• Title/Summary/Keyword: Conjugation length

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Isolation and Characterization of a Theta Glutathione S-transferase Gene from Panax ginseng Meyer

  • Kim, Yu-Jin;Lee, Ok-Ran;Lee, Sung-Young;Kim, Kyung-Tack;Yang, Deok-Chun
    • Journal of Ginseng Research
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    • v.36 no.4
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    • pp.449-460
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    • 2012
  • Plants have versatile detoxification systems to encounter the phytotoxicity of the wide range of natural and synthetic compounds present in the environment. Glutathione S-transferase (GST) is an enzyme that detoxifies natural and exogenous toxic compounds by conjugation with glutathione (GSH). Recently, several roles of GST giving stress tolerance in plants have demonstrated, but little is known about the role of ginseng GSTs. Therefore, this work aimed to provide further information on the GST gene present in Panax ginseng genome as well as its expression and function. A GST cDNA (PgGST) was isolated from P. ginseng cDNA library, and it showed the amino acid sequence similarity with theta type of GSTs. PgGST in ginseng plant was induced by exposure to metals, plant hormone, heavy metals, and high light irradiance. To improve the resistance against environmental stresses, full-length cDNA of PgGST was introduced into Nicotiana tabacum. Overexpression of PgGST led to twofold increase in GST-specific activity compared to the non-transgenic plants, and the GST overexpressed plant showed resistance against herbicide phosphinothricin. The results suggested that the PgGST isolated from ginseng might have a role in the protection mechanism against toxic materials such as heavy metals and herbicides.

Synthesis and Photovoltaic Properties of Polymers Based on Cyclopentadithiophene and Benzimidazole Units

  • Song, Su-Hee;Park, Sei-Jung;Kwon, Soon-Cheol;Shim, Joo-Young;Jin, Young-Eup;Park, Sung-Heum;Kim, Il;Lee, Kwang-Hee;Suh, Hong-Suk
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1861-1866
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    • 2012
  • The new semiconducting copolymers with 4,4-dialkyl-$4H$-cyclopenta[2,1-$b$:3,4-$b^{\prime}$]dithiophene and 2,2-dimethyl-$2H$-benzimidazole units were synthesized. The fused aromatic rings, such as cyclopentadithiophene (CPDT) unit, can make the polymer backbone more rigid and coplanar, which induces long conjugation length, narrow band gap, and strong intermolecular ${\pi}-{\pi}$ interaction. The stacking ability was controlled through attaching of linear or branched alkyl side chains. The spectra of PEHCPDTMBI and PHCPDTMBI in the solid films show absorption bands with maximum peaks at 401, 759 and 407, 768 nm, and the absorption onsets at 925 and 954 nm, corresponding to band gaps of 1.34 and 1.30 eV, respectively. The devices comprising PHCPDTMBI with $TiO_X$ showed a $V_{OC}$ of 0.39 V, a $J_{SC}$ of 1.14 $mA/cm^2$, and a $FF$ of 0.34, giving a power conversion efficiency of 0.15%. The PHCPDTMBI with linear alkyl chain on CPDT shows good solubility in organic solvent with higher PCE value than that of PEHCPDTMBI.

Optical Properties of Proton-irradiated Polyacrylonitrile Film (양성자 조사된 폴리아크릴로니트릴 필름의 광학적 특성)

  • Lee, Hwa-Su;Baek, Ga-Young;Jung, Jin-Mook;Hwang, In-Tae;Jung, Chan-Hee;Shin, Junhwa;Choi, Jae-Hak
    • Journal of Radiation Industry
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    • v.10 no.1
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    • pp.1-5
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    • 2016
  • In this study, the effect of high-energy proton irradiation on the optical properties of polyacrylonitrile (PAN) films was investigated. PAN thin films spin-coated on a substrate were irradiated 150 keV proton ions at various fluences. The changes in the chemical structure and optical properties were investigated by FT-IR and UV-vis spectroscopy. The results of the FT-IR analysis revealed that the cyclization reaction took place by proton irradiation and the degree of cyclization increased with an increasing fluence. Based on the UV-vis analysis, the optical band gap of PAN decreased from 2.84 to 2.52 eV with an increasing fluence due to the formation of carbon clusters by proton irradiation. In addition, the number of carbon atoms per carbon cluster and the number of carbon atoms per conjugation length were found to be increased with an increasing fluence.

Compensation for the Distorted WDM Signals through Dispersion Map of Trapezoid-Based Symmetry Configuration Combined with MSSI (MSSI와 결합된 사다리꼴 기반 대칭 구조의 분산 맵을 통한 WDM 신호의 왜곡 보상)

  • Seong-Real Lee
    • Journal of Advanced Navigation Technology
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    • v.28 no.4
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    • pp.552-558
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    • 2024
  • In dispersion management, which involves additionally inserting a dispersion compensation fiber of an appropriate length to eliminate or reduce the chromatic dispersion of a single-mode fiber, determining the form of the dispersion map, which is the cumulative dispersion profile according to the transmission distance, is the most basic and important. In this paper, the various symmetric dispersion map based on trapezoids applied to dispersion-managed links combined with mid-span spectral inversion (MSSI), which compensates for the distortion caused by Kerr nonlinear effects through optical phase conjugation in the middle of the entire transmission link are proposed, and the effect of each dispersion map on distortion compensation of wavelength division multiplexed (WDM) signals is analyzed. Although the degree of compensation varies depending on the factors that determine the detailed shape of the proposed trapezoid-shaped dispersion map and RDPS (residual dispersion per span), overall, it was confirmed that distortion compensation for signals with a small extinction ratio was more effective than distortion compensation for WDM channel signals with a large extinction ratio.

Effect of Exogenous Metalaxyl Seed-Soaking on Root Initiation and Elongation of Young Rice Seedling (벼 어린모 뿌리의 분화 및 신장에 미치는 Metalaxyl의 종자침청처리 효과)

  • Kim, Je-Kyu;Park, Kwng-Ho;Lee, Moon-Hee;Oh, Yun-Jin
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.38 no.6
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    • pp.545-553
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    • 1993
  • The metalaxyl seed-soaking treatment markedly increased the root-mat formation of the young rice seedling(8- to l0-day-old) for machine transplanting. This experiment was conducted to find out a possible rooting mechanism of the young rice seedling in relation to the exogenous metalaxyl seed-soaking treatment. The rice seeds of Hwaseongbyeo variety were soaked in the solution of metalaxyl for 24 hours at room temperature. Metalaxyl(25% wettable powder), a fungicide, was used at the concentration of 200ppm as a promoting substance on the root-mat formation of the young rice seedling. Seeding rate of the young rice seedling was 220g per seed tray(30${\times}$60${\times}$depth 3cm). Metalaxyl seed treatment was highly effective in root initiation and elongation of the young rice seedling in terms of root activity, the number and length of root, and amino acid content of roots. The exogenous metalaxyl application would also increase the chlorophyll content and photosynthetic rate in the young rice seedling. Those factors resulted in vigorous root-mat formation of the young rice seedling. In particular, alanine is a lead compound of metalaxyl which biochemically plays an important role in energy intermediate of the rice plant. Alanine conjugation with a glucose (N-${\beta}$-glucoside) is probably the mechanism in enhancement of initiation and elongation of rice roots of young rice seedling.

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