• Title/Summary/Keyword: Complex wavelength

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Power extraction efficiency and lasing wavelength distribution of complex-coupled DFB lasers for various facet reflectivity combinations and coupling coefficient ratios (양 단면 반사율 조합과 결합 계수 비에 따른 Complex-Coupled DFB 레이저 다이오드의 파워 추출 효율과 발진 파장 분포)

  • 김상택;김부균
    • Korean Journal of Optics and Photonics
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    • v.15 no.2
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    • pp.149-157
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    • 2004
  • We have calculated the power extraction efficiency and the lasing wavelength distribution of complex-coupled(CC) DFB lasers above threshold for various|$\chi$L| and facet reflectivity combinations, and we have compared the results with those at threshold. Also, we have investigated the effect of coupling coefficient ratio(CR) and the reflectivity of AR facet on the power extraction efficiency and the lasing wavelength distribution. At threshold, the single mode yield as a function of power extraction efficiency of in-phase(IP) CC DFB lasers is the same as that of anti-phase(AP) CC DFB lasers. Above threshold, however, the single mode yield as a function of power extraction efficiency of IP CC DFB lasers is much larger than that of AP CC DFB lasers. For IP CC DFB lasers, AR-HR combination has high single mode yield and large power extraction efficiency compared to other facet combinations. IP CC DFB laser with AR-HR combination for |$\chi$L|of 0.8 has the highest single mode yield and largest power extraction efficiency above threshold among the cases considered. For AR-HR combination, as CR increases and the reflectivity of AR facet decreases, both single mode yield and power extraction efficiency increase due to the reduction of the spatial hole burning effect. For AR-HR combination, the lasing wavelength of CC DFB laser has distributed over the stopband of DFB. As CR increases, the lasing wavelength concentrates on the long wavelength side for IP CC DFB laser, while on the short wavelength side for AP CC DFB laser. As |$\chi$L| increases, the width of the wavelength distribution decreases and the lasing wavelength moves to the long wavelength side.

A Study on the Complex Dyeing of Natural Dye (천연염료의 복합염색에 관한 연구)

  • Shin, Young-Joon
    • Journal of the Korea Fashion and Costume Design Association
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    • v.14 no.4
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    • pp.151-162
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    • 2012
  • Regarding experimental study on the dyeing properties of natural dye, I have dyed silk fabric with Styphnolobium japonicum, sappan wood, and indigo. The results of the experiment have been analysed by wavelength of maximum absorption, K/S and CIE Lab chromaticity co-ordinated. The results are as follows: In case of complex dyeing using Styphnolobium japonicum and sappan wood, dyeing with sappan wood, which is red related color, after dyeing with Styphnolobium japonicum, which is yellow related color, is more efficient. When dyeing was maden by complex of Styphnolobium japonicum and sappan wood, Dyeing method by the order of "Styphnolobium japonicum${\rightarrow}$sappan wood${\rightarrow}$mordanting" made the best result of complex dyeing. In case of complex dyeing using Styphnolobium japonicum and Indigo, dyeing with Styphnolobium japonicum after the indigo made the best result. When dyeing with indigo first, and then Styphnolobium japonicum, yellow color was not well dyed, and low level of saturation caused lusterless color. Ordering of Styphnolobium japonicum${\rightarrow}$sappan wood${\rightarrow}$indigo made the best result of complex dyeing in case of complex dying with Styphnolobium japonicum and indigo. Dyeing order, sappan wood first and then indigo last method shown 560~640 nm wavelength of maximum absorption which most color was blue related. In contrast, Indigo first and then sappan wood method shown 460~560nm wavelength of maximum absorption which color was red related. Complex dyeing with sappan wood and indigo was showing lusterless color. In case of dyeing with red and blue, dyeing with sappan wood and indigo was not appropriate.

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A MULTI-WAVELENGTH STUDY OF 30 DORADUS COMPLEX IN THE LARGE MAGELLANIC CLOUD

  • Kim, Sung-Eun
    • Journal of The Korean Astronomical Society
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    • v.38 no.3
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    • pp.365-370
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    • 2005
  • We have made a multi-wavelength study of the X-ray bright giant shell complex 30 Doradus in the Large Magellanic Cloud (LMC). This is the one of the largest H II complexes in the Local Group. The Australia Telescope Compact Array (ATCA) and the Parkes 64-m single dish observations reveal that the distribution and internal motions of H I gas show the effects of fast stellar winds and supernova blasts. The hot emitting gas within the 30 Doradus complex and the entire giant H II complex are encompassed by an expanding H I shell. We investigate the dynamical age of this H I shell and compare to the age of starbursts occurred in the 30 Doradus nebula using the radiative transfer model and the infrared properties.

Studies on the complex compounds and their analytical methods of barbiturates by means of $\alpha$-picoline-copper (II) ($\alpha$-picoline동(II)에 의한 barbital 류의 착화합물및 그의 약품분석화학적 연구)

  • 김수억
    • YAKHAK HOEJI
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    • v.13 no.1
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    • pp.1-15
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    • 1969
  • A new method of qualitative and quantitative determination of barbiturates in the pharmaceuticals by means of $\alpha$-picoline-copper (II) was studied. Barbiturates in the pharmaceuticals were dissolved in the mixed solvent of 33% $\alpha$-picoline-Carbontetrachloride to yield Complex Compounds of barbiturates-copper (II)-$\alpha$-picoline. Complex Compounds of barbiturates show uniformly maximum absorption at the wavelength of 540m.mu. and wre to be identified at the concentration of 1 X 10$^{-4}$ Mole, and also was to be quantitatively determined at the concentration of 1 X 10$^{-3}$ Mole. By this method barbiturates in the pharmaceuticals could be determined in the presence of various compounds such as sulpyrine, isopropylantipyrine, antipyrine, phenacetin and etc. But Barbiturates could be also determined by this method after seperation with aminopyrine, acetaminophen, acetylsalicylic acid and etc. by column chromatography. And barbiturates and acetylsalicylic acid could be also determined by simultaneous equation while their complex compounds show uniformly each maximum absorption at the Wavelength of 540 m${\mu}$ and 620 m${\mu}$. I.R. spectra of these complex compounds show identification of Barbiturates derivatives. The composition ratio of these complex compounds were : barbiturates : Cu : ${\alpha}$-picoline=2:1:2.

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Study on Metal Cupferrate Complex (Part II) Spectrophotometric Determination of Fe(III)-Cupferrate Composition (Metal Cupferrate Complex 에 關한 硏究 (第 2 報) Spectrophotometry 에 의한 Fe(III)-Cupferrate의 化學組成의 決定)

  • Si-Joong Kim;Doo-Soon Shin
    • Journal of the Korean Chemical Society
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    • v.7 no.4
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    • pp.280-282
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    • 1963
  • Fe (III)-cupferrate composition in chloroform phase was determined by molar ratio method, continuous variation method and slope ratio method spectrophotometrically at 325m$\mu$ and 385m$\mu$ wavelength. At both wavelength, compositions of the complex were Fe$Cupf_3$.

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Wavelength Conversion Lanthanide(III)-cored Complex for Highly Efficient Dye-sensitized Solar Cells

  • Oh, Jung-Hwan;Song, Hae-Min;Eom, Yu-Kyung;Ryu, Jung-Ho;Ju, Myung-Jong;Kim, Hwan-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2743-2750
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    • 2011
  • Lanthanide(III)-cored complex as a wavelength conversion material has been successfully designed and synthesized for highly efficient dye-sensitized solar cells, for the first time, since light with a short wavelength has not been effectively used for generating electric power owing to the limited absorption of these DSSCs in the UV region. A black dye (BD) was chosen and used as a sensitizer, because BD has a relatively weak light absorption at shorter wavelengths. The overall conversion efficiency of the BD/WCM device was remarkably increased, even with the relatively small amount of WCM added to the device. The enhancement in $V_{oc}$ by WCM, like DCA, could be correlated with the suppression of electron recombination between the injected electrons and $I_3{^-}$ ions. Furthermore, the short-circuit current density was significantly increased by WCM with a strong UV light-harvesting effect. The energy transfer from the Eu(III)-cored complex to the $TiO_2$ film occurred via the dye, so the number of electrons injected into the $TiO_2$ surface increased, i.e., the short-circuit current density was increased. As a result, BD/WCM-sensitized solar cells exhibit superior device performance with the enhanced conversion efficiency by a factor of 1.22 under AM 1.5 sunlight: The photovoltaic performance of the BD/WCM-based DSSC exhibited remarkably high values, $J_{sc}$ of 17.72 mA/$cm^2$, $V_{oc}$ of 720 mV, and a conversion efficiency of 9.28% at 100 mW $cm^{-2}$, compared to a standard DSSC with $J_{sc}$ of 15.53 mA/$cm^2$, $V_{oc}$ of 689 mV, and a conversion efficiency of 7.58% at 100 mW $cm^{-2}$. Therefore, the Eu(III)-cored complex is a promising candidate as a new wavelength conversion coadsorbent for highly efficient dye-sensitized solar cells to improve UV light harvesting through energy transfer processes. The abstract should be a single paragraph which summaries the content of the article.

An Asymmetric Sampled Grating Laser and Its Application to Multi-Wavelength Laser Array

  • Ryu, Sang-Wan;Kim, Je-Ha
    • ETRI Journal
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    • v.24 no.5
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    • pp.341-348
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    • 2002
  • We propose an asymmetric sampled grating laser and a multi-wavelength laser array associated with it. Asymmetric sampling periods combined with an index shifter make it possible to use first order reflection for lasing operations. With the structure of our design, we achieved a simple fabrication procedure as well as a high yield without using complex and time-consuming e-beam lithography for multi-period gratings. We analyzed the effect of mirror coating by numerical analysis to improve single mode and power extraction performance. By using high reflection-antireflection coatings, we obtained high power extraction efficiency without degradation of the single mode property. For the multi-wavelength laser array, to gain wavelength control, we varied the sampling periods from one laser to an adjacent laser across the array. With this approach, we showed the feasibility of an array of up to 30 channels with 100 GHz wavelength spacing.

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Determination of L-Dopa by Spectrofluorimetry Using Co-fluorescence Enhancer (보조 형광증가제를 이용한 L-Dopa의 형광분광법적 정량)

  • Lee, Sang Hak;Ahn, Jung Mi
    • Journal of the Korean Chemical Society
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    • v.44 no.6
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    • pp.541-546
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    • 2000
  • Methods to determine L-dopa(L-3,4-dihydroxyphenylalanine) in aqueous solution by spectrofluorimetry based upon the ligand sensitized luminescence of Tb(III) ion L-dopa complex have been studied. Tb(III) ion and Lu(III) ion were used as ligand sensitized fluorescencer and co-fluorescence enhancer, respectively. The effects of excitation wavelength, pH, concentration of Tb(III) ion, concentration of Lu(III) ion and emission wavelength on the fluorescence intensity were investigated. The fluorescence intensity of the Tb(III) ion L-dopa complex was further increased with addition of Lu(III) ion. The calibration curve for L-dopa was linear over the range from 5.0 ${\times}$ $10^{-7}$ M to 1.0${\times}$ $10^{-4}$ M and the detection limit was 4.0 ${\times}$ $10^{-8}$ M under the optimal experimental conditions of 300 nm, 8.0, 1.0 ${\times}$ $10^{-4}$ M and 545 nm for excitation wavelength, pH, concentration of Tb(III) ion and emission wavelength, respectively. When Lu(III) ion was added to Tb(Ⅲ) ion L-dopa complex, the concentration range of linear response and detection limit were 1.0${\times}$$10^{-8}$ M to 2.0 ${\times}$ $10^{-4}$ M and 1.0 ${\times}$ $10^{-9}$ M, respectively under the optimal experimental conditions of 300 nm, 8.5, 1.0 ${\times}$ $10^{-5}$ M, 1.0 ${\times}$ $10^{-5}$ M, 545 nm for excitation wavelength, pH, concentration of Tb(III) ion, concentration of Lu(III) ion and emission wavelength, respectively.

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Study on the Excited Energy Transfer in Light-harvesting Complex (LH2) of Rhodobacter sphaeroides

  • Liu, Yuan;Guo, Lijun;Qian, Shixiong;Xu, Chunhe
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.359-361
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    • 2002
  • A green mutant of Rhodobacter sphaeroides 60I was acquired by chemical induction. The blue-shifted of the carotenoid absorption was found in the Light-harvesting complex II (LH2) of the mutant. With the excitation at different wavelength, we observed that the evolution of excited-state dynamics in LH2 of Rhodobacter sphaeroides 60I. The dynamical traces demonstrate a dominant absorption followed concomitantly by an ultrafast transmission increase and decay with 818nm excitation.

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Syntheses and Photofading of Intermolecular Charge-Transfer Complex Dyes of Phenothiazine and Quinonoid Compounds (Phenothiazine과 Quinone계 분자간 전하 이동형 색소의 합성 및 광 퇴색)

  • 김성훈;이순남;임용진
    • Textile Coloration and Finishing
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    • v.4 no.2
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    • pp.64-68
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    • 1992
  • The charge-transfer(CT) complexes derived from phenothiazine as donor and quinonoid compounds as accepters were evaluated as coloring matter. Light fastness of the intermolecular charge-transfer(CT) complex dyes as well as absorption wavelength is an important factor when the complexes are applied to coloring matters. The photofading mechanism of CT complex dyes of phenothiazine and accepters were examined. The addition of effective radical scavenger, antioxidant and photostabilizer gave a remarkable enhancement of the photostability of CT dyes.

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