• 한국광학회지
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• 제15권2호
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• pp.149-157
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• 2004

문턱 전류 이상에서 complex-coupled(CC) DFB 레이저의 여러 가지 ｜$\chi$L｜과 양 단면 반사율 조합에 대하여 파워 추출 효율과 발진 파장 분포를 구하였고 문턱 전류에서의 결과와 비교하였다. 또한 결함 계수 비(CR)와 Ar 단면의 반사율이 파워 추출 효율과 발진 파장 분포에 미치는 영향에 대하여 살펴보았다. 문턱 전류에서 in-phase(IP) CC DFB 레이저와 anti-phase(AP) CC DFB 레이저의 파워 추출 효율에 대하여 도시한 단일 모드 수율은 정확히 일치하였다. 그러나 문턱 전류 이상에서는 IP CC DFB 레이저의 파워 추출에 대하여 도시한 단일 모드 수율은 AP CC DFB 레이저보다 크게 나타났다. IP CC DFB 레이저의 경우 양 단면 반사율 조합이 AR-HR의 경우가 다른 반사율 조합에 비해 단일 모드 수율이 크고 또한 파워 추출 효율이 큼을 알 수 있었다. 본 논문에서 고려한 경우 중에서 ｜$\chi$L｜이 0.8이고 AR-HR인 경우가 문턱 전류 이상에서 단일 모드 수율과 파워 추출 효율이 가장 컸다. 양 단면 반사율 조합이 AR-HR인 경우 CR이 커질수록, AR단면의 반사율이 작아질수록 spatial hole burning 현상이 완화되어 단일 모드 수율과 파워 추출 효율이 커졌다. 양 단면 반사율 조합이 AR-HR인 경우 CC DFB 레이저의 발진 파장은 DFB 금지 대역 내에 넓게 분포하였다. CR이 증가할수록 IP CC DFB 레이저는 장파장 모드에, AP CC DFB 레이저는 단파장 모드에 발진 파장 분포가 증가하였다. ｜$\chi$L｜이 커질수록 발진 파장이 존재하는 파장 폭이 작아 지고 발진 파장 분포가 장파장 쪽으로 이동하였다.

• 한국의상디자인학회지
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• 제14권4호
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• pp.151-162
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• 2012

Regarding experimental study on the dyeing properties of natural dye, I have dyed silk fabric with Styphnolobium japonicum, sappan wood, and indigo. The results of the experiment have been analysed by wavelength of maximum absorption, K/S and CIE Lab chromaticity co-ordinated. The results are as follows: In case of complex dyeing using Styphnolobium japonicum and sappan wood, dyeing with sappan wood, which is red related color, after dyeing with Styphnolobium japonicum, which is yellow related color, is more efficient. When dyeing was maden by complex of Styphnolobium japonicum and sappan wood, Dyeing method by the order of "Styphnolobium japonicum${\rightarrow}$sappan wood${\rightarrow}$mordanting" made the best result of complex dyeing. In case of complex dyeing using Styphnolobium japonicum and Indigo, dyeing with Styphnolobium japonicum after the indigo made the best result. When dyeing with indigo first, and then Styphnolobium japonicum, yellow color was not well dyed, and low level of saturation caused lusterless color. Ordering of Styphnolobium japonicum${\rightarrow}$sappan wood${\rightarrow}$indigo made the best result of complex dyeing in case of complex dying with Styphnolobium japonicum and indigo. Dyeing order, sappan wood first and then indigo last method shown 560~640 nm wavelength of maximum absorption which most color was blue related. In contrast, Indigo first and then sappan wood method shown 460~560nm wavelength of maximum absorption which color was red related. Complex dyeing with sappan wood and indigo was showing lusterless color. In case of dyeing with red and blue, dyeing with sappan wood and indigo was not appropriate.

• 천문학회지
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• 제38권3호
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• pp.365-370
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• 2005

We have made a multi-wavelength study of the X-ray bright giant shell complex 30 Doradus in the Large Magellanic Cloud (LMC). This is the one of the largest H II complexes in the Local Group. The Australia Telescope Compact Array (ATCA) and the Parkes 64-m single dish observations reveal that the distribution and internal motions of H I gas show the effects of fast stellar winds and supernova blasts. The hot emitting gas within the 30 Doradus complex and the entire giant H II complex are encompassed by an expanding H I shell. We investigate the dynamical age of this H I shell and compare to the age of starbursts occurred in the 30 Doradus nebula using the radiative transfer model and the infrared properties.

• 약학회지
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• 제13권1호
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• pp.1-15
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• 1969

A new method of qualitative and quantitative determination of barbiturates in the pharmaceuticals by means of $\alpha$-picoline-copper (II) was studied. Barbiturates in the pharmaceuticals were dissolved in the mixed solvent of 33% $\alpha$-picoline-Carbontetrachloride to yield Complex Compounds of barbiturates-copper (II)-$\alpha$-picoline. Complex Compounds of barbiturates show uniformly maximum absorption at the wavelength of 540m.mu. and wre to be identified at the concentration of 1 X 10$^{-4}$ Mole, and also was to be quantitatively determined at the concentration of 1 X 10$^{-3}$ Mole. By this method barbiturates in the pharmaceuticals could be determined in the presence of various compounds such as sulpyrine, isopropylantipyrine, antipyrine, phenacetin and etc. But Barbiturates could be also determined by this method after seperation with aminopyrine, acetaminophen, acetylsalicylic acid and etc. by column chromatography. And barbiturates and acetylsalicylic acid could be also determined by simultaneous equation while their complex compounds show uniformly each maximum absorption at the Wavelength of 540 m${\mu}$ and 620 m${\mu}$. I.R. spectra of these complex compounds show identification of Barbiturates derivatives. The composition ratio of these complex compounds were : barbiturates : Cu : ${\alpha}$-picoline=2:1:2.

• 대한화학회지
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• 제7권4호
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• pp.280-282
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• 1963

Spectrophotometry에 의한 몰比法, 運續變化法 및 傾科比法으로 chloroform phase에 存在하는 Fe(III)-cupferrate의 組成을 決定하였는데, 그 황化合物은 325m$\mu$에서와 385m$\mu$에서 모두 $FeCupf_3^인 化學式을 갖는 것이었다.

• Bulletin of the Korean Chemical Society
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• 제32권8호
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• pp.2743-2750
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• 2011

Lanthanide(III)-cored complex as a wavelength conversion material has been successfully designed and synthesized for highly efficient dye-sensitized solar cells, for the first time, since light with a short wavelength has not been effectively used for generating electric power owing to the limited absorption of these DSSCs in the UV region. A black dye (BD) was chosen and used as a sensitizer, because BD has a relatively weak light absorption at shorter wavelengths. The overall conversion efficiency of the BD/WCM device was remarkably increased, even with the relatively small amount of WCM added to the device. The enhancement in $V_{oc}$ by WCM, like DCA, could be correlated with the suppression of electron recombination between the injected electrons and $I_3{^-}$ ions. Furthermore, the short-circuit current density was significantly increased by WCM with a strong UV light-harvesting effect. The energy transfer from the Eu(III)-cored complex to the $TiO_2$ film occurred via the dye, so the number of electrons injected into the $TiO_2$ surface increased, i.e., the short-circuit current density was increased. As a result, BD/WCM-sensitized solar cells exhibit superior device performance with the enhanced conversion efficiency by a factor of 1.22 under AM 1.5 sunlight: The photovoltaic performance of the BD/WCM-based DSSC exhibited remarkably high values, $J_{sc}$ of 17.72 mA/$cm^2$, $V_{oc}$ of 720 mV, and a conversion efficiency of 9.28% at 100 mW $cm^{-2}$, compared to a standard DSSC with $J_{sc}$ of 15.53 mA/$cm^2$, $V_{oc}$ of 689 mV, and a conversion efficiency of 7.58% at 100 mW $cm^{-2}$. Therefore, the Eu(III)-cored complex is a promising candidate as a new wavelength conversion coadsorbent for highly efficient dye-sensitized solar cells to improve UV light harvesting through energy transfer processes. The abstract should be a single paragraph which summaries the content of the article.

• ETRI Journal
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• 제24권5호
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• pp.341-348
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• 2002

We propose an asymmetric sampled grating laser and a multi-wavelength laser array associated with it. Asymmetric sampling periods combined with an index shifter make it possible to use first order reflection for lasing operations. With the structure of our design, we achieved a simple fabrication procedure as well as a high yield without using complex and time-consuming e-beam lithography for multi-period gratings. We analyzed the effect of mirror coating by numerical analysis to improve single mode and power extraction performance. By using high reflection-antireflection coatings, we obtained high power extraction efficiency without degradation of the single mode property. For the multi-wavelength laser array, to gain wavelength control, we varied the sampling periods from one laser to an adjacent laser across the array. With this approach, we showed the feasibility of an array of up to 30 channels with 100 GHz wavelength spacing.

• 대한화학회지
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• 제44권6호
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• pp.541-546
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• 2000

리간드 증감 유발 형광법을 이용하여 Tb(III)-L-dopa (L-3,4-dihydroxyphenyl alanine) 착이온의 방출세기를 측정함으로써 수용액 중의 L-dopa를 정량하는 방법에 대하여 연구하였다. 들뜸파장, pH, 보조 형광증가제의 선택, Tb(III) 이온의 농도, 보조 형광증가제로 사용된 Lu(III) 이온의 농도 및 방출파장의 방출세기에 대한 영향을 조사하였다. 보조 형광증가제로서 Lu(III) 이온을 첨가하였을때 Tb(III) 이온의 방출세기가 현저히 증가함을 관찰하였고, L-dopa의 검출한계를 낮출 수 있었다. 보조 형광증가제를 첨가하지 않았을 경우에 L-dopa 검정곡선의 직선감응범위는 들뜸파장, pH 및 Tb(Ⅲ) 이온의 농도가 각각 300 nm, 8.0 및 $1.0{\times}10^{-4}$ M였을때, $5.0{\times}10^{-7}$ M~$1.0{\times}10^{-4}$ M였다. 이 조건에서의 검출한계는 $4.0{\times}10^{-8}$ M였다. 보조 형광증가제를 첨가하였을 경우에는 들뜸파장, pH, Tb(III) 이온의 농도, 보조 형광증가제로 사용된 Lu(III) 이온의 농도 및 방출파장이 각각 300 nm, 8.5, $1.0{\times}10^{-5}$ M, $1.0{\times}10^{-5}$ M 및 545 nm였을 때, 직선감응범위가 1.0×$10^{-8}$ M~2.0{\times}10^{-4}$ M였고, 이 때의 검출한계는 $1.0{\times}10^{-9}$ M였다.

• Journal of Photoscience
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• 제9권2호
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• pp.359-361
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• 2002

A green mutant of Rhodobacter sphaeroides 60I was acquired by chemical induction. The blue-shifted of the carotenoid absorption was found in the Light-harvesting complex II (LH2) of the mutant. With the excitation at different wavelength, we observed that the evolution of excited-state dynamics in LH2 of Rhodobacter sphaeroides 60I. The dynamical traces demonstrate a dominant absorption followed concomitantly by an ultrafast transmission increase and decay with 818nm excitation.

• 한국염색가공학회지
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• 제4권2호
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• pp.64-68
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• 1992

The charge-transfer(CT) complexes derived from phenothiazine as donor and quinonoid compounds as accepters were evaluated as coloring matter. Light fastness of the intermolecular charge-transfer(CT) complex dyes as well as absorption wavelength is an important factor when the complexes are applied to coloring matters. The photofading mechanism of CT complex dyes of phenothiazine and accepters were examined. The addition of effective radical scavenger, antioxidant and photostabilizer gave a remarkable enhancement of the photostability of CT dyes.