• Proceedings of the Korean Vacuum Society Conference
• /
• 2014.02a
• /
• pp.92-92
• /
• 2014

Recently, many state-of-art spectroscopy techniques are used to unravel the mysteries of condensed matters. And numerous heterostructures have provided a new avenue to search for new emergent phenomena. Especially, near the interface, various forms of symmetry-breaking can appear, which induces many novel phenomena. Although these intriguing phenomena can be emerged at the interface, by using conventional measurement techniques, the experimental investigations have been limited due to the buried nature of interface. One of the ways to overcome this limitation is in situ investigation of the layer-by-layer evolution of the electronic structure with increasing of the thickness. Namely, with very thin layer, we can measure the electronic structure strongly affected by the interface effect, but with thick layer, the bulk property becomes strong. Angle-resolved photoemission spectroscopy (ARPES) is powerful tool to directly obtain electronic structure, and it is very surface sensitive. Thus, the layer-by-layer evolution of the electronic structure in oxide heterostructure can be investigated by using in situ ARPES. LaNiO3 (LNO) heterostructures have recently attracted much attention due to theoretical predictions for many intriguing quantum phenomena. The theories suggest that, by tuning external parameters such as misfit strain and dimensionality in LNO heterostructure, the latent orders, which is absent in bulk, including charge disproportionation, spin-density-wave order and Mott insulator, could be emerged in LNO heterostructure. Here, we performed in situ ARPES studies on LNO films with varying the misfit strain and thickness. (1) By using LaAlO3 (-1.3%), NdGaO3 (+0.3%), and SrTiO3 (+1.7%) substrates, we could obtain LNO films under compressive strain, nearly strain-free, and tensile strain, respectively. As strain state changes from compressive to tensile, the Ni eg bands are rearranged and cross the Fermi level, which induces a change of Fermi surface (FS) topology. Additionally, two different FS superstructures are observed depending on strain states, which are attributed to signatures of latent charge and spin orderings in LNO films. (2) We also deposited LNO ultrathin films under tensile strain with thickness between 1 and 10 unit-cells. We found that the Fermi surface nesting effect becomes strong in two-dimensions and significantly enhances spin-density-wave order. The further details are discussed more in presentation. This work was collaborated with Hyang Keun Yoo, Seung Ill Hyun, Eli Rotenberg, Ji Hoon Shim, Young Jun Chang and Hyeong-Do Kim.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.15 no.3
• /
• pp.125-133
• /
• 2011

The requirement for durability of concrete bridge deck is increasing as the deterioration for the concrete bridge deck exposed to severe environment has been increased. For this reason, the concern about high-durable concrete is being high. Recently, a metakaolin is highly spotlighted as new admixture because its strength and durability are equivalent to silica fume. On the other hands, there are few researches for the metakaolin concrete bridge deck in domestic. So many various long-term data on the mechanical property and durability is needed to apply metakaolin concrete at the concrete bridge deck construction field. This study is aim to evaluate the long-term mechanical properties and durability of metakaolin concrete bridge deck with curing age. Mechanical properties are estimated by the compressive and flexural strength, and the drying shrinkage, the chloride resistance, the scaling, and freezing and thawing characteristics are compared with curing age. According to the results, when the metakaolin concrete is used, the development of compressive and flexural strength proceed in both the early and old ages. It is also improved the resistance of chloride penetration, freezing and thawing in concrete. It was showed that replacement of metakaolin was efficient for the reduction of the drying shrinkage.

• Journal of the Korean Ceramic Society
• /
• v.40 no.10
• /
• pp.1005-1014
• /
• 2003

This paper examines the hydration and physical properties of alkali-blast furnace slag cement activated by Na$_2$SiO$_3$, Na$_2$CO$_3$, NaOH, Na$_2$SO$_4$. Four levels of Na$_2$O content in mixtures, 1, 3, 5, and 7 wt%, were investigated, and a W/S ratio 0.5 was used to prepare paste and mortar specimens. Compressive strength measurement of mortars was carried out adding alkali activated slag 30 wt% to OPC. The main hydration products with alkali activator kinds were C-S-H,C$_4$AH$\_$13/, AFt and Al(OH)$_3$ etc. For using Na$_2$CO$_3$ activated slag, hydration ratio of slag was higher than that of different activators, and Na$_2$SO$_4$ activated slag mortar appeared the highest compressive strength values at 28 days with activator content of 5 and 7 wt%.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.17 no.2
• /
• pp.101-109
• /
• 2013

Recently, it is certain that the increase of heating and cooling energy consumption by radical change in climate condition has caused serious problems related to environmental and energy concerns associated with increase of fossil fuel usage and carbon dioxide production as well as global warming. So, various actions to reduce greenhouse gas exhaustion and energy consumption have been prepared by world developed countries. Our government has also been trying to seek energy control methods for houses and buildings by proclaiming political polices on low-carbon green growth and construction and performance standards for environment-friendly housing. The energy consumption by buildings approximately reaches 25% of total korea energy consumption, and the increasing rate of energy consumption by buildings is stiffer than the rate by the other industries. The greatest part in the buildings of the energy consumption is building facade. While lots of research projects for reducing energy consumption of the facade have been conducted, but a few research projects on concrete comprising more than 70% of outsider of buildings has been tried. This research presents here a study to improve the insulation property of structural concrete formed by micro form admixture (MFA) with experimentally reviewing the physical, mechanical and thermal characteristics of the concrete. As the results of this experiment, in the case of concrete mixed with MFA, slump loss has been improved. As the mixing ratio of MFA increases, the compressive strength is decreased and thermal conductivity is increased. Also it was found that water-cement ratio increases, the compressive strength is decreased and thermal conductivity is increased. but, there was not big influence by the change of fine aggregate ratio.

• The Journal of Engineering Geology
• /
• v.14 no.1
• /
• pp.61-69
• /
• 2004

Building stones are used mainly as a material for making decoration and sculpture, and consequently they must have predominant physical properties extensively. Among various physical properties, the coefficient of pore dominates the usefulness of building stones, so the plans were made for establishing the quality classification of building stones with respect to the nature of pore. For this study, bore-hole core samples according to the depth of the biotite granites and the granitic gneiss were applicated. From the related chart between porosity and absorption ratio, Mungyeong granitic gneiss($Gn_1$) shows the widest phase of distribution in the range of measurement values, and the values decrease in the order of Pocheon granite($Gr_2$) and Mungyeong granite($Gr_1$) in the range. The strength of each rock mass varies with the degree of alteration. Also in correlation between compressive strength and tensile strength, the range of measurement values decrease in the order of $Gn_1$, $Gr_2$and $Gr_1$. Porosity is adopted as a representative physical property for establishing the quality classification of building stones, and then relative evaluation was made with regard to various physical properties. From the related chart between porosity(n)-specific gravity(G), absorption ratio(Ab), compressive strength(${\sigma}_{c}$), tensile strength(${\sigma}_{t}$), shore hardness(Hs) and Young's modulus($E_{t}$), standard of each grade is established.

• Journal of Navigation and Port Research
• /
• v.37 no.2
• /
• pp.165-171
• /
• 2013

YoungDo bridge is the first suspension bridge in Busan which experienced several times repair and reinforcement after completion in 1934. The bridge is under demolition for extension and restoration work since 2011. The purpose of this research is to establish data base about modern concrete. The mix design of the concrete is like that cement : fine aggregate : coarse aggregate = 1 : 2 : 4 or 1 : 3 : 6 by the parts. The compressive strength is in the ranges from 50 to 55 MPa and the elastic modulus is in the ranges from 25 to 35 GPa. From the fact that the deviation is less than 10 %, considerably high quality control was conducted in those days. The carbonation depth is 5.92 cm at the bridge post and 14.3 cm at the machine room. That is why ocean environment keeps the high humidity. The diffusion coefficient of chloride ion through the pores in concrete is 1.052e-12 $m^2/s$ from the regression analysis using the experiment data. The water cement ration is estimated at approximately 35 % in case if the concrete using ordinary Portland cement.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.20 no.1
• /
• pp.200-207
• /
• 2019

Cement is one of the most commonly used materials in the construction and civil engineering industry. However, emissions of carbon dioxide generated during the production of cement have been linked to climate change and environment pollutants. In order to replace cement, many studies have been actively performed research to utilizing Blast Furnace Slag(BFS), which is a byproduct of the steel industry. This study aims to investigate the physiochemical properties of the BFS powder based grout to determine whether it can be used as an environment-friendly grout material. As a fine powder, BSF can be used instead of cement grout due to its potential hydraulic property. BSF has also been known for its ability to strengthen materials long-term and to densify the internal structure of concrete. In order to investigate the physicochemical properties of the BFS powder based grout as a grout material, in this study assessment tests were performed through a gel-time measurement, uniaxial compressive strength, and chemical resistance tests, and heavy-metal leaching test. Characteristics and advantages of the slag were studied by comparing slag and cement in various methods.

• Journal of the Korean earth science society
• /
• v.40 no.1
• /
• pp.46-55
• /
• 2019

In this study, we investigated the stone materials used in the Woldae of Kwanghwamun gate to estimate their provenances. The Woldae was partly reconstructed in 2010 using red-colored original stone and greyish new stone. We carried out geological survey in Mt. Bukhan (Bukhansan) and Mt. Surak (Suraksan) to estimate the source of stone, where red-colored granitic rocks are widely distributed. Though the petrographical features of the granitic rocks from the surveyed area are quite similar, there exists a slight variation of magnetic susceptibility and color index of the rocks: the granitic rocks from Mt. Surak have higher value of magnetic susceptibility and clearer reddish feature. A series of evidence, such as historical records, stone cutting traces and petrographical features, for the source of stone materials used in the Woldae tells that Mt. Surak would have been the provenance for the stone materials used in the Woldae. We also conducted a nondestructive test to examine the physical property of the rocks. The original stone shows low compressive strength (147 MPa) due to the weathering, whereas the rock in Mt. Surak has higher compressive strength (244 MPa) capable of being used as building materials. If there were any difficulties to use the granitic rocks in Mt. Surak, some granitic rocks that have similar petrological characteristics, such as Changsu stone and Yeongjung stone from the Pocheon area, could be used as building material instead.

• Journal of the Korean Geotechnical Society
• /
• v.35 no.1
• /
• pp.31-42
• /
• 2019

About 3% of Casein is included in milk and it accounts for 80% of milk's protein. It has an adhesive property when mixed with calcium hydroxide and sodium hydroxide solutions. It has been usually used to bond woods under dry condition but becomes weak when exposed to moisture. Such weakness is very critical when casein is applied for soil cementation under groundwater condition. Therefore, this study was aimed to protect such weakness by changing or adding certain ingredients of casein adhesive. Two types of cemented specimens were prepared with Nakdong river sand and tested for unconfined compressive strength and durability. Each specimen was mixed with casein or cement. Ingredients of casein binder suggested by the University of Wisconsin, which is called a standard casein recipe, was also prepared. This study tried 6 different types of casein binder recipe. Among them, one with 30% hydroxide calcium increase and 50% hydroxide sodium decrease compared with the standard casein was most effective. Based on the most effective casein recipe, cemented sand with 1-4% of casein ratio was prepared and tested. The unconfined compressive strength and durability index were 6,253kPa and 92% for the specimen with 4% of casein ratio and 1,500kPa and 62% for the one with 8% of cement ratio. Therefore, casein cemented sand showed better performance. In addition, over 3% of casein cemented sand had over 80% durability index.

• Journal of Conservation Science
• /
• v.35 no.3
• /
• pp.227-235
• /
• 2019

In Korea, various methods are applied to prevent wooden structures from being damaged by termites. However, since there is no way to quickly bring toxic substances in contact with the termites inside the timber, it leads to the damage of wooden cultural property due to the prolonged period of controlling the termites. Accordingly, an indoor evaluation criteria study was conducted for the introduction of powder-type termiticides in Korea, which produced rapid control effects by drilling wood and directly contacting and transferring toxic substances inside the timber. First, contact toxicity and transfer ability of termite dusts were evaluated to establish the criteria for evaluation of effectiveness against Reticulitermes speratus. The contact toxicity confirmed 100% mortality of fipronil, deltamethrin and cyfluthrin termite dusts within 24 h of contact; however, differences occurred in the active ingredient transfer time to the sublethal. In addition, in the case of transfer ability evaluation, the rate of mortality gradually decreased under 1:9 and 1:25 ratio conditions; however, the difference in the reduction rate was identified depending on the type of termite dust. the results of the evaluation of compressive strength of the wood showed that the difference in the measured values between the control group and the conditions of perforation 1 to 3 times, which does not significantly affect the compressive strength of wood. In this study, the criteria of termite dust selection and evaluation method of dust-type termiticides were presented and the applicability of the method was identified.