• Title/Summary/Keyword: Concentration and Dispersion

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A Study on the Prediction of SO2 Concentrations by the Regional Segment ISCST3 Modeling in the Seoul Metropolitan Area (지역 분할 방법에 의한 ISCST3 모델링으로 수도권 지역에서 SO2 농도 예측 연구)

  • Koo, Youn-Seo;Kim, Sung-Tae;Shin, Bong-Sup;Shin, Dong-Yoon;Lee, Jeong-Joo
    • Journal of Environmental Impact Assessment
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    • v.12 no.4
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    • pp.245-257
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    • 2003
  • $SO_2$ concentrations in the Seoul Metropolitan Area (SMA) were predicted by the regional segment ISCST3 modeling. The SMA was segmented by three modeling regions where the weather monitoring station exists since the area of the SMA, approximately $100km{\times}100km$, is too wide to be modeled by one modeling domain. The predicted concentrations by the model were compared with the measured concentrations at 39 air monitoring stations located in the SMA to validate the ISCST3 modeling coupled with the regional segment approach. The predicted concentrations by the regional segment method showed better performance in depicting the measurements than those by the non-segment ISCST3 modeling. The correction methods of the calculated concentrations reviewed were here the correlation method by the first order linear equation and the ratio method of observed to calculated concentrations. The corrected concentrations by two methods showed good agreement with the measured data. The ratio method was, however, easily applicable to the concentration correction in case of a wide modeling region considered in this study.

Characteristics of Graphene Production from Graphite using Plant Extracts (식물추출액을 이용한 흑연으로부터 그래핀 생산 특성)

  • Jeong, Yongjae;Ryu, Hojun;Choi, Chorong;An, Sanghyeon;Kim, Woojung;Kim, Dongho;Choi, Byeongseo;Salunke, Bipinchandra K.;Kim, Beom Soo
    • KSBB Journal
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    • v.31 no.4
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    • pp.208-213
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    • 2016
  • Recently, numerous studies have utilized graphene in biomedical applications such as drug delivery, cancer therapy, and bioimaging. In this study, graphene was eco-friendly prepared by liquid phase exfoliation of graphite using plant extracts in water. Initially, 12 different plants or plant parts were screened for the characteristic graphene peak at near 268 nm using UV-Vis spectrophotometric analyses. The ability to form stable black graphene dispersion was highest using Xanthium strumarium extract. Transmission electron microscopy images showed that about 5 layer-graphene was produced from 1 g/L of graphite, while more than 5 layers were formed from 2 g/L of graphite. The optimum X. strumarium concentration for graphene production was 2 g/100 mL.

Lead Transport in Groundwater in Door County, Wisconsin (위스컨신주 도어지역의 지하수내 납성분의 이동)

  • Woo, Nam C.
    • Economic and Environmental Geology
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    • v.27 no.1
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    • pp.93-100
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    • 1994
  • This study examined the mechanisms of lead transport in the groundwater system and those of irregular detections in groundwater in Door County, Wisconsin. During the spring recharge period in 1991, water-level movement and water-quality change were monitored from two monitoring wells equipped with three piezometers each and from five house wells, respectively. Water-level responses to recharge events were fast with a relatively short lag time ranging from 3 to 10 days, indicating that recharge of groundwater occurs through the high hydraulic conductivity (K) zones in the Silurian dolomite aquifer system. Lead was detected only on particles filtered from groundwater, but not in dissolved state. Concentrations ranged from 0.2 to $7.1{\mu}g/mg$, converted into the total lead concentration in groundwater ranging from $0.3{\mu}g/l$ to $4.7{\mu}g/l$. A lag time between recharge events and peak particle movement at the sampled wells was estimated to range from 19 to 22 days. Due to the particulate nature of lead in groundwater, only the wells connected with the high K zones detect lead, causing the spatial variation. In a given well, lead concentration varies at different sampling times due to the variation in the initial amounts of lead-carrying particles introduced into the groundwater system during recharge events, the lag in particle transport and the dispersion of lead-carrying particles along the advective flowpaths.

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Seasonal Nitrogen Oxides Improvement due to On-road Mobile Air Pollution Source Emission Control Plan in Seoul Metropolitan Area (도로이동오염원 대기오염 저감대책에 의한 수도권 지역 계절별 질소산화물 개선효과)

  • Kim, Yoo Jung;Jeong, Hye-Seon;Kim, Suhyang;Ma, Young-Il;Lee, Woo-Keun;Kim, Jeongsoo;Sunwoo, Young
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.5
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    • pp.269-278
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    • 2016
  • In order to improve air quality in the Seoul Metropolitan Area (SMA), the "Special Act on Seoul Metropolitan Air Quality Improvement" has been enforced since 2005. The strategy has resulted in some reduction of air pollution, but there has not been much research into the quantitative impact analysis of each separate preventive countermeasure. Therefore, we analyzed nitrogen oxide reduction resulting from implementation of the emission control plan for on-road mobile sources. The MM5-SMOKE-CMAQ model system was employed for air quality prediction. Reduced $NO_x$ emissions for SMA was 16,561 ton, 4.7% of reduction rate, in 2007. One countermeasure, tighter acceptable standards for manufacturing vehicles, dominated other countermeasures for effective $NO_x$ emission control. Large spatial differences in reduced emissions, those for Seoul being twice that of Incheon and Gyeonggi, showed greater $NO_x$ emission reduction impact in the heart of the metropolitan complex. The $NO_2$ concentration decreased by 0.60 ppb (2.0%), 0.18 ppb (1.5%), and 0.22 ppb (1.7%) in Seoul, Incheon, and Gyeonggi, respectively. Concentration decreases in spring and winter were larger, 1.5~2.0 times, than summer and fall. However, the $NO_2$ reduction impact did not correspond directly to local $NO_x$ emission controls in the city area because of the natural flow and dispersion, both urban and downwind.

Supercritical Fluid Dyeing of Polyester Fiber with Two Different Dispersion Dyes (두 종류의 분산염료를 이용한 폴리에스테르 섬유의 초임계유체 염색)

  • Jung, In-Il;Lee, Sang-Yun;Lim, Gio-Bin;Ryu, Jong-Hoon
    • Clean Technology
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    • v.17 no.2
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    • pp.110-116
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    • 2011
  • The dyeing of polyester fiber with two different disperse dyes (Disperse Red 60 and Disperse Yellow 54) was carried out using supercritical carbon dioxide ($SCCO_2$) as a dyeing medium at temperatures ranging from $50^{\circ}C$ to $90^{\circ}C$ and at pressures from 15 MPa to 30 MPa. The dye uptake of Disperse Red 60 on polyester fiber was found to increase with temperature at constant pressure and $SCCO_2$ density (700 kg/$m^3$). At $90^{\circ}C$ and 30 MPa, the dye uptake on polyester fiber increased with dyeing time and the saturation concentration of Red 60 was attained within 240 min, while a longer dyeing time was required for Yellow 54 to reach its saturation concentration. When dyestuff mixtures with mixing ratios of 0.01 to 9.0 (Red 60/Yellow 54) were used, the uptake ratio of the two dyes was found to be proportional to 0.26 power of their mixing ratio. Dyed fibers showed an orange color and the depth of the color depended upon the mixing ratio of the dyestuffs.

A Spatial Analysis on the Socio-Cultural Level of Informatization Aspects (정보화 차원의 사회 ${\cdot}$ 문화 발전 수준에 대한 공간 분석)

  • Yoo, Yeong-Jun
    • Journal of the Korean Geographical Society
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    • v.31 no.3
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    • pp.529-541
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    • 1996
  • The Korean economy has recently changed from industry-based economy toward information-based one, empha-sizing on information utiliation and technological development. It is important to examine the background for the incoming information society and spatial aspect of infromation, because informati-zation process itself contains spatial features like spatial concentrtion and dispersion. This paper generally focuses on the socio-cultural aspects of the informati-zation aspects. The main questions are as follows: 1) what are the ain questions of the exsisting Korean case studies on the informatization; 2) how can we find the charateristics of spatial concentration of informatization by informatization indices; 3) is there any relationship between the degree of informatiztion and regional development? The results of this study can be found in the following facts: (1) The exsisting studies cannot be generallized as spatial analysis on the informatization In general, they focus only a single aspect of information industry or information job. Futhermore, their spatial unit of analysis is limited to provincial level, rather thn city-level micro study. (2) There are big differences between the Capital region, especially Seoul, and others with regard to the socio-cultural aspects of informatiation. Such informatization is concentrated in Seoul. Inchon and Kyeonggi-do, which are the better positions in information intensive activities. (3) The regional differences for the level of informatization are much bigger than those for the level of welfare, suggesting that the informatization tends to concentrate in specified large cities like Seoul. It is clear the Korea is now entering the initial stage of information society.

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Hydraulic Experiment for Pollutant Discharge Characteristics in a Wolseong Nuclear Power Plant Port (월성원자력발전소의 항내 오염물 유출 특성에 관한 수리실험)

  • Yang, Byung-Mo;Min, Byung-Il;Park, Kihyun;Kim, Sora;Lee, Jung Lyul;Suh, Kyung-Suk
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.2
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    • pp.113-122
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    • 2016
  • In this study, the dispersion process of pollutant substances in a port under wave and current environments was evaluated by a hydraulic experiment. Once the contaminants washed ashore into the port of Wolseong nuclear power plant, transport processes of pollutants were investigated by tracking the tracer according to the variations of experimental condition through a hydraulic experiment. Several hydraulic experiments were performed to analyze the pollutant discharge rate of the surface coming from the different coastal environments. From the hydraulic experiment results, the tracer concentration decreased exponentially. These results suggested that, after the tracer was transported to the open sea, a different gradient was shown under different conditions. For the case of a diluted condition, the half-life of flow rate was 2.70, 10.40, and 26.39 days for 30, 20 and 10 rpm in the left-side, respectively. The decrease of the tracer concentration under conditions of 30 rpm was much faster than that under conditions of 10 rpm. For the wave condition, the half-life of flow rate was 4.59 and 15.35 days for the right and left side of the port in a hydraulic scale prototype, respectively.

Phase Behavior of Ternary Mixture of Poly(ethylene-co-octene) - Ethylene - 1-Octene (Poly(ethylene-co-octene) - Ethylene - 1-Octene 3성분계 혼합물의 상거동)

  • Lee, Sang-Ho;Sohn, Jin-Eun;Chung, Sung-Yoon;Han, Sang-Hoon
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.116-124
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    • 2006
  • Cloud-point data to $160^{\circ}C$ and 1,000 bar are presented with poly(ethylene-co-15.3 mole% octene) copolymers ($PEO_{15}$) in pure 1-octene and mixtures of ethylene - 1-octene. The cloud-point curves for $PEO_{15}$ - ethylene - 1-octene mixture dramatically increase in pressure to as high as 1,000 bar with an increasing ethylene concentration. At ethylene concentrations less than 18 wt%, the ternary mixture has bubble- and cloud-point curves. As the ethylene concentration of the ternary mixture increases, the bubble-point curve and the single-phase region reduce. The reduction in the single phase region with increasing ethylene concentrations is the result of reduced dispersion interactions between $PEO_{15}$ and the mixed solvent. The single-phase region decreases with increasing temperatures when ethylene concentrations are lower than 36 wt%, whereas the single-phase region increases with temperatures at ethylene concentrations greater than 50 wt%. At ethylene concentrations greater than 50 wt% the effect of the polar interactions of the mixed solvent, which is unfavorable to dissolve PEO, is greater than the effect of the density of the mixed solvent. Therefore, the cloud-point pressures increase with a decreasing temperature. However, at ethylene concentrations less than 50 wt%, the cloud-point pressures decrease with temperature, because the effect of the polar interactions is less than the density effect.

Flow Behavior of Polystyrene and Poly(butyl methacrylate) Composite Particles Filled with Varying Concentrations of Carbon Black (다양한 농도의 카본블랙을 함유하는 폴리스티렌 및 폴리뷰틸메타크릴레이트 복합체 입자의 유동성)

  • Park, Moon-Soo
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.336-342
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    • 2009
  • We measured shear viscosity of polystyrene (PS) and poly(butyl methacrylate) (PBMA) particles, with a capillary rheometer, prepared by suspension polymerization with 1.0 wt% hydrophobic silica as a stabilizer by varying the initiator concentration at $75^{\circ}C$. PS particles with weight average molecular weight of 66,500 g/mol displayed a Newtonian behaior at low shear rates at $190^{\circ}C$. With increasing molecular weight, PS particles showed shear thinning over the entire range of shear rates. For PBMA particles, steady shear measurement was carried out at $170^{\circ}C$. PBMA particles with weight average molecular weight of 156,700 g/mol showed a Newtonian behaior only at low shear rates. PBMA particles also showed shear thinning with an increase in molecular weight and its pattern similar to that of PS. When carbon black was incorporated into PS and PBMA polymers, steady shear measurement was conducted at $170^{\circ}C$. An increase in carbon black concentration in PS and PBMA composite particles exhibited a progressive increase in shear viscosity. The increase in shear viscosity, however, was less pronounced compared to an increase as a function of molecular weight. Preparing PS composites containing carbon black by internal mixing resulted in an increase in shear viscosity. Its increase, however, was found to be less than that shown in PS composite particles. We speculate that this is caused by an enhanced dispersion of carbon black particles with an internal mixer. Yield behavior was not observed in any of the samples we selected in this experiment.

Analysis of Solute Transport based on Electrical Resistance Measurements from Laboratory Column Tests (전기저항센서가 부착된 주상실험기에서 측정된 전기저항값을 이용한 용질의 이동해석)

  • Kim, Yong-Sung;Kim, Jae-Jin;Park, Junboum
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.4C
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    • pp.231-238
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    • 2008
  • A column testing device capable of measuring the electrical resistivity of soil at 3 different locations was developed to verify applicability of bulk electrical conductivity (BEC) breakthrough curves in monitoring contaminant transport. Tracer injection tests were conducted with three different types of saturated sands to obtain average linear velocities and longitudinal hydrodynamic dispersion coefficients based on BEC breakthrough curves and effluent solute breakthrough curves. Comparative analysis of transport parameters obtained from curve fitting the results into the analytical solutions confirmed the validity of resistance measurements in estimating time-continuous resident solute concentration. Under the assumption that a linear relationship exists between ${\sigma}_{sat}-{\sigma}_w-C$, the BEC breakthrough curves are able to effectively reduce the laborious and time-consuming processes involved in the conventional method of sampling and analysis. In order to reduce possible uncertainties in analyzing the BEC breakthrough curves, it was recommended that resistance measurements take place nearby the effluent boundary. In addition, a sufficient electrical contrast or difference in the electrical conductivity of the influent and the saturating solution is required to conduct reliable analysis.