• Composites Research
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• v.26 no.3
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• pp.160-164
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• 2013

In this study, the effect of phosphoric acid (PA) as a fiber spinning aid on the strength increase of polyacrylonitrile (PAN) nano-fibers by using modified mechano-electrospinning technologies has been analyzed. The medium carbonization temperature of $800^{\circ}C$ has been selected for the future economic production of these new materials. The concentration of PAN in dimethyl sulfoxide (DMSO) was fixed as 5 wt%. The weight fraction of PA was selected as being 2%, 4%, 6%, and 8% in comparison to PAN. These solutions have been used to make the nanofibers. The mechano-electrospinning apparatus installed in KRICT was made by our own design. By using this apparatus the continous and highly aligned precursor nano-fibers have been obtained. The bundle of 50 well aligned nano diameter continuous fibers with the diametr of 10 microns with 6 wt% phosphoric acid for addition showed maximum mechanical properties of 1.6 GPa as tensile strength and 300 GPa as Young's modulus. The weight of final product can be increased 19%, which can improve the economical benefits for the application of these new materials.

• Journal of the Korean Ceramic Society
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• v.55 no.5
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• pp.461-472
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• 2018

$Gd_2O_3:Eu/Bi$ nanoparticles were synthesized via spray pyrolysis and applied for the preparation of a luminescent pearl pigment as an anti-counterfeiting material. The luminescence properties were optimized by changing the $Eu^{3+}$ and $Bi^{3+}$ concentration. Ethylene glycol was used as an organic additive to prepare the $Gd_2O_3:Eu/Bi$ nanoparticles. The highest emission intensity was achieved when the total dopant content was 10.0 at.% and the mole fraction of Bi was 0.1. The concentration quenching was mainly due to dipole-dipole interactions between the same activators, and the critical distances were 9.0 and $19.6{\AA}$ for $Eu^{3+}$ and $Bi^{3+}$, respectively. The prepared $Gd_2O_3:Eu/Bi$ powder exhibited an average size of approximately 82.5 nm and a narrow size distribution. Finally, the $Gd_2O_3:Eu/Bi$ nanophosphor coated on the surface of the pearl pigment was confirmed to have good red emission under irradiation from a portable ultraviolet light-emitting diode lamp (365 nm).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.60-60
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• 2008

We manufactured Liquid Crystal Polymer (LCP) and (1-x)$BaTiO_3-xSrTiO_3$(BST) ceramic composites and investigated dielectric properties to use as embedded capacitor in printed circuit boards and replace LTCC substrates. The dielectric properties of these composites are varied with volume fraction of BST and ratios of BT/ST. Dielectric constants are in the range of 3~28. In addition, we could get low TCC and High Q value that could not achieve in other ceramic-polymer composites. Especially, in composite with x=0.4 and 50vol% BST, the dieletric constant and Q-value are 27 and 300, respectively. And more TCC is -116~145ppm/$^{\circ}C$ in the temperature range of -55~$125^{\circ}C$. We think that this composites can be used high-Q substrate material like LTCC and embedded temperature compensation capacitor in printed circuit boards.

• Steel and Composite Structures
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• v.20 no.1
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• pp.205-225
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• 2016

In this study the finite element method is utilized to predict the deflection and vibration characteristics of rectangular plates made of saturated porous functionally graded materials (PFGM) within the framework of the third order shear deformation plate theory. Material properties of PFGM plate are supposed to vary continuously along the thickness direction according to the power-law form and the porous plate is assumed of the form where pores are saturated with fluid. Various edge conditions of the plate are analyzed. The governing equations of motion are derived through energy method, using calculus of variations while the finite element model is derived based on the constitutive equation of the porous material. According to the numerical results, it is revealed that the proposed modeling and finite element approach can provide accurate deflection and frequency results of the PFGM plates as compared to the previously published results in literature. The detailed mathematical derivations are presented and numerical investigations are performed while the emphasis is placed on investigating the effect of the several parameters such as porosity volume fraction, material distribution profile, mode number and boundary conditions on the natural frequencies and deflection of the PFGM plates in detail. It is explicitly shown that the deflection and vibration behaviour of porous FGM plates are significantly influenced by these effects. Numerical results are presented to serve as benchmarks for future analyses of FGM plates with porosity phases.

• Steel and Composite Structures
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• v.22 no.3
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• pp.691-712
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• 2016

In this editorial, buckling analytical investigation of the nanocomposite plate with square cut out reinforced by carbon nanotubes (CNTs) surrounded by Pasternak foundation is considered. The plate is presumed has square cut out in center and resting on Pasternak foundation. CNTs are used as amplifier in plate for diverse distribution, such as uniform distribution (UD) and three patterns of functionally graded (FG) distribution types of CNTs (FG-X, FG-A and FG-O). Moreover, the effective mechanical properties of nanocomposite plate are calculated from the rule of mixture. Domain decomposition method and orthogonal polynomials are applied in order to define the shape function of nanocomposite plate with square cut out. Finally, Rayleigh-Ritz energy method is used to obtain critical buckling load of system. A detailed parametric study is conducted to explicit the effects of the dimensions of plate, length of square cut out, different distribution of CNTs, elastic medium and volume fraction of CNTs. It is found from results that increase the dimensions of plate and length of square cut out have negative impact on buckling behavior of system but considering CNTs in plate has positive influence.

• Steel and Composite Structures
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• v.17 no.2
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• pp.173-184
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• 2014

This study aimed to theoretical calculate the thermal residual stress in continuous SiC fiber reinforced titanium matrix composites. The analytical solution of residual stress field distribution was obtained by using coaxial cylinder model, and the numerical solution was obtained by using finite element model (FEM). Both of the above models were compared and the thermal residual stress was analyzed in the axial, hoop, radial direction. The results indicated that both the two models were feasible to theoretical calculate the thermal residual stress in continuous SiC fiber reinforced titanium matrix composites, because the deviations between the theoretical calculation results and the test results were less than 8%. In the titanium matrix composites, along with the increment of the SiC fiber volume fraction, the longitudinal property was improved, while the equivalent residual stress was not significantly changed, keeping the intensity around 600 MPa. There was a pronounced reduction of the radial residual stress in the titanium matrix composites when there was carbon coating on the surface of the SiC fiber, because carbon coating could effectively reduce the coefficient of thermal expansion mismatch between the fiber and the titanium matrix, meanwhile, the consumption of carbon coating could protect SiC fibers effectively, so as to ensure the high-performance of the composites. The support of design and optimization of composites was provided though theoretical calculation and analysis of residual stress.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.232-233
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• 2007

We manufactured Liquid Crystal Polymer (LCP) and (1-x)CaTiO3-xLaAlO3 (CT-LA) ceramic composites and investigated dielectric properties to use as embedded capacitor in printed circuit boards and replace LTCC substrate. The dielectric properties of these composites are varied with volume fraction of CT-LA and ratios of CT/LA. Dielectric constants are in the range of 3~15. In addition, we could get low TCC and High Q value that could not achieve in other ceramic-polymer composites. Especially, in composite with x=0.01 and 30 vol% CT-LA, the dieletric constant and Q-value are 10 and 200, respectively. And more TCC is $-28{\sim}300ppm/^{\circ}C$ in the temperature range of $-55{\sim}125^{\circ}C$. We think that this composites can be used high-Q substrate material like LTCC and embedded temperature compensation capacitor in printed circuit boards.

• Journal of the Korean Wood Science and Technology
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• v.45 no.2
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• pp.182-194
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• 2017

The optimum alkali pretreatment parameters (reaction time, reaction temperature and potassium hydroxide concentration) for facilitate the conversion into fermentable sugar (glucose) from steam exploded (severity log Ro 2.45) barley husk were determined using Response Surface Methodology (RSM) based on a factorial Central Composite Design (CCD). The prediction of the response was carried out by a second-order polynomial model and regression analysis revealed that more than 88% of the variation can be explained by the models. The optimum conditions for maximum cellulose content were determined to be 201 min reaction time, $124^{\circ}C$ reaction temperature and 0.9% potassium hydroxide concentration. This data shows that the actual value obtained was similar to the predicted value calculated from the model. The pretreated barley husk using acid hydrolysis resulted in a glucose conversion of 94.6%. This research of steam explosion and alkali pretreatment was a promising method to improve cellulose-rich residue for lignocellulosic biomass.

• Structural Engineering and Mechanics
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• v.67 no.2
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• pp.115-123
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• 2018

By using the first order shear deformation plate theory (FSDT) in the present paper, the effect of porosity on the buckling behavior of carbon nanotube-reinforced composite porous plates has been investigated analytically. Two types of distributions of uniaxially aligned reinforcement material are utilized which uniformly (UD-CNT) and functionally graded (FG-CNT) of plates. The analytical equations of the model are derived and the exact solutions for critical buckling load of such type's plates are obtained. The convergence of the method is demonstrated and the present solutions are numerically validated by comparison with some available solutions in the literature. The central thesis studied and discussed in this paper is the Influence of Various parameters on the buckling of carbon nanotube-reinforced porous plate such as aspect ratios, volume fraction, types of reinforcement, the degree of porosity and plate thickness. On the question of porosity, this study found that there is a great influence of their variation on the critical buckling load. It is revealed that the critical buckling load decreases as increasing coefficients of porosity.

• Steel and Composite Structures
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• v.34 no.2
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• pp.227-239
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• 2020

The aim of this study is to obtain the nonlinear and post-buckling responses of relatively thick functionally graded plates with oblique elliptical cutouts using a new semi-analytical approach. To model the oblique elliptical hole in a FGM plate, six plate-elements are used and the connection between these elements is provided by the well-known Penalty method. Therefore, the semi-analytical technique used in this paper is known as the plate assembly technique. In order to take into account for functionality of the material in a perforated plate, the volume fraction of the material constituents follows a simple power law distribution. Since the FGM perforated plates are relatively thick in this research, the structural model is assumed to be the first order shear deformation theory and Von-Karman's assumptions are used to incorporate geometric nonlinearity. The equilibrium equations for FGM plates containing elliptical holes are obtained by the principle of minimum of total potential energy. The obtained nonlinear equilibrium equations are solved numerically using the quadratic extrapolation technique. Various sets of boundary conditions for FGM plates and different cutout sizes and orientations are assumed here and their effects on nonlinear response of plates under compressive loads are examined.