• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
• /
• pp.561-562
• /
• 2006

The effect of chemical composition of the sintering atmosphere on density, microstructure and mechanical properties of Fe-3%Mn-(Cr)-(Mo)-0.3%C steels is described. Pre-alloyed Astaloy CrM and CrL, ferromanganese and graphite were used as the starting powders. Following pressing in a rigid die, compacts were sintered at 1120 and $1250^{\circ}C$ in atmospheres having different $H_2/N_2$ ratio and furnace cooled to room temperature. It has been found that the atmosphere composition has negligible effect on the as-sintered properties of the investigated materials.

• Journal of Ginseng Research
• /
• 제22권2호
• /
• pp.73-81
• /
• 1998

In order to stabilize the price of fresh ginseng by extension of seasonal variation and marketing structure, and to reduce the cost of production by works of intensive and short term, studies were carried out. As fresh ginseng of 4 years old by the MA (modified atmosphere storage) and CA (controlled atmosphere storage) was stored for 12 week at 4$^{\circ}C$, samples were collected after every 1, 2, 3, 4, 6, 8, 12 weeks for processing red ginseng. Chemical characteristics on ginseng steamed red for the quality evaluation are summarized as follows. The composition of free sugar was consisted of fructose, glucose, sucrose, and maltose in fresh ginseng. And small change was revealed in free sugar composition during the storage period. Glucose and sucrose were largely increased in both treatments of MA (modified atmosphere storage) and CA (controlled atmosphere storage) after 4 week, wherein maltose was decreased. Fifteen different amino acids were identified, and total amount of histamine and arginine were over 40%. Phenylalanine was slightly decreased. As the volatile components in control red ginseng, six different ones including triisopropyl benzene were detected. B-1 ($CO_2$ : $O_2$ : N2=6 : 4.90, DF-100) of CA and E-1 (CPP, DF-100) of MA did not shown triisopropyl benzene as the volatile components. And ${\gamma}$-muurolene, guaiaene, and beta-patchoulene were reduced, but the other components showed the trend of increase.

• 한국세라믹학회지
• /
• 제37권7호
• /
• pp.645-650
• /
• 2000

Effects of the chemical composition and sintering atmosphere on the formation of reaction phases and physical properties of reactive hot-pressed TiB2-AlN-BN composites were investigated. At N2 atmosphere, TiN was formed by the reaction between Ti and N2, which inhibited the densification and results in inferior mechanical-and electrical properties of the composites. However, at Ar atmosphere, enhanced densification and physical properties of composites were obtained due to that the TiN formation reaction was excluded. Densification of the composites was also hindered by BN, therefore, inferior mechanical-and electrical properties of composites were obtained with amount of BN in the starting materials. At Ar atmosphere, TiB2-AlN-BN composites having 318 MPa of flexural strength, 3.5 MPa.m1/2 of fracture toughness and 276$\mu$Ω.cm of electrical resistivity were fabricated from mole ratio 1:2:1.6 of Ti-Al-BN mixtures.

• 한국세라믹학회지
• /
• 제26권1호
• /
• pp.31-36
• /
• 1989

In order to synthesize AlN-polytypes from AlN-SiO2-Al2O3 system, composition A (AlN/SiO2/Al2O3=1/0.3/0.05, mole ratio) and composition B(AlN-SiO2-Al2O3=1/0.2/0.05, mole ratio) were used. AlN-polytypes were produced by nitriding the mixture at 175$0^{\circ}C$~190$0^{\circ}C$ under N2 atmosphere. For lower reaction temperature, 15R phase was produced and in the case of higher reaction temperature, AlN phase was only produced. As each composition was heated at 185$0^{\circ}C$ in N2 atmosphere, produced main phases were 15R phase for composition A and 21R phase for composition B respectively. The fracture surfaces of produced reactants showed porous skeleton structure.

• 대한화학회지
• /
• 제62권4호
• /
• pp.288-298
• /
• 2018

이 연구에서는 과학교사 11명을 대상으로 서로 다른 질량을 가진 분자들로 이루어진 대기의 균질권에 대한 사고를 알아보기 위하여 사전 사후 검사지를 개발하고 조사하였다. 사전 검사 결과, 교사들은 크게 2가지 유형의 사고로 분류되었으며, 대기를 균일 용액처럼 생각하여 조성비가 균일하다는 사고와 입자의 질량이 다름을 고려하여 대기의 조성비가 비균질하다는 사고가 나타났다. 각각의 사고는 다시 중력의 크기를 크게 고려한 경우와 작게 고려한 경우, 그 중간 정도로 고려한 경우 등 3가지 유형으로 재분류 되어서 총 6가지 유형의 사고를 찾아볼 수 있었다. 이러한 다양한 사전 개념을 제시하고 교사들에게 학문간 교차개념의 중요성을 소개한 후에 화학에서의 원자량과 온도에 따른 분자 운동, 공기라는 용액의 균질성, 물리에서 다루는 질량과 중력, 그리고 거리의 관계, 지구과학에서 다루는 대기의 분포 및 대류 현상 등의 개념을 연계하여 사고하도록 제안하였다. 교사들 간의 토론 후에 사후 개념을 조사한 결과 사전 개념에서 벗어나 중력, 질량, 온도, 고도 등을 고려하여 대기의 조성에 대한 통합적 시각을 가지는 사고로 변화하였다. 이러한 변화를 통해 다양한 학문에서 다루는 교차개념의 중요성에 대해 확인할 수 있었으며, 통합과학에서 앞으로 이러한 유형의 사고를 교사들이 학생들에게 제공함으로써 일관된 세계관을 형성하고 지적 도구로 탐구적 사고를 실행할 수 있도록 도울 필요가 있다고 이 연구에서는 제안하였다.

• 한국세라믹학회지
• /
• 제15권2호
• /
• pp.85-88
• /
• 1978

Influence of cooling atmosphere on the whiteness in white portland cement was studied. The effective composition of gaseous medium of cooling atmosphere is desirable less than 0.5% of $O_2$ and 0.5~1.5% of CO. When theclinker is quenched in nitrogen atmosphere, the color of clinker becomes bright pink. In a weakly reducing gaseous medium or vacuum, the absence of oxygen brings defects in crystal and transformation in the coordination of iron, and as a result, whiteness is raised.

• 한국세라믹학회지
• /
• 제26권3호
• /
• pp.402-408
• /
• 1989

$\beta$-Sialon powder was synthesized by the simultaneous reduction and nitridation of the mixed powder of Hadong kaolin and Kimcheon quartzite, using graphite as a reducing agent. The synthesized $\beta$-Sialon powder (Z=1) was hot-pressed at 175$0^{\circ}C$, for 90min under 30MPa in N2 atmosphere, after Yttria and YAG composition material were added as sintering agents. The effects of grain-boundary crystallization on high-temperature mechanical properties of $\beta$-Sialon ceramics were investigated. Strength degradation was observed at above 1,00$0^{\circ}C$ for the $\beta$-Sialon (Z=1)-8wt% Y2O3 composition, but it was not observed up to 1,20$0^{\circ}C$ for the $\beta$-Sialon-8wt% YAG composition which was annealed at 1,40$0^{\circ}C$ for 4 hours in N2 atmosphere. After the $\beta$-Sialon-8wt% YAG composition was annealed, the decrease of fracture toughness was observed.

• 한국세라믹학회지
• /
• 제31권1호
• /
• pp.39-46
• /
• 1994

LiTaO3 single crystals were growth without cracking using Pt-Rh crucible and Ir crucible. The starting composition to get the melt of congruent melting composition, which has been dependent upon the experimental procedure, was taken after fixing the total growing process by the result of preliminary experiments. The Rh contamination from the Pt-Rh crucible was to be neglected if the crystal had been grown under inert atmosphere, which resulted in the crystal color being slightly yellow. This color was decolored after 24 hour's annealing at 1200℃ under air atmosphere. The optimum conditions for the crystal growing and the diameter control were so dependent upon the crucible material in spite of using the crucible of the same size. The liquid-solid interface of LiTaO3 crystal of 1" diameter has been flat if the rotation speed was 45rpm.

• Journal of Advanced Marine Engineering and Technology
• /
• 제30권8호
• /
• pp.853-862
• /
• 2006

The present study is numerically investigated the flame structure of non-premixed counterflow jet flames using the laminar flamelet model Detailed flame structures with the fuel composition of 40% CO, 30% $H_2$. 30% $N_2$ and an oxidizer composition of 79% $N_2$ and 21% $O_2$ in a non-premixed counterflow flame are studied numerically. This study is aimed to investigate the effects of axial velocity gradient and combustion atmosphere pressure on flame structure. The results show that the role of axial velocity gradient on combustion processes is globally opposite to that of combustion atmosphere pressure. That is, chemical nonequilibrium effects become dominant with increasing axial velocity gradient, but are suppressed with increasing ambient pressure. Also, the flame strength is globally weakened by the increase of axial velocity gradient but is augmented by the increase of ambient pressure. However, flame extinction is described better on the basis of only chemical reaction and in this study axial velocity gradient and ambient pressure play a similar role conceptually such that the increase of axial velocity gradient and ambient pressure cause flame not to be extinguished and extend the extinction limit, respectively. Consequently it is suggested that a combustion process like flame extinction is mainly influenced by the competition between the radical formation reaction and the third-body recombination reaction.

• 한국세라믹학회지
• /
• 제26권5호
• /
• pp.637-644
• /
• 1989

Beta-sialon powder(Z=1) was synthesized by the simultaeous reduction and nitridation of the mixed powders of Hadong kaolin and silica. Silicon hydroxide was prepared from Si-alkoxide by a hydrolysis method and amorphous silica was obtained from the calcination of the prepared silicon hydroxide. Hadong kaolin was mixed with both the silicon hydroxide and amorphous silica, respectively. The average particle size was 4${\mu}{\textrm}{m}$ and the morphology of particle was rod-like and equiaxed in the case of beta-sialon powder prepared form Hadong kaolin and silicon hydroxide(COMPOSITION A), whereas the average particle size was 3${\mu}{\textrm}{m}$ and the morphology of particle was equiaxed in the case of beta-sialon powder prepared from Hadong kaolin and amorphous silica(COMPOSITION B). The synthesized beta-sialon powders were hot-pressed at 175$0^{\circ}C$ for 2 hours under 30 MPa in a nitrogen atmosphere after YAG composition(8wt%) was added to these powders as a sintering agent. The hot-pressed specimens were annealed a 140$0^{\circ}C$ for 4 hours in a nitrogen atmosphere. The mechanical properties of sintered bodies were investigated in terms of M.O.R., fracture toughness and hardness. The measured values are as follows. COMPOSITION A : M.O.R. 508MPa, KIC 3.5MN/m3/2, hardness 13.6GPa. COMPOSITION B : M.O.R. 653MPa, KIC 5.4MN/m3/2, hardness 13.5GPa.