• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.4
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• pp.440-448
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• 1998

This paper considers the influence of circumferential wall heat conduction for the case of forced convection around a circular cylinder in cross flow of air. Keeping uniform heat generation from the inner surface of the cylinder in radial direction, heat is transferred by wall conduction in the circumferential direction due to the asymmetric nature of the temperature distribution of the cylinder and by convection around the perimeter of the cylinder. The wall conduction depends on conductivity of the cylinder and size of the cylinder radius and thickness and affects the local convective heat transfer rate significantly for geometrically similar surfaces and flow conditions. A nondimensional conjugation parameter K. (=k$_t$R/k$_w$b) has been used to characterize the effect of the circumferntial wall heat conduction. The small values of conjugation parameter K are found to be associated with large effect of wall conduction on the local convective heat transfer rate.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.10 no.5
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• pp.523-534
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• 1998

The convection heat transfer on horizontal circular tube is studied as a conjugated heat transfer problem. With uniform heat generation in a cylindrical heater placed in a cross flow boundary condition, heat flow that is conducted along the wall of the heater creates a non-isothermal surface temperature and non-uniform heat flux distribution. In the present investigation, the effects of circumferential wall heat conduction on convection heat transfer are investigated for the case of forced convection around horizontal circular tube in cross flow of air and water. Non-dimensional conjugation parameter $ K^*$ which can be deduced from the governing energy differential equation should be used to express the effect of circumferential wall heat conduction. Two-dimensional temperature distribution$ T({\gamma,\theta})$ is presented. The influence of circumferential wall heat conduction is demonstrated on graph of local Nusselt number.

• Journal of the Korean Chemical Society
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• v.37 no.12
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• pp.1047-1052
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• 1993

The electronic spectra of enzyme-model organocobalt(Ⅲ) complexes containing completely or partially conjugated macrocyclic ligands were measured in various solvents to investigate the solvent effect on the charge transfer band for the axial cobalt-carbon bond by the extent of conjugation in the equatorial macrocyclic ring; completely conjugated, $CH_3CoL,\;C_6H_5CoL,\;CNCoL,\;CH_3CoL',\;CNCoL'$, partially conjugated $CH_3(py)Co(DH)_2, CH_3CoL＂$, unconjugated dienes, $[CH_3Co(1,4-CT)](ClO_4)_2$, and open ring, $CH_3Co(salen)$. The position of the charge transfer band which corresponds to the cobalt-carbon bond was shifted to a shorter wavelength as the polarity of solvent increased and the transition energy $(E_T)$ had a linear relationship with solvent polarity parameter, Z-value, only in the case of completely conjugated system. However, the linear correlation between $E_T$and Z was not observed for partially conjugated and open ring systems.