• 제목/요약/키워드: Conductive mechanism

검색결과 108건 처리시간 0.032초

Characterization of TiO2 Nanocrystalline Films for High Performance Dye-Sensitized Solar Cells

  • Jung, Heung-Joe
    • Transactions on Electrical and Electronic Materials
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    • 제12권3호
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    • pp.123-126
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    • 2011
  • Titanium dioxide ($TiO_2$) thin films were deposited by the sol-gel method with a surfactant-assisted mechanism. Its application for dye-sensitized solar cells (DSSCs) was investigated. Brunauer-Emmett-Teller, X-ray diffraction and field emission scanning electron microscopy techniques were used to characterize the surface characteristics of thin films. Photovoltaic-current density measurements were performed to determine the photoelectrochemical properties of the thin films and the performance of DSSCs. Energy conversion efficiency of about 6.1% was achieved for cells with conductive glass under illumination with AM 1.5 (100 $mWcm^{-2}$) simulated sunlight. Investigation showed higher photo-energy conversion efficiency for mesoporous $TiO_2$ nanocrystalline films used in DSSCs relative to commercially available Degussa P25 films.

SiInZnO/Ag/SiInZnO 다층박막의 Ag 형성 메카니즘에 따른 광학적 특성 변화 (Effect of Ag Formation Mechanism on the Change of Optical Properties of SiInZnO/Ag/SiInZnO Multilayer Thin Films)

  • 이영선;이상렬
    • 한국전기전자재료학회논문지
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    • 제26권5호
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    • pp.347-350
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    • 2013
  • By inserting a very thin metal layer of Ag between two outer oxide layers of amorphous silicon indium zinc oxide (SIZO), we fabricated a highly transparent SIZO/Ag/SIZO multilayer on a glass substrate. In order to find the optimized thickness of Ag layers, we investigated the variation of optical properties depending on Ag thickness. It was found that the transition of Ag layer from island formation to a continuous film occurred at a critical thickness. Continuity of the Ag film is very important for optical properties in SIZO/Ag/SIZO multilayer. With about 15 nm thick Ag layer, the multilayer showed a high optical transmittance of 80% at 550 nm and low emissivity in IR.

인발다이 가공을 위한 니들 호닝기용 툴혼 설계 (Design of The Tool Horn for Dies Needle Horning Manufacturing)

  • 윤형준;윤영식
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.231-232
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    • 2006
  • Ultrasonic machining technology has been developed over recent years for manufacturing the quality-assured precision parts fur several industrial application such as optics, semiconductors, aerospace and automobile application. Ultrasonic needle horning is widely used in cutting(drilling) of non-conductive, brittle workpiece materials. This paper intends to understanding of the basic mechanism of ultrasonic needle horning. And frequency analysis program is used to easily predict the natural frequency of ultrasonic vibration cutting tools.

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Electrochemical Study of Poly(aniline N-alkylsulfonate)s

  • Kim, Eunkyoung;Rhee, Suh Bong
    • 분석과학
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    • 제8권4호
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    • pp.631-636
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    • 1995
  • Electrochemical properties of self-dopable poly(aniline N-butylsulfonate)s in various acidic medium were investigated by spectroelectrochemical techniques. Cyclic voltammetric study showed more than two reversible process of one electron transfer, the potential and peak intensity of which were dependent on the acid concentration and dopant ion. Spectroscopic study at different oxidation level indicated that the electrochromic switching of the poly(aniline N-alkylsulfonate)s film involves structural changes from benzenoid ring to quinoid ring. Spectrocyclic voltammetry together with impedance spectra of the PANBUS film in 0.1 M $LiClO_4$ solution of acetonitrile containing 0.46 M of perchloric acid showed two types of highly conductive states at the intermediate oxidation levels, which can be related to the metallic polaron states doped by two different process.

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A Review of Wet Chemical Etching of Glasses in Hydrofluoric Acid based Solution for Thin Film Silicon Solar Cell Application

  • Park, Hyeongsik;Cho, Jae Hyun;Jung, Jun Hee;Duy, Pham Phong;Le, Anh Huy Tuan;Yi, Junsin
    • Current Photovoltaic Research
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    • 제5권3호
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    • pp.75-82
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    • 2017
  • High efficiency thin film solar cells require an absorber layer with high absorption and low defect, a transparent conductive oxide (TCO) film with high transmittance of over 80% and a high conductivity. Furthermore, light can be captured through the glass substrate and sent to the light absorbing layer to improve the efficiency. In this paper, morphology formation on the surface of glass substrate was investigated by using HF, mainly classified as random etching and periodic etching. We discussed about the etch mechanism, etch rate and hard mask materials, and periodic light trapping structure.

SiC-$ZrB_2$계(係) 복합체(複合體)의 전기전도기구(電氣傳導機溝) (Electrical Conduction Mechanism of SiC-$ZrB_2$ Composites)

  • 주진영;권주성;신용덕
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1997년도 하계학술대회 논문집 C
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    • pp.1336-1338
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    • 1997
  • Relations between the composites of SiC-$ZrB_2$ electro-conductive ceramic composites and their electrical resistivity, as well as their temperature, were investigated. The electrical resistivity of hot-pressed composites was measured by the Pauw method in the temperature of RT to $100^{\circ}C$. The electrical resistivity of the composites follow the electrical conduction model for a homogenous mixture of two kinds of particles with different conductivity. Also the electrical resistivity versus temperature curves indicate the formation of local chains of $ZrB_2$ particles. In the case of SiC-$ZrB_2$ composites containing above 30Vol.% $ZrB_2$ showed PTCR, whereas the electrical resistivity of SiC-15Vol.% $ZrB_2$ showed NTCR.

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저온소성 기판과 Cu와의 동시소성에 미치는 CuO의 첨가효과 (The Influence of CuO on Bonding Behaviors of Low-Firing-Substrate and Cu Conductor)

  • 박정현;이상진
    • 한국세라믹학회지
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    • 제31권4호
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    • pp.381-388
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    • 1994
  • A new process which co-fires the low-firing-substrate and copper conductor was studied to achieve good bond strength and low sheet resistance of conductor. Cupric oxide is used as the precursor of conductive material in the new method and the firing atmosphere of the new process is changed sequently in air H2N2. The addition of cupric oxide and variations of firing atmosphere permited complete binder-burnout in comparison with the conventional method and contributed to the improvement of resistance and bonding behaviors. The potimum conditions of this experiment to obtain the satisfactory resistance and bond strength are as follows (binder-burnout temperature in air; 55$0^{\circ}C$, reducing temperature in H2; 40$0^{\circ}C$ for 30 min, ratio of copper and cupric oxide; 60:40~30:70 wt%). The bonding mechanism between the substrate and metal was explained by metal diffusion layer in the interface and the bond strength mainly depended on the stress caused by the difference of shrinkage and thermal expansion coefficient between the substrate and metal.

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코로나 대전된 복합절연재료의 표면상태가 전위감쇠에 미치는 영향 (The Characteristics of Potential Decay on the Corona Electrified Composite Insulating Material by Surface Condition)

  • 황명환;정재희;조한구;송진호;이덕출
    • 한국안전학회지
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    • 제12권2호
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    • pp.65-69
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    • 1997
  • Especially, Fiber glass Reinforced Plastics(FRP) is the best composite insulating material which has been so far. Therefore, it's worthy of notice to investigate on the corona electrified composite insulating material by surface condition. And then some other materials will be focussed on. In this study, charge decay were measured with charging-time and grid voltage on FRP composite material surface in order to analyze the mechanism. As a result we have studied that the way of the composite glass fiber(GF) and Polymer and the condition of the contaminated surface was different. In case of the GF is mixed with vertical, charge decay speed is fast because the charge is easily leaked. On the other hand, the surface charge decay speed is depend on conductive or insulated of the contaminant.

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XPS 분석에 의한 AZO 박막의 전기전도 메커니즘 해석 (Electric conduction mechanism Analysis of AW Thin Films using XPS Measurement)

  • 진은미;김경민;박춘배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.446-447
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    • 2007
  • Aluminisum-doped zinc oxide (AZO) films are attractive materials as transparent conductive electrode because they are inexpensive, nontoxic and abundant element compared with indium tin oxide (ITO). In our paper, AZO films have been deposited on glass (coming 1737) substrates by RF magnetron sputtering. The AZO film was post-annealed at $600^{\circ}C$, $800^{\circ}C$ for 2 hr with $N_2$ atmosphere, respectively. We investigated that the electric properties and qualitative analysis of AZO films, which measured using the methods of Hall effect, X-ray photoelectron spectroscopy (XPS).

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우레아를 이용한 ATO(Antimony doped Tin Oxide)의 특성 연구 (Study of the Feature of Antimony doped Tin Oxide Using Urea)

  • 김진철;안용관;최병현;이미재;백종후;심광보
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.361-362
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    • 2005
  • Antimony doped tin oxide(ATO) nano powders have been synthesized by homogeneous precipitation method using $SnCl_4\cdot5H_2O$ for precursor, $SbCl_3$ as doped material and urea. The hydrolysis of urea and conductive mechanism and Heat treatment was performed at the temperature from $500^{\circ}C$ to $700^{\circ}C$ in air. The ATO nano powders are characterized by means of Thermogravimetry differential thermal analyzer (TG-DTA), X-ray diffraction (XRD), Brunauer, Emmett, and Teller adsorption (BET), Scanning electron microscopy (SEM) ATO nano powders with an average size of nm and the highest surface area 129 $m^2g^{-1}$ are obtained.

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