• 한국표면공학회지
• /
• 제43권6호
• /
• pp.283-288
• /
• 2010

Ni-$TiO_2$ nano composite coatings were fabricated using pulse current electrodeposition technique at 100 Hz pulse frequency with a constant 50% pulse duty cycles and reference was taken with respect to the direct current (dc) electrodeposition. The properties of the composite coatings were investigated by using SEM, XRD, Wear test and Vicker's microhardness test. Pulse electrodeposited composite has exhibited enhancement of (111), (220), and (311) diffraction lines with an attenuation of (200) line. The results demonstrated that the microhardness of composite coatings under pulse condition was significantly improved than that of pure nickel coating as well as dc electrodeposited Ni-$TiO_2$ composite coatings. Wear tracks have shown the less plastic deformation in pulse plated composite. Coefficient of friction was also found to be lower in pulse plated composite coatings as compared to dc plated composite coatings.

• 한국재료학회지
• /
• 제20권8호
• /
• pp.439-443
• /
• 2010

Nano sized SiC particles (270 nm) are easily agglomerated in nickel sulfamate electrolytic bath during a composite electrodeposition process. The agglomeration of nano particles in composite coatings can significantly reduce the mechanical properties of the composite coatings. In this study, Ni-SiC nano composite coatings were fabricated using a conventional electrodeposition process with the aid of ultrasound. Nano particles were found to be distributed homogeneously with reduced agglomeration in the ultrasonicated samples. Substantial improvements in mechanical properties were observed in the composite coatings prepared in presence of ultrasound over those without ultrasound. Ni-SiC composite coatings were prepared with variable ultrasonic frequencies ranging from 24 kHz to 78 kHz and ultrasonic powers up to 300 watts. The ultrasonic frequency of 38 kHz with ultrasonic power of 200 watt was revealed to be the best ultrasonic conditions for homogeneous dispersion of nano SiC particles with improved mechanical properties in the composite coatings. The microstructures, phase compositions, and mechanical properties of the composite coatings were observed and evaluated using SEM, XRD, Vickers microhardness, and wear test. The Vickers microhardness of composite coatings under ultrasonic condition was significantly improved as compared to the coatings without ultrasound. The friction coefficient of the composite coating prepared with an ultrasonic condition was also smaller than the pure nickel coatings. A synergistic combination of superior wear resistance and improved microhardness was found in the Ni-SiC composite coatings prepared with ultrasonic conditions.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
• /
• pp.153-153
• /
• 2011

Ni $TiO_2$ nano composite coatings were fabricated by using pulse current electrodeposition technique at 100 Hz pulse frequency with a constant 50% pulse duty cycles and reference was taken with respect to the direct current electrodeposition. The properties of the composite coatings were investigated by using SEM, XRD, Wear test and Vicker's microhardness test. XRD patterns of pulse deposited composite coatings were found to be changed from preferred (100) orientation to the random mixed orientations. The results demonstrated that the Vickers microhardness of composite coatings under pulse condition was significantly improved than that of pure nickel coating as well as direct current electrodeposited Ni-$TiO_2$ composite coatings. Wear tracks have shown the less plastic deformation at pulse condition with reduced coefficient of friction. Nickel matrix grain size was also found to be lower in pulse plated composite coatings as compared to direct current electrodeposited composite coatings.

• Journal of Welding and Joining
• /
• 제26권5호
• /
• pp.36-42
• /
• 2008

Carbon nanotube (CNT) aluminum composite coatings were built up through kinetic spraying process. Deposition behavior of CNT aluminum composite on an aluminum 1050 alloy substrate was analyzed based on deposition mechanism of kinetic spraying. The microstructure of CNT aluminum composite coating were observed and analyzed. Also, the electrical resistivity, bond strength and micro-hardness of the CNT aluminum composite coatings were measured and compared to kinetic sprayed aluminum coatings. The CNT aluminum composite coatings have a dense structure with low porosity. Compared to kinetic sprayed aluminum coating, the CNT aluminum composite coatings present lower electrical resistivity and higher micro-hardness due to high electrical conductivity and dispersion hardening effects of CNTs.

• 한국표면공학회지
• /
• 제43권5호
• /
• pp.224-229
• /
• 2010

$Ni-Si_3N_4$ nano-composite coatings were prepared by pulse current (PC) electrodeposition and direct current (DC) electrodeposition techniques. The micro-structure of the coatings was characterized by scanning electron microscopy (SEM), vickers microhardness, X-Ray Diffraction (XRD) and wear-friction tests. The results showed that the micro-structure and wear performance of the coatings were affected by the electrodeposition techniques. Pulse current electrodeposited $Ni-Si_3N_4$ composite coatings exhibited higher microhardness, smooth surface, and better wear resistance properties as compared to coatings prepared under DC condition. The $Ni-Si_3N_4$ composite coatings prepared at 50 Hz pulse frequency with 10% duty cycles has shown higher codeposition of nano-particles. Consequently, increased microhardness and less plastic deformations occurred in coatings during sliding wear test. The XRD patterns revealed that the increased pulse frequencies changed the preferred (100) nickel crystallite orientations into mixed (111) and (100) orientations.

• 한국표면공학회지
• /
• 제44권3호
• /
• pp.89-94
• /
• 2011

In this study, the photocurrent characteristics of plasma sprayed $TiO_2$ coatings have been investigated according to additive transition metal (Fe, Mn, Nb powder) and heat treatment conditions. The plasma sprayed $TiO_2$ coatings by heat treatment at $400^{\circ}C$ and 90 min had the higher photocurrent at ultraviolet light, no photocurrent at visible light. The photocurrent of plasma sprayed $TiO_2$ coatings added by Fe, Mn, Nb (named by plasma sprayed $TiO_2$ composite coatings) was lower than that of plasma sprayed $TiO_2$ coatings at ultraviolet light, as was low in intensity ratio of XRD(101)/(110). and the atomic percentage of oxygen by plasma sprayed $TiO_2$ composite coatings was higher than that by plasma sprayed $TiO_2$ coatings. The photocurrent of plasma sprayed $TiO_2$ composite coatings in heat treatment at $400^{\circ}C$ and 90 min was higher than that of plasma sprayed $TiO_2$ coatings in same heat treatment conditions at ultraviolet and visible light, as was high in oxygen affinity by heat treatment.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2010년도 춘계학술발표대회
• /
• pp.26.1-26.1
• /
• 2010

Ni-SiC nano composite coatings were fabricated using electrodeposition technique with the aid of ultrasound. The properties of the nano composite were investigated by using SEM, XRD, Wear test and Vicker's microhardness test. The results demonstrated that the microhardness of composite coatings under ultrasonic condition was improved significantly as compared to conventional electrodeposition techniques without ultrasound. The nano particles were found to be distributed homogeneously with reduced agglomeration. The synergistic combination of superior wear resistance and improved microhardness was found in ultrasonicated conditions to the Ni-SiC nano composite coatings.

• 한국표면공학회지
• /
• 제52권3호
• /
• pp.156-162
• /
• 2019

Electroless Ni-P coatings are widely used in the chemical, mechanical, and electronic industries because of their excellent wear and abrasion resistance. In this study, The influence of pH values on properties of Ni-P-PTFE composite coatings was investigated. To improve mold lubrication, Ni-P-PTFE composite coatings at different pH value were studied. The morphology and phase structure of Ni-P-PTFE composite coatings were analyzed by scanning electron microscopy(SEM) and X-ray diffractometry(XRD). The result showed that Ni-P-PTFE composite coating is composed of Ni, P and PTFE. It exhibits an amorphous structure and good Corrosion Resistance to the substrate. Ni-P-PTFE composite coatings have higher open circuit potential than that of the substrate, which obtained at pH value of 5.0 optimal integrated properties.

• Tribology and Lubricants
• /
• 제12권3호
• /
• pp.33-38
• /
• 1996

High temperature wear behaviors of plasma-sprayed ZrO$_{2}$-$Y_{2}O_{3}$ composite coatings were investigated for high temperature wear resistance applications. The composite powders containing 20, 50, 80 vol% of alumina for plasma spray were made by spray drying method. Wear tests with composite coated specimens were performed at temperature ranges from room temperature to 800$^{\circ}$C. Wear tests were also carried out with heat treated specimens at room temperature. The microstructural change of coatings and the worn surface were examined by SEM and XRD. Sharp increase of wear loss at high temperature wear test was observed in specimens containing 50 and 80 vol% alumina. Similar trend was observed in the heat treated coatings. The measured residual stress was increased with increased alumina contents and heat treating temperatures. Residual stress induced during heat treatment appeared to be responsible to the observed harmful effect of alumina additions on the high temperature wear.

• 한국표면공학회지
• /
• 제43권4호
• /
• pp.165-169
• /
• 2010

$Ni-Al_2O_3$ nanocomposite coatings were fabricated by conventional electrodeposition technique using nickel sulfamate bath. Effect of plating parameters on electrodeposition of $Ni-Al_2O_3$ nanocomposite were studied. The properties of the nano composite were investigated by using SEM, XRD, and Vicker's microhardness test. The results demonstrated that $Al_2O_3$ incorporation in the composite coatings was found to be increased by increasing stir rate and $Al_2O_3$ content in plating bath. Microhardness of the composite coatings was also increased with increasing content of the nano particles in the plating bath. The surface morphologies of the nanocomposite coatings were found to be varied with varying pH, current densities as well as alumina content in the plating bath.