• Title/Summary/Keyword: Composite Degree

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Fabrication and Electrical Properties of Conductive Carbon Black filled Poly(Vinyliden Fluoride) Composite (도전성 카본블랙/PVdF 복합재의 제조 및 전기적 특성)

  • Kim, Myung-Chan;Moon, Seung-Hwan;Lim, Jae-Seok;Hahm, Hyun-Sik;Park, Hong-Soo;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.3
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    • pp.212-220
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    • 2003
  • Electrical properties of carbon filler/PVdF [poly(vinylidene fluoride)] composite were investigated as a funtion of carbon filler/PVdF ratio in the range of 0.2${\sim}$0.5. Three kinds of comercialzied conductive carbon blacks such as Hiblack 41Y, KE300J, and KE600J, and carbon nanofibers prepared by the catalytic chemical vapor deposition of $C_2H_4$ over Ni-Cu catalysts were used as the carbon fillers. The electrical conductivity of carbon filler/PVdF composites were in the range of 0.65 to 13.5 S/cm depending the fillers' electrical conductivity ranging from 5.6 to 23.1 S/cm. Among the carbon fillers used, the KE600J carbon black showed the highest conductivity both in the composite and filler itself because of its high degree of graphitization due to the high-temperature thermal treatment and its high surface area due to the activation treatment.

Evaluation and Application of T-Ray Nondestructive Characterization of FRP Composite Materials (FRP 복합재료의 T-Ray 비파괴특성 평가 및 적용)

  • Im, Kwang-Hee;Hsu, David K.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.5
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    • pp.429-436
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    • 2010
  • Recently, (terahertz ray) applications have emerged as one of the most promising new powerful nondestructive evaluation (NDE) techniques. In this study, a new T-ray time-domain spectroscopy system was utilized for detecting and evaluating layup effect and flaw in FRP composite laminates. Extensive experimental measurements in reflection and thru-transmission modes were made to map out the T-ray images. Especially this was demonstrated in thick GFRP laminates containing double saw slots. In carbon composites the penetration of terahertz waves is limited to some degree and the detection of flaws is strongly affected by the angle between the electric field(E-field) vector of the terahertz waves and the intervening fiber directions. The artificial defects investigated by terahertz waves were bonded foreign material, simulated disbond and delamination and mechanical impact damage. The effectiveness and limitations of terahertz radiation for the NDE of composites are discussed.

Coordinated Control Strategy and Optimization of Composite Energy Storage System Considering Technical and Economic Characteristics

  • Li, Fengbing;Xie, Kaigui;Zhao, Bo;Zhou, Dan;Zhang, Xuesong;Yang, Jiangping
    • Journal of Electrical Engineering and Technology
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    • v.10 no.3
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    • pp.847-858
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    • 2015
  • Control strategy and corresponding parameters have significant impacts on the overall technical and economic characteristics of composite energy storage systems (CESS). A better control strategy and optimized control parameters can be used to improve the economic and technical characteristics of CESS, and determine the maximum power and stored energy capacity of CESS. A novel coordinated control strategy is proposed considering the coordination of various energy storage systems in CESS. To describe the degree of coordination, a new index, i.e. state of charge coordinated response margin of supercapacitor energy storage system, is presented. Based on the proposed control strategy and index, an optimization model was formulated to minimize the total equivalent cost in a given period for two purposes. The one is to obtain optimal control parameters of an existing CESS, and the other is to obtain the integrated optimal results of control parameters, maximum power and stored energy capacity for CESS in a given period. Case studies indicate that the developed index, control strategy and optimization model can be extensively applied to optimize the economic and technical characteristics of CESS. In addition, impacts of control parameters are discussed in detail.

Low velocity impact response and dynamic stresses of thick high order laminated composite truncated sandwich conical shell based on a new TDOF spring-mass-damper model considering structural damping

  • Azizi, A.;Khalili, S.M.R.;Fard, K. Malekzadeh
    • Steel and Composite Structures
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    • v.26 no.6
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    • pp.771-791
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    • 2018
  • This paper deals with the low velocity impact response and dynamic stresses of composite sandwich truncated conical shells (STCS) with compressible or incompressible core. Impacts are assumed to occur normally over the top face-sheet and the interaction between the impactor and the structure is simulated using a new equivalent three-degree-of-freedom (TDOF) spring-mass-damper (SMD) model. The displacement fields of core and face sheets are considered by higher order and first order shear deformation theory (FSDT), respectively. Considering continuity boundary conditions between the layers, the motion equations are derived based on Hamilton's principal incorporating the curvature, in-plane stress of the core and the structural damping effects based on Kelvin-Voigt model. In order to obtain the contact force, the displacement histories and the dynamic stresses, the differential quadrature method (DQM) is used. The effects of different parameters such as number of the layers of the face sheets, boundary conditions, semi vertex angle of the cone, impact velocity of impactor, trapezoidal shape and in-plane stresses of the core are examined on the low velocity impact response of STCS. Comparison of the present results with those reported by other researchers, confirms the accuracy of the present method. Numerical results show that increasing the impact velocity of the impactor yields to increases in the maximum contact force and deflection, while the contact duration is decreased. In addition, the normal stresses induced in top layer are higher than bottom layer since the top layer is subjected to impact load. Furthermore, with considering structural damping, the contact force and dynamic deflection decrees.

Visible Light-Driven $CuInS_2-TiO_2$ Nanotube Composite Photoelectrodes with Heterojunction Structureusing Pulsed-Electrochemical Deposition Process (Pulse 전위를 적용한 전기화학적 증착 공정으로 제조된 가시광 활성 이종접합 $CuInS_2-TiO_2$ Nanotube 화합물 광전극)

  • Yun, Jung-Ho;Amal, Rose;Park, Young-Koo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.1
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    • pp.49-56
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    • 2013
  • Excellent electron transport properties with enhanced light scattering ability for light harvesting have made well-ordered one dimensional $TiO_2$ nanotube(TNT) arrays an alternative candidate over $TiO_2$ nanoparticles in the area of solar energy conversion applications. The principal drawback of TNT arrays being activated only by UV light has been addressed by coupling the TNT with secondary materials which are visible light-triggered. As well as extending the absorption region of sunlight, the introduction of these foreign components is also found to influence the charge separation and electron lifetime of TNT. In this study, a novel method to fabricate the TNT-based composite photoelectrodes employing visible responsive $CuInS_2$ (CIS) nanoparticles is presented. The developed method is a square wave pulse-assisted electrochemical deposition approach to wrap the inner and outer walls of a TNT array with CIS nanoparticles. Instead of coating as a dense compact layer of CIS by a conventional non-pulsed-electrochemical deposition method, the nanoparticles pack relatively loosely to form a rough surface which increases the surface area of the composite and results in a higher degree of light scattering within the tubular channels and hence a greater chance of absorption. The excellence coverage of CIS on the tubular $TiO_2$ allows the construction of an effective heterojunction that exhibits enhanced photoelectrochemical performance.

COLOR CHANCES IN COMPOSITES ACCORDING TO VARIOUS LIGHT CURING SOURCES (광중합원에 따른 복합레진의 색채변화)

  • Cho, Young-Gon;Kim, Myung-Cho
    • Restorative Dentistry and Endodontics
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    • v.27 no.1
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    • pp.87-94
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    • 2002
  • The purpose of this study was to evaluate the color changes of composite resin polymerized with three type of light curing units. Composite resin (Z100, shade A2) were applied in a cylindrical metal mold(2 mm thick, 7 mm diameter). Twenty specimens according to light curing units were made. Group 1 : the specimens were polymerized with Apollo 95E for 3seconds(1370 mW/$\textrm{cm}^2$). Group 2 : the specimens were polymerized with XL 3000 for 40seconds (480 mW/$\textrm{cm}^2$). Group 3 : the specimens were polymerized with Spectrum 800 for 10 seconds(250 mW/$\textrm{cm}^2$) and 30 seconds(700 mW/$\textrm{cm}^2$). The microhardness values(VHN) of upper and lower surfaces specimens after light polymerization were measured for the degree of polymerization. All specimens were stored in distilled water at 6$0^{\circ}C$ for 30 days. The color characteristics(L$^*$, a$^*$, b$^*$) of the specimens before and after immersion were measured by spectrophotometer and the total color difference ($\Delta$E$^*$) was computed. The results obtained were as follows : 1. The microhardness values of Group I showed significantly lower than those of Group II and III (p<0.05). 2. In all groups the $\Delta$E$^*$ values presented below 2.0. 3 Group I showed the highest $\Delta$E$^*$ values followed order from highest to lowest by Group II and III (p<0.05).

Cracked-Healing and Bending Strength of Si3N4 Ceramics (Si3N4 세라믹스의 균열 치유와 굽힘 강도 특성)

  • Nam, Ki-Woo;Park, Seung-Won;Do, Jae-Youn;Ahn, Seok-Hwan
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.11
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    • pp.957-962
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    • 2008
  • Crack-healing behavior of $Si_3N_4$ composite ceramics has been studied as functions of heat-treatment temperature and amount of additive $SiO_2$ colloidal. Results showed that optimum amount of additive $SiO_2$ colloidal and coating of $SiO_2$ colloidal on crack could significantly increase the bending strength. The heat-treatment temperature has a profound influence on the extent of crack healing and the degree of strength recovery. The optimum heat-treatment temperature depends on the amount of additive $SiO_2$ colloidal. Crack healing strength was far the better cracked specimen with $SiO_2$ colloidal coating on crack surface. After heat treatment at the temperature 1,273 K in air, the crack morphology almost entirely disappeared by scanning prob microscope. At optimum healing temperature 1,273 K, the bending strength with additive $SiO_2$ colloidal 0.0 wt.% without $SiO_2$ colloidal coating recovered to the value of the smooth specimens at room temperature for the investigated crack sizes $100\;{\mu}m$. But that with $SiO_2$ colloidal coating increase up to 140 %. The amount of optimum additive $SiO_2$ colloidal was 1.3 wt.% and crack healed bending strength with $SiO_2$ colloidal coating increase up to 160 % to smooth specimen of additive $SiO_2$ colloidal 0.0 wt.%. Crack closure and rebonding of the crack due to oxidation of cracked surfaces were suggested as a dominant healing mechanism operating in $Si_3N_4$ composite ceramics.

Temperature changes under demineralized dentin during polymerization of three resin-based restorative materials using QTH and LED units

  • Mousavinasab, Sayed-Mostafa;Khoroushi, Maryam;Moharreri, Mohammadreza;Atai, Mohammad
    • Restorative Dentistry and Endodontics
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    • v.39 no.3
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    • pp.155-163
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    • 2014
  • Objectives: Light-curing of resin-based materials (RBMs) increases the pulp chamber temperature, with detrimental effects on the vital pulp. This in vitro study compared the temperature rise under demineralized human tooth dentin during light-curing and the degrees of conversion (DCs) of three different RBMs using quartz tungsten halogen (QTH) and light-emitting diode (LED) units (LCUs). Materials and Methods: Demineralized and non-demineralized dentin disks were prepared from 120 extracted human mandibular molars. The temperature rise under the dentin disks (n = 12) during the light-curing of three RBMs, i.e. an Ormocer-based composite resin (Ceram. X, Dentsply DeTrey), a low-shrinkage silorane-based composite (Filtek P90, 3M ESPE), and a giomer (Beautifil II, Shofu GmbH), was measured with a K-type thermocouple wire. The DCs of the materials were investigated using Fourier transform infrared spectroscopy. Results: The temperature rise under the demineralized dentin disks was higher than that under the non-demineralized dentin disks during the polymerization of all restorative materials (p < 0.05). Filtek P90 induced higher temperature rise during polymerization than Ceram.X and Beautifil II under demineralized dentin (p < 0.05). The temperature rise under demineralized dentin during Filtek P90 polymerization exceeded the threshold value ($5.5^{\circ}C$), with no significant differences between the DCs of the test materials (p > 0.05). Conclusions: Although there were no significant differences in the DCs, the temperature rise under demineralized dentin disks for the silorane-based composite was higher than that for dimethacrylate-based restorative materials, particularly with QTH LCU.

Simultaneous Measurement of Strain and Damage Signal in Composite Structures Using a Fiber Bragg Grating Sensor (광섬유 브래그 격자 센서를 이용한 복합재 구조물의 변형률 및 파손신호 동시 측정)

  • Koh, Jong-In;Bang, Hyung-Joon;Kim, Chun-Gon;Hong, Chang-Sun
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.7
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    • pp.43-50
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    • 2004
  • For the simultaneous measurement of strain and damage signal a fiber Bragg grating sensor system with a dual demodulator was proposed. The dual demodulator is composed of a demodulator using a tunable Fabry-Perot filter measuring the low-frequency signal with large magnitude such as strain and the other using a passive Mach-Zehnder interferometer detecting the high-frequency signal with small amplitude such as impact or damage signal. Using the proposed fiber Bragg grating sensor system, both the strain and damage signals of a cross-ply laminated composite beam under tensile loading were simultaneously measured. The strain and damage signals detected by single fiber Bragg grating sensor showed that sudden strain shifts were accompanied with vibration at a maximum frequency of several hundreds of kilohertz at the instant of matrix crack propagation in the 90 degree layer in composite beam.

AN EXPERIMENTAL STUDY ON THE MARGINAL LEAKAGE OF THE POSTERIOR COMPOSITE RESTORATIONS (구치부 복합레진의 변연누출에 관한 실험적 연구)

  • Kwon, Byeong-Goo;Lee, Chung-Suck;Park, Dong-Soo;Lee, Seung-Jong;Lee, Chan-Young
    • Restorative Dentistry and Endodontics
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    • v.15 no.1
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    • pp.44-56
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    • 1990
  • This study was designed to assess the degree of the marginal leakage of posterior composite restorations with glass ionomer cement base and Scotchbond$^{(R)}$ by means of the dye penetration at the enamel and dentinal margins. 160 cavities of class V were prepared on the buccal and lingual surfaces of 80 extracted premolar and molar teeth, which were divided into two groups. The buccal cavities of one group were filled with GC lining cement$^{(R)}$, Scotchbond$^{(R)}$ and P 50$^{(R)}$ and the lingual cavities were filled with Scotchbond$^{(R)}$ and Heliomolar$^{(R)}$. The Buccal cavities of other group were filled with Logobond$^{(R)}$, Scotchbond$^{(R)}$ and Heliomolar$^{(R)}$ and lingual cavities were filled with Scotchbond$^{(R)}$ and P 50$^{(R)}$. After finishing, all specimens were subjected manually to 50 thermal cycles at $4^{\circ}C$ and $60^{\circ}C$. They were immersed in 0.5% methylene blue solution for 24 hours and buccolingually sectioned with diamond disc. The sectioned specimens were examined under light microscope. The following results were obtained. 1. The group filled with glass ionomer cement base showed less marginal leakage than the group filled without glass ionomer cement base. 2. The enamel margins showed less microleakage than the dentinal margins in both of the two groups. 3. No significant difference was showed in the microleakage, irrespective of two glass ionomer cement base and posterior composite resin.

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