• Advances in concrete construction
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• v.2 no.2
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• pp.109-123
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• 2014

This paper presents chloride induced corrosion durability of reinforcing steel in geopolymer concretes containing different contents of sodium silicate ($Na_2SiO_3$) and molarities of NaOH solutions. Seven series of mixes are considered in this study. The first series is ordinary Portland cement (OPC) concrete and is considered as the control mix. The rest six series are geopolymer concretes containing 14 and 16 molar NaOH and $Na_2SiO_3$ to NaOH ratios of 2.5, 3.0 and 3.5. In each series three lollypop specimens of 100 mm in diameter and 200 mm in length, each having one 12 mm diameter steel bar are considered for chloride induced corrosion study. The specimens are subjected to cyclic wetting and drying regime for two months. In wet cycle the specimens are immersed in water containing 3.5% (by wt.) NaCl salt for 4 days, while in dry cycle the specimens are placed in open air for three days. The corrosion activity is monitored by measuring the copper/copper sulphate ($Cu/CuSO_4$) half-cell potential according to ASTM C-876. The chloride penetration depth and sorptivity of all seven concretes are also measured. Results show that the geopolymer concretes exhibited better corrosion resistance than OPC concrete. The higher the amount of $Na_2SiO_3$ and higher the concentration of NaOH solutions the better the corrosion resistance of geopolymer concrete is. Similar behaviour is also observed in sorptivity and chloride penetration depth measurements. Generally, the geopolymer concretes exhibited lower sorptivity and chloride penetration depth than that of OPC concrete. Correlation between the sorptivity and the chloride penetration of geopolymer concretes is established. Correlations are also established between 28 days compressive strength and sorptivity and between 28 days compressive strength and chloride penetration of geopolymer concretes.

• Magazine of the Korean Society of Agricultural Engineers
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• v.16 no.3
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• pp.3472-3476
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• 1974

This test was attempted to investigate the effects of some mix designs of concreteon the compressive strengths and corrosive rates when exposed to sea water of the West Sea. In this test, concrete mixes consisted of an ordinary concrete, a pozzolan concrete and concretes with different admixtures such as fly ash, pozzolith and vinsol resin. Compressive strengths of the concrete were measured at ages of 1-year and 2-years when exposed to both sea water and fresh water. Corrosive rate was tested at ages of 1-year and 2-years when exposed to sea water only. The results obtained from the test may be summarized as follows: (1) When all of concretes were exposed to fresh water, compressive strength of an ordinary concrete was the lowest at all mixes of concretes, and all of them showed higher strength as the exposing age is longer. It was evidance that the uses of pozsolan cement, fly ash, pozzolith and vinsol resin in mix design of concrete had an effect on increasing compressive strength and that fresh water also had an effect on curing concretes even though at a long-time age. (2) When concretes were exposed sea water, a concrete with fly ash was the highest in compressive strength and its strength was increasing as the exposing age is longer, but the other concretes were decreased at 2-year exposure. It was found that a concrete with fly ash was the most effective on compressive strength of all concrete, but the other concretes were attacked by action of the sea water. (3) The use of vinsol resin admixture was the most resistant to corrosion by sea water, while the use of pozzolith was the most serious at corrosion and the others were corroded to almost same extent. (4) The relationship between corrosions and compressive strengths of concretes was not clearly correlated yet. It was known that the corrosive rate of concretes could not affect to compressive strengths by 2-year exposure of the sea water. (5) Pozzolan concrete was the most effective in compressive strength when exposed to fresh water only, However, the use of a fly ash admixture was available for compressive strength when exposing to both fresh water and sea water. It was also noticed that the use of vinsol resin was not available for strengths of concrete but for resistance to corrosion when exposed to sea water. (6) It was found that the use of pozzolith was so defective in compressive strengths and corrosiive resistance when exposing to sea water that it was only available for fresh water.

• Computers and Concrete
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• v.20 no.2
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• pp.165-176
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• 2017

Textile Reinforced Cementitious Composite (TRCC) became the most common construction material lately and have excellent properties. TRCC can be employed in the manufacture of thin-walled facade elements, load-bearing integrated formwork, tunnel linings or in the strengthening of existing structures. These composite materials are a combination of matrix and textile materials. There isn't much research done about the usage of polymer modified matrices in textile reinforced cementitious composites. In this study, matrix materials named as fine grained concretes ($d_{max}{\leq}1.0mm$) were investigated. Air entraining effect of polymer modifiers were analyzed and air void content of fine grained concretes were identified with different methods. Aim of this research is to study the effect of polymer modification on the air content of fine grained concretes and the role of defoamer in controlling it. Polymer modifiers caused excessive air entrainment in all mixtures and defoamer material successfully lowered down the air content in all mixtures. Latex polymer modified mixtures had higher air content than redispersible powder modified ones. Air void analysis test was performed on selected mixtures. Air void parameters were compared with the values taken from air content meter. Close results were obtained with tests and air void analysis test found to be useful and applicable to fine grained concretes. Air void content in polymer modified matrix material used in TRCC found significant because of affecting mechanical and permeability parameters directly.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.10a
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• pp.223-226
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• 1999

The purpose of this study is no examine the combination effect on strength preperties of water-permeable concretes mixed with redispersible polymer, silica fume and polypropylene fibers for overlay in pavement. The water-permeable concrete with a water-cement ration of 25%, polymer-cement ratios of 0 to 10%, silica fume contents of 0 to 10% and polypropylene fiver contents of 0 to 1.5% are prepared, and tested for flexural strength, compressive strength and water permeability. It is concluded concretes are obtained at a polypropylene fiber content of 1.0% and a silica fume content of 10% with a void filling ratio of 50%. And the water-permeable concretes with a flexural strength of 14.1~28.0kgf/$\textrm{cm}^2$, a compressive strength of 71.2~128.0kgf/$\textrm{cm}^2$, and a coefficient of permeability of 1.22~2.52cm/s at a void filling ratio of 30% can be prepared. Also water-permeable concretes having flexural strength of 24.9~57.9kgf/$\textrm{cm}^2$, a compressive strength of 83.8~268.5kgf/$\textrm{cm}^2$, and a coefficient of permeability of 0.24~1.04cm/s at a void filling ratio of 50% can be prepared in the consideration of the mix proportioning factors.

• Computers and Concrete
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• v.12 no.1
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• pp.53-64
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• 2013

The curing temperature is known to influence the rate of mechanical properties development of early age concrete. In realistic sites the temperature of concrete is not isothermal $20^{\circ}C$, so the paper measured adiabatic temperature increases of four different concretes to understand heat emission during hydration at early age. The temperature-matching curing schedule in accordance with adiabatic temperature increase is adopted to simulate the situation in real massive concrete. The specimens under temperature-matching curing are subjected to realistic temperature for first few days as well as adiabatic condition. The mechanical properties including compressive strength, splitting strength and modulus of elasticity of concretes cured under both temperature-matching curing and isothermal $20^{\circ}C$ curing are investigated. The results denote that comparing temperature-matching curing with isothermal $20^{\circ}C$ curing, the early age concretes mechanical properties are obviously improved, but the later mechanical properties of concretes with pure Portland and containing silica fume are decreased a little and still increased for concretes containing fly ash and slag. On this basement using an equivalent age approach evaluates mechanical properties of early age concrete in real structures, the model parameters are defined by the compressive strength test, and can predict the compressive strength, splitting strength and elasticity modulus through measuring or calculating by finite element method the concreted temperature at early age, and the method is valid, which is applied in a concrete wall for evaluation of crack risking.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.315-320
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• 2002

The effects of slag content and polymer-binder ratio on the strength properties of the polymer-modified concretes using ground granulated blast-furnace slag and a styrene-butadiene rubber (SBR) latex are examined. As a result, the compressive, tensile and flexural strengths of the SBR-modified concretes using slag increase with increasing polymer-binder ratio and slag content, and maximized at a slag content of 40 ％. In particular, the SBR-modified concretes with a slag content of 40 ％ provide approximately two times higher tensile and flexural strengths than unmodified concretes. Such high strength development is attributed to the high tensile strength of SBR polymer and the improved bond between cement hydrates and aggregates because of the addition of SBR latex.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.945-948
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• 2008

The effects of polymer-cement ratio on strength properties of ultrarapid-hardening acrylic-modified concretes. As a result, the flexural and tensile strengths of ultrarapid-hardening acrylic-modified concretes increase with increasing of polymer-cement ratio. In particular, the acrylic-modified concretes with a polymer-cement ratio of 20% provide approximately 1.5 times higher flexural and tensile strengths than unmodified concretes. Such high strength development is attributed to the high flexrul and tensile strengths of arcylic polymer and the improved bond between cement hydrates and aggregates because of the addition of acrylic polymer. However, the compressive strengths of ultrarapid-hardening acrylic-modified concretes decrease with increasing of polymer-cement ratio.

• Computers and Concrete
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• v.23 no.6
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• pp.421-431
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• 2019

The alarming rate of depletion of natural stone based coarse aggregates is a cause of great concern. The coarse aggregates occupy nearly 60-70% by volume of concrete being produced. Research efforts are on to look for alternatives to stone based coarse aggregates from sustainability point of view. Response surface methodology (RSM) is adopted to study and address the effect of ferrochrome slag (FCS) replacement to coarse aggregate replacement in the ordinary Portland cement (OPC) based concretes. RSM involves three different factors (ground granulated blast furnace slag (GGBS) as binder, flyash (FA) as binder, and FCS as coarse aggregate), with three different levels (GGBS (0, 15, and 30%), FA (0, 15, and 30%) and FCS (0, 50, and 100%)). Experiments were carried out to measure the responses like, workability, density, and compressive strength of FCS based concretes. In order to optimize FCS replacement in the OPC based concretes, three different traditional optimization techniques were used (grey relational analysis (GRA), technique for order of preference by similarity (TOPSIS), and desirability function approach (DFA)). Traditional optimization techniques were accompanied with principal component analysis (PCA) to calculate the weightage of responses measured to arrive at the final ranking of replacement levels of GGBS, FA, and FCS in OPC based concretes. Hybrid combination of PCA-TOPSIS technique is found to be significant when compared to other techniques used. 30% GGBS and 50% FCS replacement in OPC based concrete was arrived at, to be optimal.

• Journal of Electrochemical Science and Technology
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• v.15 no.2
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• pp.242-252
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• 2024

To date, methods used to assess the interfacial transition zone (ITZ), which represents the boundary between the aggregate and paste inside concretes, have primarily relied on destructive tests, and non-destructive tests has received little attention until recently. This study assessed the interfaces of concretes with lightweight aggregates based on electrochemical impedance spectroscopy (EIS) for high-strength concretes and examined the possibility of estimating the compressive strength of concretes through non-destructive testing using EIS. The experimental results revealed that the impedance of the hardened cement increased with increasing compressive strength and aggregate density. In particular, when the results of impedance measurement were displayed as a Nyquist plot, the intercept of the x-axis depicting the effective conductivity was proportional to the compressive strength. Furthermore, an equivalent circuit was selected to interpret the correlation between cement aggregates and impedance. Consequently, the compressive strength was found to increase with the value of the resistances of the electrolyte filled in continuous pores in the cement aggregate. And, the pores formed in the ITZ affect this value. The resistance at the ITZ for different aggregates was also obtained, and it was found that the resistance was consistent with the results predicted by SEM images of the ITZ and correlated with the strength of the concretes. The proposed method can be used as a way to easily determine the strength of cement according to differences in aggregate.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.147-152
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• 2001

The purpose of this study is to ascertain the strength properties of water-permeable polymer concretes with SBR latex and redispersible polymer powder. The water-permeable polymer concretes using SBR latex and redispersible polymer powder with water-binder ratio of 29%, polymer-cement ratios of 0, 5, 10, 15 and 20% are prepared, and tested for compressive strength, tensile strength, flexural strength, water permeability. From the test results, improvements in the strength properties of the water-permeable polymer concretes due to the addition of the SBR latex and redispersible polymer powder are discussed.