• 제목/요약/키워드: Compressibility Factor

검색결과 56건 처리시간 0.031초

Accurate Determination of Hydrogen Adsorption on Metal Materials Considering the Equations of State and its Influential Errors

  • Cho, Won-Chul;Park, Chu-Sik;Han, Sang-Sup
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
    • /
    • pp.1229-1230
    • /
    • 2006
  • Adsorption isotherms of hydrogen by step-by-step method are widely used. However, the relations between the equations of state and the accumulated errors produced by step-by-step method and the mechanical errors of pressure or temperature controller were not analyzed. Considering the influence of various errors on the equations of state, we could find out the factors and compare the performance of the equations of state.

  • PDF

ESTIMATION OF CAKE FORMATION ON MICROFILTRATION MEMBRANE SURFACE USING ZETA POTENTIAL

  • Alayemieka, Erewari;Lee, Seock-Heon;Oh, Jeong-Ik
    • Environmental Engineering Research
    • /
    • 제11권4호
    • /
    • pp.201-207
    • /
    • 2006
  • A simple empirical model with good quantitative prediction of inter-particle and intra-particle distance in a cake layer with respect to ionic strength was developed. The model is an inverse length scale with functions of interaction energy and hydrodynamic factor and it explains that the inter-particle and intra-particle distance in a cake is directly related to the effective size of particles. Particle compressibility with respect to ionic strength was also predicted by the model. The model corroborated very well with experimental results of polystyrene microsphere latex particles microfiltation in a dead end operation. From the results of the model, specific cake resistance could be controlled by the same variables affecting the height of particle energy barrier described by the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory.

On the Critical Behavior of Phase Changes of a Forward-Scattered Light in a Nonpolar Binary Liquid Mixture

  • Kim, Kyoung-Ran;Kang, Young-Soo;Lee, Dong-J.
    • Bulletin of the Korean Chemical Society
    • /
    • 제23권12호
    • /
    • pp.1749-1753
    • /
    • 2002
  • The effect of concentration fluctuations on the changes of azimuth and ellipticity are analytically obtained in a binary chiral liquid mixture, when the incident light is completely linearly polarized above (or below) the horizontal at 45°. The important results are as follows;(1) When the binary liquid is in the critical region far from the cr5itical point, the ellipticity change is proportional to isothermal compressibility factor and the fifth order of frequency and shows the logarithmic divergence. (2) In the case that the system is in the critical region far from the critical point, the azimuth change is solely due to the molecular contribution. As the system approaches to the critical point, the effect of fluctuations becomes important. If it is in the extreme close to the critical point, the term due to the concentration fluctuations is comparable to or larger than the molecular contribution.

Halon-1301과 $CO_2$의 물성에 관한 실험식 (Empirical Equations for Physical Properties of Halon-1301 and $CO_2$)

  • 노경호;송명석;한순구;김재덕;이윤우
    • 한국화재소방학회논문지
    • /
    • 제16권2호
    • /
    • pp.51-58
    • /
    • 2002
  • 몬트리올 의정서에 의해서 규제받는 Halon-1301과 대체 물질중의 하나인 $CO_2$의 물성(밀도, 점도, 엔탈피)의 실험식을 구하였다. 문헌에서 얻은 실험값을 이용하여 온도에 대한 회귀분석에 의해서 실험식을 얻었다. 압축인자를 이용하여 온도에 대한 2차 함수로서 밀도에 관한 실험식을 제안하였다. 점도는 온도에 대한 지수함수로 표시되며, 보정인자를 사용하여 사용 온도범위를 확장하였다. 엔탈피는 열용량과 마찬가지로 온도에 대한 2차 함수로 정의하여 나타내었다. 본 연구에서 제안된 위의 실험식의 상관계수는 0.99 이상이었다.

전남 광양지역 연약지반의 피에조콘계수 산정 (Estimation of Soft Ground Piezocone Factors at Gwangyang, Jeonnam)

  • 오동춘;김기범;백승철
    • 한국지반환경공학회 논문집
    • /
    • 제20권2호
    • /
    • pp.59-67
    • /
    • 2019
  • 전남 남해안 지역인 광양항 동측배후단지 연약지반에서 수행한 실내시험, 현장베인시험 및 피에조콘 관입시험 결과를 이용하여 연약지반의 공학적 특성을 규명하고, 피에조콘계수 산정을 위해 최적의 피에조콘 관입시험 심도를 결정하였다. 본 논문에서 이용한 자료는 61개의 실내시험과 226회의 현장베인시험, 피에조콘 관입시험 26개소이다. 실내시험 분석 결과 남해안의 다른 지역에 비해 비중, 함수비, 액성한계 및 소성지수 등의 물리적 특성이 높게 나타나며, 일축압축강도와 비배수전단강도의 역학적 특성은 넓은 범위로 분포하고 비교적 작은 값을 나타냈다. 소성도에 의한 흙 분류 결과 소성이 큰 무기점토(CH)와 소성이 작은 무기점토(CL)로 분류되었으며, Robertson(1990) 분류도표에 의한 흙 분류 결과 대부분 Type 3인 점성토에 해당하였다. 현장베인시험으로 구한 비배수전단강도를 기준으로 경험적 방법에 의해 피에조콘계수를 산정했다. 이를 위해 현장베인시험 측정심도와 비교되는 피에조콘 관입시험의 적정 측정심도 범위를 설정하기 위해 3가지 심도범위로 상관성을 분석한 결과 베인 길이의 5배 범위 측정값의 평균을 사용하는 것이 높은 상관성을 보여준다.

실제기체 효과를 고려한 수소기체의 임계노즐 유동에 관한 연구 (Study on the Critical Nozzle Flow of Hydrogen Gas with Real Gas Effects)

  • 김재형;김희동
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2007년도 춘계학술대회B
    • /
    • pp.3003-3008
    • /
    • 2007
  • Critical nozzle has been frequently employed to measure the flow rate of various gases, but hydrogen gas, especially being at high-pressure condition, was not nearly dealt with the critical nozzle due to treatment danger. According to a few experimental data obtained recently, it was reported that the discharge coefficient of hydrogen gas through the critical nozzle exceeds unity in a specific range of Reynolds number. No detailed explanation on such an unreasonable value was made, but it was vaguely inferred as real gas effects. For the purpose of practical use of high-pressure hydrogen gas, systematic research is required to clarify the critical nozzle flow of high-pressure hydrogen gas. In the present study, a computational fluid dynamics(CFD) method has been applied to predict the critical nozzle flow of high-pressure hydrogen gas. Redlich-Kwong equation of state that take account for the forces and volume of molecules of hydrogen gas were incorporated into the axisymmetric, compressible Navier-Stokes equations. A fully implicit finite volume scheme was used to numerically solve the governing equations. The computational results were validated with some experimental data available. The results show that the coefficient of discharge coefficient is mainly influenced by the compressibility factor and the specific heat ratio, which appear more remarkable as the inlet total pressure of hydrogen gas increases.

  • PDF

불활성 기체 혼합물의 물성에 관한 열역학적 실험식 (Thermodynamic Empirical Equations for Physical Properties of Inert Gas Mixtures)

  • 김재덕;여미순;이윤우;노경호
    • 한국화재소방학회논문지
    • /
    • 제17권2호
    • /
    • pp.43-49
    • /
    • 2003
  • 대체 소화제로 사용되는 불활성 기체 중 Ar, $N_2$, $CO_2$에 대한 혼합물에서의 물성(포화압력, 밀도, 점도)에 관한 실험식을 구하였다. Mixing rule에 의해 계산한 값을 이용하여 다항식 등의 회귀분석에 의해서 실험식을 얻었다. 포화압력은 온도에 대하여 1차 실험식으로 표시하였다. 압축인자와 포화압력을 이용하여 온도에 대한 밀도에 관한 실험식을 제시하였다. 점도는 온도에 대한 지수함수로 표시하였다. Ar, $N_2$, $CO_2$혼합물의 조성이 40/50/10(mol. %)에서 열역학적 실험식을 구하였다.

외부가압 공기 베어링 지지 스핀들 시스템에서 직각도 오차가 운전 정밀도에 미치는 영향 (An Effect on the Running Accuracy of the Perpendicularity Error in the Spindle System Supported with Externally-Pressurized Air Bearing)

  • 고정석;김경웅
    • Tribology and Lubricants
    • /
    • 제15권3호
    • /
    • pp.257-264
    • /
    • 1999
  • Recently as electronics and semi-conductor industry develop, ultra-precision machine tools that use air-spindle with externally pressurized air bearing appear in need of ultra-precision products which demand high precision property. Effects of air compressibility absorbs the vibration of shaft, this is called averaging effect, however, the higher running accuracy is demanded by degrees, the more important factor is machining errors that affect running accuracy of shaft. Actually, it would be very important in the view points of running accuracy to understand effects of machining errors on the running accuracy of the spindle system quantitatively to design and manufacture precision spindle system in the aspect that efficiency in manufacturing spindle system and performance in operation. So fu, there are some researches on the effects that machining error affect running accuracy. However, because these researches deal with one bearing of spindle system, these results aren't enough to explain how much machining errors affect running accuracy in the typical spindle system overall. In this study, we investigate the effects of the perpendicularity error of bearing and shaft on running accuracy of spindle system that consists of journal and thrust bearing theoretically, and suggest design guideline about shape tolerances.

노치 영역에서 유체 관성을 고려한 압력 평형형 베인 펌프의 압력 상승에 관한 연구 (A Study on the pressure Rising Considered Fluid inertia in the Notch Area of Balanced Type Vane Pump)

  • 조명래;한동철;문호지;박민호;배홍용
    • Tribology and Lubricants
    • /
    • 제13권1호
    • /
    • pp.14-20
    • /
    • 1997
  • This paper reports on theoretical study of the pressure overshoot in the delivery ports and pressure rising within balanced type vane pump. Pressure overshoot occur due to the accelerated fluid through the notch, so, result in pressure ripple, flow ripple, and noise. For calculating the pressure rising and fluctuations of pressure, we have modeled mathematically used continuity equation based on compressibility and momentum equation considered fluid inertia in the notch, and analyzed simultaneously. As a results of analysis, we have found oscillation of pressure and compression chamber pressure depend on the rotational speeds, notches. Using the model, notches have been shown to be important design factor in relaxing the rapid pressure rising and reducing the amplitudes of pressure overshoot.

고압의 포화수증기-비응축성 수소기체 혼합기 속에서 분무수적으로의 열전달을 예측 (Prediction of Heat Transfer Rates to Spray Water Droplets in a High Pressure Mixture Composed of Saturated Steam and Noncondensable Hydrogen Gas)

  • 이상균;조종철;조진호
    • 설비공학논문집
    • /
    • 제3권5호
    • /
    • pp.337-349
    • /
    • 1991
  • Heat and mass transfer rates to spray water droplets for spray transients in a high pressure vessel have been predicted by two different droplet models: the complete mixing model and the non-mixing model. In this process, the ambient fluid surrounding the droplets is a real-gas mixture composed of saturated steam and noncondensable hydrogen gas at high pressure. The physical properties of the mixture are estimated by applying the concept of compressibility factor and using appropriate correlations. A computer program, DROPHMT, to calculate the heat and mass transfer rates for two different droplet models has been developed. As an illustrative application of the computer program to engineering practices, heat and mass transfer rates to spray water droplets for spray transients in a Pressurized Water Reactor (PWR) pressurizer have been calculated, and the typical results have been provided.

  • PDF