• Title/Summary/Keyword: Concentration Polarization

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Evaluation of Fracture Toughness($J_{IC}$) on 304 Stainless Steel Weldments Artificially Degraded under SCC Environment (SCC 분위기 하에서 장시간 인공열화된 304 스테인리스강 용접부의 파괴인성($J_{IC}$)평가)

  • 김성우;배동호;조선영;김철한
    • Journal of Welding and Joining
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    • v.17 no.2
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    • pp.76-83
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    • 1999
  • Fracture toughness({TEX}$J_{IC}${/TEX}) on 304 austenitic stainless steel weldments artificially degraded for long period under SCC environments were evaluated to investigate its reliability and environmental characteristics. Electro-chemical polarization tests were previously carried out to evaluate corrosion susceptiblility of weldment, and stress corrosion cracking was tested under various conditions of 3.5wt.% NaCl solution, the temperature of $25^{\circ}$C and $95^{\circ}$C, and oxygen concentration during 3000hours. From the results obtained, it was found that 304 stainless steel weldment was so susceptible under high temperature and high oxygen concentration of 3.5wt.% NaCl solution, and fracture toughness({TEX}$J_{IC}${/TEX}) was also considerably reduced by material degradation.

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A Study on the Initiation of Pitting Corrosion of Fe-17Cr Alloy Using Micro-Droplet Cell Technique (Micro-droplet cell을 이용한 Fe-17Cr 합금의 공식 발생에 대한 연구)

  • Kim, Jae-Jung;Lee, Jae-Bong
    • Korean Journal of Metals and Materials
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    • v.46 no.12
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    • pp.809-816
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    • 2008
  • The influences of various parameters such as inclusions, surface roughness, exposed areas and chloride ion concentrations on the initiation of pitting of Fe-17Cr alloy were investigated, using micro-droplet cell technique. Micro-droplet cell allows one to align the micro-electrode to the desired spot of the working electrode and measure directly local currents with the potentiodynamic polarization. Micro electrochemical tests were carried out at the inclusions after EDX analysis of inclusion. EDX analysis identified inclusions as Cr-oxides. It was found that some active inclusions among Cr-oxide inclusions acted as initiation sites for pitting corrosion. In addition, the rougher surface and the denser chloride ion concentration offered easier pit initiation sites, causing the more susceptible to pitting corrosion.

Investigation of some Natural Product Extracts as Corrosion Inhibitors for Mild Steel in Acid Mediu

  • Subramania, A.;Sathiya Priya, A.R.;Saravanan, S.;Abdul Nasser, A.J.;Vasudevan, T.
    • Corrosion Science and Technology
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    • v.4 no.6
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    • pp.231-235
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    • 2005
  • The inhibitive effect of extracts of tamarind seeds and jackfruit seeds, curry leaves and henna leaves on corrosion of mild steel in 1M HCl solution have been studied by weight loss, potentiodynamic polarization and impedance measurements. Results obtained from the electrochemical techniques were in good agreement with weight loss results. From the weight loss data, the values of surface coverage ($\Theta$) and corrosion rate were calculated. The inhibition efficiency (IE) increased with increasing inhibitor concentration in 1M HCl solution. In all the cases the adsorption of the natural product extracts on the mild steel surface from 1M HCl follows the Langmuir adsorption isotherm relationship. Potentiodynamic polarization studies reveal the fact that all the four natural product extracts act as mixed type inhibitors. The decrease in the inhibition efficiency follows the order: Extracts of jackfruit seed>henna leaves>curry leaves>tamarind seed.

Lornoxicam & Tenoxicam Drugs as Green Corrosion Inhibitors for Carbon Steel in 1 M H2SO4 Solution

  • Fouda, A.S.;El-Defrawy, A.M.;El-Sherbeni, M.W.
    • Journal of Electrochemical Science and Technology
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    • v.4 no.2
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    • pp.47-56
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    • 2013
  • Inhibition performance of Lornoxicam & Tenoxicam against corrosion of carbon steel in 1M $H_2SO_4$ solutions was investigated by weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements. The inhibition efficiency increased with increasing inhibitor's concentration, but decreased with increase in temperature. Potentiodynamic polarization curves showed that, the inhibitors were of mixed type. The apparent activation energy ($E^*_a$) and other thermodynamic parameters for the corrosion process have also been calculated and discussed. The inhibition of carbon steel corrosion is due to the adsorption of the inhibitor molecules on the surface, which follows Temkin adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors.

Process and Characteristics of High Power Catalyst Electrode for PEM Fuel Cell

  • Chang H.;Lim C.;Kim J.
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.171-175
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    • 1999
  • Novel process for high power catalyst electrode for PEM fuel cell has been developed. MEA having this catalyst electrode showed $0.5W/cm^2\;with\;0.2mg/cm^2$ of Pt loading at aunospheric humid hydrogen and oxygen condition. In this process, platinized carbon and plain carbon powders were coated with ionomer (Nafion) and hydrophobic polymer (PTFE), respectively and it could maximize two roles of catalyst electrode, l.e., reaction and gas supplying component. Those polarization characteristics proved the improved performance by reducing potential drop especially in the concentration polarization region.

Evaluation of Electrochemical and Mechanical Characteristics in MIG Welding Parts of Dissimilar Al Alloys for Ship (선박용 이종 알루미늄 합금 미그 용접부의 기계적 및 전기화학적 특성 평가)

  • Woo, Yong-Bin;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.42 no.1
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    • pp.34-40
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    • 2009
  • In the study, it was carried out dissimilar metal welding on materials for Al ship. The electrochemical and mechanical characteristics evaluated for specimen welded by ROBOT. The hardness of welding zone is lower than those of heat affected zone and base metal. At the result of tensile test, the specimen welded with ER5183 welding material presented excellent property compared with ER5556. The polarization trend for the base metal and welding metal showed the effects of concentration polarization due to oxygen reduction and activation polarization due to hydrogen generation. At the Tafel experiments result, the corrosion density in welded with ER5183 welding material presented the lowest value.

Electrochemical model for the simulation of solid oxide fuel cells (고체산화물연료전지의 시뮬레이션을 위한 전기화학모델)

  • Park, Joon-Guen;Lee, Shin-Ku;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.63-66
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    • 2008
  • This study presents 0-dimensional model for solid oxide fuel cells(SOFCs). The physics of the cell and the simplifying assumptions are presented, and only hydrogen participates in the electrochemical reaction. The electrical potential is predicted using this model. The Butler-Volmer equation is used to describe the activation polarization and the exchange current density is changed according to the partial pressure of reactants and the temperature. The electrical conductivities of electrodes and an electrolyte are calculated for the ohmic polarization. Material characteristics and temperature affect those factors. Analysis of concentration polarization based on transport of gaseous species through porous electrodes is incorporated in this model. Both binary diffusion and Knudsen diffusion are considered as the diffusion mechanism. For validation, simulation results at this work are compared with our experimental results and numerical results by other researchers.

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The Study on the Behavior of Polarization curve of Reinforcement with Oxidation Layer (산화피막이 있는 철근의 분극곡선의 거동에 대한 연구)

  • 한정섭
    • Journal of Ocean Engineering and Technology
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    • v.14 no.1
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    • pp.60-66
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    • 2000
  • In order to study for corrosion behavior of reinforcing steel with oxidation layer. Experiments were done with various NaCl concentrations and with immersion time in simulated concrete pore solution(SPS) the characteristics of corrosion behavior were measured by polarization resistance method and cyclic potentiodynamic method. reinforcements were coated by epoxy except corrosion without oxidation layer and it also showed two anodic-nose. by the result of potention dynamic test the potential curve shift to low with time and anodic-nose was appeared with 3% NaCl solution after 15 days. By result of cyclic Potentiodynamic test the type of corrosion was different accoding to concentration.

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