• Title/Summary/Keyword: Concentration Gradient

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Roughness and micro pit defects on surface of SUS 430 stainless steel strip in cold rolling process

  • Li, Changsheng;Zhu, Tao;Fu, Bo;Li, Youyuan
    • Advances in materials Research
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    • v.4 no.4
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    • pp.215-226
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    • 2015
  • Experiment on roughness and micro pit defects of SUS 430 ferrite stainless steel was investigated in laboratory. The relation between roughness and glossiness with reduction in height, roll surface roughness, emulsion parameters was analyzed. The surface morphology of micro pit defects was observed by SEM, and the effects of micro pit defects on rolling reduction, roll surface roughness, emulsion parameters, lubrication oil in deformation zone and work roll diameter were discussed. With the increasing of reduction ratio strip surface roughness Ra(s), Rp(s) and Rv(s) were decreasing along rolling and width direction, the drop value in rolling direction was faster than that in width direction. The roughness and glossiness were obtained under emulsion concentration 3% and 6%, temperature $55^{\circ}C$ and $63^{\circ}C$, roll surface roughness $Ra(r)=0.5{\mu}m$, $Ra(r)=0.7{\mu}m$ and $Ra(r)=1.0{\mu}m$. The glossiness was declined rapidly when the micro defects ratio was above 23%. With the pass number increasing, the micro pit defects were reduced, uneven peak was decreased and gently along rolling direction. The micro pit defects were increased with the roll surface roughness increase. The defects ratio was declined with larger gradient at pass number 1 to 3, but gentle slope at pass number 4 to 5. When work roll diameter was small, bite angle was increasing, lubrication oil in micro pit of deformation zone was decreased, micro defects were decreased, and glossiness value on the surface of strip was increased.

Radial Distribution of Calcium, Phosphorus, Iron, Thiamine and Riboflavin in the Degermed Brown Rice Kernel (현미입(玄米粒) 내의 칼슘, 인, 철, 비타민$B_1$$B_2$의 분포에 관한 연구)

  • Kim, Sung-Kon;Cheigh, Hong-Sik
    • Korean Journal of Food Science and Technology
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    • v.11 no.2
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    • pp.122-125
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    • 1979
  • Degermed brown rice of Akibare (short grain) and Milyang 23 (medium grain) was abraded fiveconsecutive times to remove outer $5{\sim}6%$ of the kernel per milling. Samples were analyzed for calcium, phosphorus, iron, thiamine and riboflavin. Milled fraction I (about $5{\sim}6%$ of the kernel) contained 8 times as much calcium and phosphorus as did the original kernel; iron, $4{\sim}5$; thiamine, 3; and riboflavin, 4. Contents of fraction I were much greater than those in the residual kernel; 18 times as great for calcium; $32{\sim}36$ times for phosphorus; $5{\sim}10$ times for iron 5 times for thiamine; and $19{\sim}30$ times for riboflavin. Milyang 23 showed a steeper concentration gradient of calcium and riboflavin, but more even distribution of iron than did Akibare. There were no significant differences in phosphorus and thiamine gradients between the two rices.

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The Effect of NaCl on the Greening of Etiolated Leaves of Barely (Hordeum vulgare L.) Seedings (NaCl이 황백화된 보리(Hordeum vulgare L.) 잎의 녹화에 미치는 영향)

  • 정화숙;임영진;송승달;노광수;송종석;박강은
    • Journal of Environmental Science International
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    • v.11 no.10
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    • pp.1023-1030
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    • 2002
  • The effects on photosynthesis of NaCl(0, 0.2, 0.4, 0.6, 0.8 or 1.0 M) were examined in etiolated barley seedlings. Chlorophyll(Chl) a, Chl b and carotenoid contents, Chl a fluorescence and quenching coefficients of Chl fluorescence have been determined in the primary leaves of etiolated barley seedlings cultivated under low light(60 $\mu$$m^{-2}\;s^{-1}$). Chl a, b, and carotenoid contents were decreased remarkably in comparison with the control at 0.4 M NaCl. However, the value of Fo and Fv were decreased at 0.6 M NaCl and the ratio of Fv/Fm were deceased at 1.0 M NaCl. Chlorophyll synthesis was seriously inhibited from 0.4 M NaCl, and the photosynthetic electron transport system was inhibited from 0.6 M NaCl. Quantum of photosystem II reaction center was inhibited at 1.0 M NaCl. The effects of NaCl on the Chl content were raised in a 6 hrs, but the effects of NaCl on the value of Fo, Fv and Fv/Fm were raised in 30 hrs. The value of qP was decreased in comparison with the control at all concentrations, but there was a small change in the value qE. These results provide evidence that NaCl inhibited effects of various concentration of NaCl were inhibited quinone redox, however, proton gradient between thylakoid membranes was little damaged.

Cometabolism degradation of lignin in sequencing batch biofilm reactors

  • Kuang, Faguo;Li, Yancheng;He, Lei;Xia, Yongqiu;Li, Shubai;Zhou, Jian
    • Environmental Engineering Research
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    • v.23 no.3
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    • pp.294-300
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    • 2018
  • Cometabolism technology was employed to degrade lignin wastewater in Sequencing Batch Biofilm Reactor. Cometabolic system (with glucose and lignin in inflow) and the control group (only lignin in inflow) were established to do a comparative study. In contrast with the control group, the average removal rates of lignin increased by 14.7% and total oarganic carbon increased by 32% in the cometabolic system with glucose as growth substrate, under the condition of 5 mg/L DO, $0.2kgCOD/(m^3{\cdot}d)$ lignin and glucose $1.0kgCOD/(m^3{\cdot}d)$. Functional groups of lignin are degraded effectively in cometabolic system proved by fourier transform infrared spectroscopy and Gas Chromatography-Mass Spectrometer, and the degradation products were amides (mainly including acetamide, N-ethylacetamide and N, N-diethylacetamide), alcohols (mainly including glycerol and ethylene glycol) and acids. Meanwhile, results of Polymerase Chain Reaction-Denaturing Gradient Gel Electrophoresis showed great differences in microbial population richness between cometabolic system and the control group. The Margalef's richness index and Shannon-Wiener's diversity index of microorganism in cometabolic system were 3.075 and 2.61, respectively. The results showed that extra addition of glucose, with a concentration of 943 mg/L, was beneficial to lignin biodegradation in cometabolic system.

Distribution of Minerals within the Degermed Brown Rice Kernel (배아를 제거한 현미립내의 무기질의 분포)

  • Song, Bo-Hyeon;Kim, Dong-Youn;Kim, Sung-Kon;Kim, Young-Du;Choi, Kap-Seong
    • Applied Biological Chemistry
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    • v.31 no.2
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    • pp.162-168
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    • 1988
  • The contents of minerals of the milled fractions of degermed Japonica and J/Indica brown rices were determined. The fraction I(about 4.4% of the kernel weight) contained 14.8 times as much sodium as did the original kernel; phosphorus, 5.7 times; potassium and iron, 5.4 times; magnesium, 4.2 times; calcium, 3.8 times; manganese, 3.7 times; Copper, 3.6 times; and Zinc, 2.3 times. Concentrations of these minerals were the lowest in the residual kernel, which contained less than the original brown rice. Sodium showed the most deepest concentration gradient, while iron was the most evenly distributed within the kernel in all samples.

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Mechanical Properties and Shape Memory Characteristics of NiAl Alloys by Powder Metallurgy (분말야금법으로 제작한 NiAl합금의 기계적성질 및 형상기억특성)

  • Han, Chang-Suk;Jin, Sung-Yooun;Kwon, Hyuk-Ku
    • Korean Journal of Materials Research
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    • v.30 no.5
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    • pp.231-238
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    • 2020
  • The composition of martensite transformation in NiAl alloy is determined using pure nickel and aluminum powder by vacuum hot press powder metallurgy, which is a composition of martensitic transformation, and the characteristics of martensitic transformation and microstructure of sintered NiAl alloys are investigated. The produced sintered alloys are presintered and hot pressed in vacuum; after homogenizing heat treatment at 1,273 K for 86.4 ks, they are water-cooled to produce NiAl sintered alloys having relative density of 99 % or more. As a result of observations of the microstructure of the sintered NiAl alloy specimens quenched in ice water after homogenization treatment at 1,273 K, it is found that specimens of all compositions consisted of two phases and voids. In addition, it is found that martensite transformation did not occur because surface fluctuation shapes did not appear inside the crystal grains with quenching at 1,273 K. As a result of examining the relationship between the density and composition after martensitic transformation of the sintered alloys, the density after transformation is found to have increased by about 1 % compared to before the transformation. As a result of examining the relationship between the hardness (Hv) at room temperature and the composition of the matrix phase and the martensite phase, the hardness of the martensite phase is found to be smaller than that of the matrix phase. As a result of examining the relationship between the temperature at which the shape recovery is completed by heating and the composition, the shape recovery temperature is found to decrease almost linearly as the Al concentration increases, and the gradient is about -160 K/at% Al. After quenching the sintered NiAl alloys of the 37 at%Al into martensite, specimens fractured by three-point bending at room temperature are observed by SEM and, as a result, some grain boundary fractures are observed on the fracture surface, and mainly intergranular cleavage fractures.

Quantitative Analysis and Antioxidant Effects of Gyejibokryeong-hwan (LC-MS/MS를 이용한 계지복령환(桂枝茯苓丸)의 동시분석 및 항산화 효능 연구)

  • Seo, Chang-Seob;Kim, Ohn Soon;Shin, Hyeun-Kyoo
    • Korean Journal of Pharmacognosy
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    • v.45 no.3
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    • pp.240-248
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    • 2014
  • Gyejibokryeong-hwan (GJBRH) has been used for treatment of patients with climacteric syndrome. In this study, an ultra-performance liquid chromatography-electrospray ionization-mass spectrometer (UPLC-ESI-MS) method was established for the simultaneous quantification of seven marker compounds in GJBRH extract. In addition, we assessed the antioxidant effects of GJBRH. All analytes were separated by gradient elution using two mobile phases on a UPLC BEH $C_{18}$ column and maintained at $45^{\circ}C$. The antioxidant activities of GJBRH were evaluated by measuring free radical scavenging activities on 2,2'-azinobis-3-ethyl-benzothiazoline-6-sulfonic acid (ABTS) and 1-1-diphenyl-2-picrylhydrazyl (DPPH). The inhibitory effects on low-density lipoprotein (LDL) oxidation were evaluated by the formation of thiobarbituric acid relative substances (TBARS) and relative electrophoretic mobility (REM). Regression equations of the seven compounds were acquired with $r^2$ values ${\geq}0.9988$. The amounts of the seven compounds, amygdalin, albiflorin, paeoniflorin, coumarin, cinnamic acid, cinnamaldehyde, and paeonol in GJBRH water extract were 21.71, 2.16, 17.17, 1.97, 0.40, 0.78, and 3.42 mg/g, respectively. The GJBRH showed the radical scavenging activity in a dose-dependent manner. The concentration required for 50% reduction ($RC_{50}$) against ABTS and DPPH radicals were $54.18{\mu}g/mL$ and $79.53{\mu}g/mL$. Furthermore, GJBRH reduced the oxidation properties of LDL induced by $CuSO_4$.

An Estimation of the New Production in the Southern East Sea Using Helium Isotopes

  • Kim, Kyung-Ryul;Hahm, Do-Shik
    • Journal of the korean society of oceanography
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    • v.36 no.1
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    • pp.19-26
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    • 2001
  • The biological pump is one of the important pumping mechanisms absorbing CO$_2$ from the atmosphere into the ocean and can be quantified by estimating new production. New production in the open ocean mostly depends on the supply of nitrate from the water below the mixed layer. While nitrate is affected by many biological processes, the helium isotope ($^3$He) is inert and has very simple physical properties. Using the $^3$He flux and the relation between $^3$He and NO${_3}\;{^-}$- within the thermocline, the nitrate flux supporting new production was estimated in the southern East Sea. The average ${\delta}^3$He within the mixed layer was -14$%_o$ and -l5.4$%_o$ in the winter and autumn, respectively. Through the year excess $^3$He occurs in the mixed layer except for a slight depletion of -17$%_o$ in summer. The $^3$He flux of 13$%_o$md$^{-1}$ associated with the concentration gradient at the air-sea interface was calculated from the product of the piston velocity and the excess $^3$He. Tritium decay within the mixed layer could support only 2$%_o$md$^{-1}$ of the flux. Thus, the remaining 11$%_o$md^{-1}$ could be attributed to the flux of tritiugenic $^3$He from the water below the mixed layer. Nitrate and $^3$He were positively correlated within the thermocline layer with the slope of 0.21 ${\mu}$mol kg$^{-1}$ $%_o\;^{-1}$. The annual nitrate flux estimated from the upward flux of $^3$He and the NO$_{3}\;{^-}$-$^3$He relation was 0.8${\pm}$0.2 mol(N) m$^{-2}$yr$^{-1}$. This flux corresponds to an annual new production of 64 g(C) m$^{-2}$yr$^{-1}$, which is consistent with that in the north-west Pacific.

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A first-principles theoretical investigation of the structural, electronic and magnetic properties of cubic thorium carbonitrides ThCxN(1-x)

  • Siddique, Muhammad;Rahman, Amin Ur;Iqbal, Azmat;Azam, Sikander
    • Nuclear Engineering and Technology
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    • v.51 no.5
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    • pp.1373-1380
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    • 2019
  • Besides promising implications as fertile nuclear materials, thorium carbonitrides are of great interest owing to their peculiar physical and chemical properties, such as high density, high melting point, good thermal conductivity. This paper reports first-principles simulation results on the structural, electronic and magnetic properties of cubic thorium carbonitrides $ThC_xN_{(1-x)}$ (X = 0.03125, 0.0625, 0.09375, 0.125, 0.15625) employing formalism of density-functional-theory. For the simulation of physical properties, we incorporated full-potential linearized augmented plane-wave (FPLAPW) method while the exchange-correlation potential terms in Kohn-Sham Equation (KSE) are treated within Generalized-Gradient-Approximation (GGA) in conjunction with Perdew-Bruke-Ernzerhof (PBE) correction. The structural parameters were calculated by fitting total energy into the Murnaghan's equation of state. The lattice constants, bulk moduli, total energy, electronic band structure and spin magnetic moments of the compounds show dependence on the C/N concentration ratio. The electronic and magnetic properties have revealed non-magnetic but metallic character of the compounds. The main contribution to density of states at the Fermi level stems from the comparable spectral intensity of Th (6d+5f) and (C+N) 2p states. In comparison with spin magnetic moments of ThSb and ThBi calculated earlier with LDA+U approach, we observed an enhancement in the spin magnetic moments after carbon-doping into ThN monopnictide.

On vertical profiles of cohesive sediment: concentration, velocity gradient, and Stokes number (가는 유사 부유의 연직구조 특성 : 농도, 속도경사, 스토크스 수)

  • Son, Minwoo;Byun, Jisun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2016.05a
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    • pp.391-391
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    • 2016
  • 유수동역학적인 요소와 유사의 부유는 서로 상호작용을 주고받으며 다양한 현상을 만들어낸다. 많은 선행연구를 통해 유사 농도 등의 특성이 난류 구조 등의 변화를 야기하며, 변화한 난류 구조 역시 유사의 부유 등에 2차적인 영향을 준다는 점이 확인되었다. 본 연구에서는 가는 유사에 보다 집중하여 유사 부유와 이에 따른 연직구조 특성의 변화를 살펴본다. 본 연구에서는 1차원 연직 모형을 이용하여 수치실험을 수행한다. 본 연구에 이용된 모형은 가는 유사의 특성인 빠른 입자 반응 시간(Particle Response Time)이 가정되는 모형으로 선행연구를 통해 적용성이 검증된 것으로 판단한다. 주요 분석대상은 유사의 농도와 속도경사 간의 관계 등이며, 분석하는 유사 농도 종류는 일반적인 비점착성 유사의 경우에 관심을 가지는 질량 농도에 집중하여 결정된다. 수치실험 수행을 위해서는 정류 흐름, 진동파 흐름 등이 적용되었고 다양한 경우의 가는 유사를 고려하기 위한 실험조건의 변경이 이루어졌다. 수치실험 결과 진동파의 다양한 위상에서 조금씩 달라지는 연직구조가 확인되었다. 이는 보정되는 Schmidt 수의 값과도 연관관계를 가지는 것으로 나타났다. 특히 가는 유사의 경우에도 입자의 크기에 따라 다른 연직구조의 특성이 모의되었으며 이를 통해 수치실험의 경우에도 입자 크기의 고려 하에 매개변수의 보정이 이루어져야 한다는 점을 알 수 있다. 스토크스 수는 입자 반응 시간과 유체 난류 시간규모(Fluid Turbulence Ttime Scale)의 비율을 의미한다. 본 연구를 통해 스토크스 수가 유사의 확산강도 결정과 큰 상관 관계를 가지는 것을 알 수 있다. 이때 유사의 크기와 보정되는 Schmidt 수의 값은 고정되었다. 수치 계산시에 확산계수의 값이 부유 및 이에 따른 연직구조의 특성을 결정하는 중요한 변수라는 점을 고려할 때, 가는 유사의 부유를 모의할 때에는 세심한 주의가 요구된다는 점을 이해할 수 있다. 선행 연구사례를 통해 볼 때 부유하는 입자의 관성력이 Schmidt 수의 결정과 이에 따른 연직 구조의 계산에 큰 영향을 준다는 점을 알 수 있다. 본 연구에서는 스토크스 수를 관성력을 나타낼 수 있는 지표로서 계산하였지만 보다 정량적이고 효율적인 입자 관성력 지표가 제시될 때 효율적인 연구결과의 제시가 이루어질 수 있을 것으로 기대한다.

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