived with a finite difference scheme in the real space. This derivation with a finite difference scheme gives the hint how the fractal derivative order and fractal diffusion coefficient can be estimated physically In contrast to the classical ADE, the fractal ADE is expected to be able to provide solutions that resemble the highly skewed and heavy-tailed time-concentration distribution curves of contaminant plumes observed in rivers.

• Journal of Korea Water Resources Association
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• v.45 no.2
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• pp.179-189
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• 2012

To simulate the transport of pollutant, a numeric model for the advection-diffusion equation with the decay term is developed. This is finite-difference model using the implicit method (with the weight factor ${\alpha}$) and Gauss-Seidel SOR(successive over-relaxation). This model is compared to the analytical solutions (of simpler dimensional or boundary conditions), and in the condition of Peclet number < 5~20, the result shows stable condition, and Crank-Nicolson method (${\alpha}$=0.5) shows the more accurate results than fully-implicit method (${\alpha}$=1). The mass of advection, diffusion and decay is calculated and the error of mass balance is less than 3%. This model can evaluate the 3-D concentrations of the advection-diffusion and decay problems, but this model uses only the finite-difference method with the fixd grid system, so it can be effectively used in the problems with small Peclet numbers like the pollutant transport in groundwater.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.6
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• pp.658-665
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• 1998

This paper investigates local exhaust effectiveness in a room with a supply and an exhaust slots on the ceiling. The mean age of air is an indicator of supply effectiveness, while the mean residual life time can be used as an indicator of exhaust effectiveness. The distribution of local mean residual life time in a space is calculated by four different numerical procedures. The reverse-flow calculation method has been proved to show quite accurate results while it can save considerable amount of computation time and efforts, compared to the method by its original definition. It is concluded that the diffusion term in the equation of mean residual life time can be neglected. The spatial and temporal diffusion characteristics of the contaminant are also discussed.

• Journal of the Korean Geotechnical Society
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• v.24 no.6
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• pp.17-25
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• 2008

Permeable reactive barriers (PRBs) technology can be applied to contaminated groundwater remediation. It is necessary to select adequate reactive material according to contaminant characterization. In groundwater. In this research, the reaction between reactive material and heavy metal contaminants was estimated through batch test. Reactive material was slag, which has been produced in Gwangyang power plant, and heavy metal contaminants were cadmium, lead and copper. Batch test consisted of two testes: 1) sorption equilibrium test and 2) sorption kinetic test. Sorption equilibrium test was performed for estimating slag sorption capacity against contaminants. And sorption kinetic test was performed for slag sorption rate with contaminants species, contaminants initial concentration and sulfate. Sorption capacity and sorption rate were affected by contaminant species. Sorption rate increased with increasing initial concentration in lead and copper but decreased with increasing initial concentration in cadmium. Sorption rate increased in existing sulfate. In low concentration, film diffusion was domain mechanism, and in high concentration, particle diffusion was domain mechanism.

• Membrane and Water Treatment
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• v.2 no.4
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• pp.239-250
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• 2011

A photovoltaic powered ultrafiltration and reverse osmosis system was tested with a number of natural groundwaters in Australia. The objective of this study was to compare system performance at six remote field locations by assessing the impact of water composition and fluctuating energy on inorganic contaminant removal using a BW30-4040 membrane. Solar irradiance directly affected pressure and flow. Groundwater characteristics (including TDS, salts, heavy metals, and pH), impacted other performance parameters such as retention, specific energy consumption and flux. During continual system operation, retention of ions such as $Ca^{2+}$ and $Mg^{2+}$ was high (> 95%) with each groundwater which can be attributed to steric exclusion. The retention of smaller ions such as $NO_3{^-}$ was affected by weather conditions and groundwater composition, as convection/diffusion dominate retention. When solar irradiance was insufficient or fluctuations too great for system operation, performance deteriorated and retention dropped significantly (< 30% at Ti Tree). Groundwater pH affected flux and retention of smaller ions ($NO_3{^-}$ and $F^-$) because charge repulsion increases with pH. The results highlight variations in system performance (ion retention, flux, specific energy consumption) with real solar irradiance, groundwater composition, and pH conditions.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.5
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• pp.282-287
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• 2017

The purpose of this study was predicted the effects of mixing and diffusion due to the operation of the apparatus before the development of the mixed diffusion device for the decontamination absorbent to minimize the influence of contaminant inflow due to radiation accident. The tracer used for the flow characteristics was $^{68}Ga$, $^{99m}Tc$, which is a radioactive isotope, and 2 inch NaI radiation detector was used to detect it. The impeller of the decontamination mixed diffusion system applied to this study was made into three types and the mixing diffusion effect was compared. As a result of analyzing the flow characteristics of the radio-isotope with decontamination mixed diffusion device, mixing, diffusion and flow pattern were obtained. The radial mixing type impeller was able to diffuse to the water surface by the upflow flow, and the fin structure was adjusted for finding optimal conditions. The model 3 type consists of a fin guiding part and an auxiliary fin so that the diffusion speed is higher than that of other types of impellers. It also showed a short time to reach complete mixing.

• Journal of the Korean Society of Safety
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• v.14 no.2
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• pp.109-115
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• 1999

The release of gas from the LPG storage tank by the rupture or leakage can occure explosion and this causes serious damage to people and structures. In this study, the explosion effect and damaging distance were measured for the LPG cloud explosion to perform the quantitative risk assessment for the PSM, and the effective parameters on the explosion were found. The gas dispersion and mass contaminant in the explosion limits were calculated by using DEGADIS, and it was converted to TNT equivalency and damaging distance. As a result, the wind speed was the most effective parameter on the diffusion rate and TNT equivalency, and the damaging distance were increased with decrease of wind speed and surface roughness.