• Title/Summary/Keyword: Composite Material

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The Effect of Glass Fabric Separator Elongation on Electric Property in Structural Battery (유리섬유 분리막 인장으로 인한 구조전지의 전기적 물성 변화)

  • Shin, Jae-Sung;Park, Hyun-Wook;Park, Mi-Young;Kim, Chun-Gon;Kim, Soo-Hyun
    • Composites Research
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    • v.30 no.1
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    • pp.46-51
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    • 2017
  • Structural battery has been researched extensively to combine the functions of the battery and structure without gravimetric or volumetric increments compared to their individual components. The main idea is to employ carbon fabric as the reinforcement and electrode, glass fabric as the separator, and solid-state electrolyte which can transfer load. However, state-of-the-art solid-state electrolytes do not have sufficient load carrying functionality and exhibiting appropriate ion conductivity simultaneously. Therefore, in this research, a system which has both battery and load carrying capabilities using glass fabric separator and liquid electrolyte was devised and tested to investigate the potential and feasibility of this structural battery system and observe electric properties. It was observed that elongating separator decreased electrical behavior stability. A possible cause of this phenomenon was the elongated glass fabric separator inadequately preventing the penetration of small particles of the cathode material into the anode. This problem was verified additionally by using a commercial separator. The characteristic of the glass fabric and the interface between the electrode and glass fabric needed to be further studied for the realization of such a load carrying structural battery system.

Toughness of Polyurethane-Modified Unsaturated Polyester Resin (폴리우레탄으로 개질한 불포화 폴리에스테르 수지의 강인성)

  • Hwang, Yeong-Geun;Min, Kyung-Eun;Choi, Gwan-Young;Kim, Woo-Sik;Lee, Dong-Ho;Park, Lee-Soon;Seo, Kwan-Ho;Kang, Inn-Kyu;Jun, Il-Ryun
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.71-77
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    • 2001
  • Unsaturated polyester(UP) resin is one of the major thermosetting resins. It is very useful as the matrix resin of the composite material because of its low viscosity. The polymer resin, however, has several drawbacks; The volume shrinkage occurs during the crosslinking reaction of the UP resin with styrene monomer and the resulting polymer is weak to the alkali and also brittle. The mechanical properties of UP resin can be improved by blending various materials. In this study, polyurethane(PU) was used as a modifier in order to enhance the toughness of the UP resin. The goal of the research is to study the effect of the polyol molecular weight as a PU soft segment and the PU contents on the toughness of PU-modified UP resins. UP/PU polymer network may occur through the reaction between isocyanate group in the methyldiisocyanate(MDI) and hydroxyl group in the UP molecules. The maximum toughness value was shown at 2 wt% of the PU content. This effect results from the incorporation of the PU segment into the UP resin.

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Field Application of 80MPa High Strength Fire Resistant Concrete using Ternary Blended Cement (설계강도 80MPa 3성분계 고강도내화콘크리트의 현장적용 및 성과분석)

  • Kim, Seong-Deok;Kim, Sang-Yun;Bae, Ki-Sun;Park, Su-Hee;Lee, Bum-Sik
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.5
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    • pp.113-119
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    • 2010
  • Fire resistance and field tests for high-strength concrete(HSC) of 80MPa were carried out to evaluate whether or not it shows the same material properties even in the field condition of being mass-produced and supplied. As a result, it was found that fire resistant HSCs containing composite fiber(NY, PP) of 0.075% have great resistance to fire and spalling. In the field test, before the pumping air contents, slump flow, U-box, L-flow, compressive strength, gap of hydration temperature of interior and exterior of specimen and placing ratio per hour satisfied the required properties of HSC. However, after the pumping of HSC, as slump flow and L-flow were slightly less than required criterion, they need to be improved. In terms of hydration temperature of HSC, it was found to satisfy the related criterion. Packing ability as well as placing ratio per hour of HSC, which was about $44m^3$, show outstanding results. If slump flow of developed ternary HSC is improved after the pumping it can be useful for the construction of high-rise buildings.

Fundamental Properties of Magnesia-Prosphate Composite Considering Mix Conditions and Curing Temperature (배합조건 및 양생온도에 따른 마그네시아 인산염 복합체의 기초물성 평가)

  • Cho, Hyun Woo;Kang, Su Tae;Shin, Hyun Seop;Lee, Jang Hwa
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.6
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    • pp.163-170
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    • 2012
  • With the advantage of a rapid exothermic reaction property, jet set concrete may be used as a cold weather concrete because it can reach the required strength before being damaged by cold weathers. And it can be hardened more quickly if the field temperature is properly compensated by heating. Because ordinary concrete cannot be hardened well under sub-zero temperatures, anti-freeze agents are typically added to prevent the frost damage and to ensure the proper hardening of concrete. While the addition of a large amount of anti-freeze agent is effective to prevent concrete from freezing and accelerates cement hydration resulting in shortening the setting time and enhancing the initial strength, it induces problems in long-term strength growth. Also, it is not economically feasible because most anti-freeze agents are mainly composed of chlorides. Recent studies reported that magnesia-phosphate composites can be hardened very quickly and hydrated even in low temperatures, which can be used as an alternative of cold weather concrete for cold weathers and very cold places. As a preliminary study, to obtain the material properties, mortar specimens with different mixture proportions of magnesia-phosphate composites were manufactured and series of experiments were conducted varying the curing temperature. From the experimental results, an appropriate mixture design for cold weathers and very cold places is suggested.

A Study on the Compression Moldablity for Continuous Fiber-Reinforced Polymeric Composites ―Part 1 : The Mechanical Propertis and the Cup-type Compression Moldability for Numbers of Needling― (연속섬유강화 플라스틱 복합재료의 압축성형에 관한 연구 -제I보 : 니들펀칭횟수에 따른 물성치 및 컵형 압축성형성-)

  • 오영준;김형철;김이곤
    • Composites Research
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    • v.12 no.5
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    • pp.31-39
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    • 1999
  • Glass-fiber reinforced polymeric composites provide the desitable properties of high stiffness and strength as well as specific weight. Hence, they have become some of the most important materials in several industries. These composites can be grouped into thermoplastic and thermoset composites, with thermoplastic composites having several advantages over thermoset composites in mechanical properties and processing. As a result, the study of the material behavior and forming techniques of such composites has attracted considerable attention in recent years. When the continuous fiber-reinforced polymeric composites are molded by flow molding, the molded parts leads to be nonhomogeneity and anisotropic because of the separation and orientation of fibers. As the characteristics of the products are greatly dependent on the separation, it is very important to clarify the separation in relarion to molding conditions, fiber mat structures and mold geometry. In this study, the effects of the mold geometry and the fiber mat structure on the compression moldability are studied using the cup-type molding.

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Finite Element Analysis of Instrumented Posterior Lumbar Interbody Fusion Cages for Reducing Stress Shielding Effects: Comparison of the CFRP cage and Titanium cage (요추유합술에서 응력방패 현상 감소를 위한 케이지의 유한요소해석 : CFRP 케이지와 티타늄 케이지 비교 연구)

  • Kang, Kyung-Tak;Chun, Heoung-Jae;Kim, Ho-Joong;Yeom, Jin-S.;Park, Kyoung-Mi;Hwang, In-Han;Lee, Kwang-Ill
    • Composites Research
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    • v.25 no.4
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    • pp.98-104
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    • 2012
  • In recent years, degenerative spinal instability has been effectively treated with a cage. However, little attention is focused on the stiffness of the cage. Recent advances in the medical implant industry have resulted in the use of medical carbon fiber reinforced polymer (CFRP) cages. The biomechanical advantages of using different cage material in terms of stability and stresses in bone graft are not fully understood. A previously validated three-dimensional, nonlinear finite element model of an intact L2-L5 segment was modified to simulate posterior interbody fusion cages made of CFRP and titanium at the L4-L5 disc with pedicle screw, to investigate the effect of cage stiffness on the biomechanics of the fused segment in the lumbar region. From the results, it could be found that the use of a CFRP cage would not only reduce stress shielding, but it might also have led to increased bony fusion.

Effect of Epoxy Mixed with Nafion Solution as an Anode Binder on the Performance of Microbial Fuel Cell (산화전극 결합제로서 나피온용액에 혼합된 에폭시가 미생물연료전지의 성능에 미치는 영향)

  • Song, Young-Chae;Kim, Dae-Seop;Woo, Jung-Hui
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.1
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    • pp.1-6
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    • 2014
  • The composite anodes of exfoliated graphite (EG) and multiwall carbon nanotube (MWCNT) were fabricated by using the binders with different content of epoxy in Nafion solution. The influence of the epoxy content in the anode binder on the performance of microbial fuel cell (MFC) was examined in a batch reactor. With the increase in the epoxy content in the anode binder, increase in physical binding force was observed, but at the same time an increase in the internal resistance of MFC was also observed. This was due to the increase in activation and ohmic resistance. For the anode binder without epoxy, the maximum power density was $1,892mW/m^2$, but a decrease in maximum power density was observed with the increase in the epoxy content in the anode binder. With the epoxy content of 50% in the anode binder, a decrease in the maximum power density to $1,425mW/m^2$ was observed, which about 75.3% of the anode binder without epoxy is. However, the material consisting of the same amount of epoxy and Nafion solution is a good alternative for anode binder in terms of durability and economics of MFC.

Analysis on the Reduction of Phosphorus Release in River and Lake Sediments through Application of Capping Technology (Capping 기술을 이용한 하천 및 호소 퇴적토의 인 용출 저감 효과 분석)

  • Kim, Seog-Ku;Yun, Sang-Leen
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.11
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    • pp.781-790
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    • 2014
  • Contaminants such as organic matters, nutrients and toxic chemicals in rivers and lakes with a weak flow rate are first removed from the water and accumulated in the sediments. Subsequently, they are released into the water column again, posing direct/indirect adverse effects on the water quality and aquatic ecosystems. In particular, phosphorus is known to accelerate the eutrophication phenomenon when it is released into the water column via physical disturbance and biological/chemical actions as one of important materials that determine the primary production of aquatic ecosystems and an element that is stored mainly in the sediments in the process of material circulation in the body of water. In this study, the effect on reducing phosphorus release in sediments was analyzed by applying different capping materials to lake water, where the effect of aquatic microorganisms is taken into account, and to distilled water, where the effect of microorganisms is excluded. The experimental results showed that capping with chemical materials such as Fe-gypsum and $SiO_2$-gypsum further reduced the phosphorus release by at least 40% compared to the control case. Composite materials like granule gypsum+Sand showed over 50% phosphorus release reduction effect. Therefore, it is determined that capping with chemical materials such as granule-gypsum and eco-friendly materials such as sand is effective in reducing phosphorus release. The changes in phosphorus properties in the sediments before and after capping treatment showed that gypsum input helped to change the phosphorus that is present in lake sediments into apatite-P, a stable form that makes phosphorus release difficult. Based on the above results, it is expected that the application of capping technology will contribute to improving the efficiency of reducing phosphorus release that occurs in river and lake sediments.

Electrodeposition onto the Surface of Carbon Fiber and Its Application to Composites (II) - CFRC with MVEMA and EMA Interphase - (탄소섬유 표면에의 고분자 전착과 복합재료 물성 (II) - MVEMA 및 EMA 계면상을 갖는 탄소섬유 복합재료 -)

  • Kim, Minyoung;Kim, Jihong;Bae, Jongwoo;Kim, Wonho;Hwang, Byungsun;Choi, Youngsun
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.336-342
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    • 1999
  • Various surface treatment techniques can be applied onto the surface of carbon fibers to increase interlaminar shear strength (ILSS). In a commerciaI treatment, first, surface of carbon fiber was oxidized, after that, a sizing agent was coated to improve handleability and adhesion to the matrix. Carbon fiber reinforced composites (CFRC) which is made of these fibers show excellent ILSS but show low vaIues of impact strength In this study, reactive and ductile interphase was introduced between fiber and matrix to increase both the ILSS and impact strength. By using electric conductivity of carbon fibers, flexible polymers which have ionizable group, i.e., MVEMA and EMA, were coated onto the surface (oxidized) of carbon fiber by the technique of electrodeposition. ILSS and impact strength of composites were evaluated according to the surface treatments, i.e., commercial sizing treatment, interphase introduction, and without sizing treatment. Izod impact strength and ILSS of CFRC were simultaneously improved in thc thickness range of $0.08{\sim}0.12{\mu}m$ of MVEMA interphase. Water resistance of the composites was decreased by introducing MVEMA interphase.

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Behavior of Hybrid Stud under Compressive Load (복합스터드의 압축 좌굴 거동)

  • Lee, Sang Sup;Bae, Kyu Woong
    • Journal of Korean Society of Steel Construction
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    • v.16 no.5 s.72
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    • pp.609-619
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    • 2004
  • An investigation was conducted on the activities around Europe in order to solve the problem of the thermal bridging of steel studs, which had caused a significant disadvantage. This study included the following: diminishing the contact area between the studs and the sheathing, lengthening the heat transfer route, replacing the steel web with a less conductive material, and placing foam insulation in locations where the thermal shorts are most critical. Although energy efficiency is usually the focus of such foreign cases because their stud application is mostly limited to low-rise residential buildings, both structural and thermal performance are taken into consideration in this study because these target middle-story buildings. A hybrid stud composed of steel and polymer was also developed. This hybrid stud, which is 150 SL in size, is made of a galvanized steel sheet (SGC58) and a glass fiber reinforced polymer (GFRP) withepoxy bonding. A total of 32 specimens were manufactured. Its parameters comprise two types of connection detail,s: the thickness of steel (1.0mm and 1.2mm) and of the GFRP (4mm-4ply and 6mm-6ply), and the ratio of the length to the depth (L/D = 3, 6, 9, 12). Steel stud specimens with the same conditions were compared to the hybrid stud. The test revealed that in the case of the steel specimen with a thickness of 1.0mm, the maximum load of hybrid studs increased an average of 1.62 times comparedto that of the steel stud. In the case of the steel specimen with a thickness of 1.2mm, on the other hand, the average increase was 1.46times. All specimens showed full composite action until the collapse.