• 한국지하수토양환경학회지:지하수토양환경
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• 제15권1호
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• pp.50-56
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• 2010

Oil contamination soil has been one of the most environmental social issues for decades in the inside and outside of country. The law of soil environmental preservation was carried out in the 1990s and the government controlled not only soil environment management and the remediation of contaminated soil but also promoted the development of remedial technology and cleanup business of contaminated soil by national policy. In addition to agriculture areas, the main oil contaminated sites are a gas station, oil reservoir, petro-chemical complex, site of railway carriage base and military camp. The contamination-frequency of agriculture area and effect sites are low but it has significantly important area on account of producing food for human beings. Therefore, we should be concerned about oil contamination damage of agriculture area. The oil contamination damage of agriculture area influenced drop of birth and breeding since the oil directly adheres to seeds and farm products even diffusion of contaminated soil to cultivation area. The studies of the crops and the food vegetation has not enough detailed data caused by the incident of oil contamination. This study investigated the effect of oil in germination and growth of selected plant seeds. In this study, we try to verify whether the oil contamination by accidents on farmland influenced the damage of farm produce and the mutual relation both oil contaminated soil or the vegetation of crops. The impact of oil on plant development was followed by phytotoxicity assessments. The plants exhibited visual symptoms of stress, growth reduction and perturbations in developmental parameters. The increase of the degree of pollution induced more marked effects in plants, likely because of the physical effects of oil. The relationships between the phytotoxicity contents of plants and growth reduction suggest a chemical toxicity of fuel oil. In addition, while cleaned up the contaminated soil under the standard of contaminated soil we examined it was suitable for region standard and it may have practical possibility for fill material of construction of afforestation and molding soil of landfill.

• Biomolecules & Therapeutics
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• 제15권1호
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• pp.65-72
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• 2007

Flax seed(Linseed, Linum usitatissimum L.) and its oil, a richest source of alpha-linolenic acid(ALA)(${\omega}-3$), contain saturated fatty acids, neurotoxic cyanogen glycosides and immuno-suppressive cyclic-nonapeptides. Present paper describes the development of two chemical processes, Process-A and -B, to remove saturated fatty acids and to destroy cyclic nonapeptides and cyanogen glycosides from flax seed oil. Process-A consists of three major steps, i.e., extraction of fatty acid mixture by alkaline saponification, removal of saturated fatty acid by urea-complexation, and triglyceride reconstruction of unsaturated fatty acid via fatty acyl-chloride activation using oxalyl chloride. Process-B consists of preparation of fatty acid ethyl ester by transesterification, elimination of saturated fatty acid ester by urea-complexation, and reconstruction of triglyceride by interesterification with glycerol-triacetate (triacetin). The destruction of lipophilic cyclic nonapeptide during saponification or transesterification processes could be demonstrated indirectly by the disappearance of antibacterial activity of bacitracin, an analogous cyclic-decapeptide. The cyanogen glycosides were found only in the dregs after hexane extraction, but not in the flax seed oil. The reconstructed triglyceride of flax seed oil, obtained by these two different pathways after elimination of saturated fatty acid and toxic components, showed agreeable properties as edible oil in terms of taste, acid value, iodine and peroxide value, glycerine content, and antioxidant activity.

• 대한기계학회논문집B
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• 제35권11호
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• pp.1163-1168
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• 2011

압축착화 방식의 디젤엔진은 스파크점화 방식의 가솔린 엔진에 비하여 열효율이 높아 연비가 향상되고 그 결과 $CO_2$ 저감효과도 높다. 또한 디젤엔진은 점화계통 장치의 불필요 등 기존 엔진의 개조비용이 적어 세탄가가 높은 바이오연료의 적용엔진으로서 적합한 장점이 있다. 따라서 본 연구에서는 식물성 자트로파유, 대두유 2종의 바이오연료와 경유연료의 분무특성을 비교 분석하였다. 실험변수로서는 분사압력과 자트로파 연료의 경우는 혼합비율(BD3, BD5, BD20)을 달리하였다. 분사압력은 500bar, 1000bar, 1500bar 및 1600bar로 설정하고 분사기간은 500ms로 동일하게 하였다. 본 연구의 결과로서, 사용한 바이오디젤 연료의 종류 및 분사압력 변화에 대한 분무거동특성(분무각)의 변화는 뚜렷하지 않으나, 고압분사의 경우가 분무각이 약간 감소하는 결과를 얻을 수 있었다.

• 약학회지
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• 제37권4호
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• pp.331-340
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• 1993

Inclusion complex of omeprazole(OMZ) with hydroxypropyl-$\beta$-cyclodextrin(HP-$\beta$-CD) was prepared by freeze-drying method. The complexation was confirmed by means of UV, CD, IR, DSC, XRD and $^{1}$H-NMR spectra. The benzimidazole moiety of OMZ might be found to be included into the cavity of HP-$\beta$-CD and the inclusion complex appeared to be $A_{L}$ type. The stoichiometric ratio of OMZ : HP-$\beta$-CD was found to be 1:1, and the stability constants of the inclusion complex by solubility and UV method were about 34 and 45 M$^{-1}$, respectively. The dissolution of OMZ was significantly enhanced from powder and. yablet of OMZ-HP-$\beta$-CD complex when compared to those of OMZ alone, and oil-to-water partition coefficient of OMZ-HP-$\beta$-CD complex was significantly higher than that of OMZ alone. Therefore, it was expected that the bioavailability of OMZ could be improved markedly by inclusion complexation of OMZ with HP-$\beta$-CD.

• 한국식품저장유통학회지
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• 제6권1호
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• pp.115-120
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• 1999

This study was carried out to investigate the effect of Pine needle extract on lipid oxidation and free radical reaction in iron sources reacted with active oxygen species. The results were summarized as follow; The pine needle extracts didn`t show a distinct effect on reduction of lipid oxidation if the iron ion didn`t exist in oil emulsion. The pine needle extracts played role as a strong chelating agents to bind iron ion if Ferrous iron(Fe\ulcorner) exist in oil emulsion. Ferric iron(Fe) was lower effect than Ferrous iron(Fe) on free radical reaction in oil emulsion. And also, the Fe\ulcorner reacted with pine needle extract did not show distinct effect on free radical reaction, compared to Fe\ulcorner reacted with pine needle extract. And also, Pine needle extracts reacted with H\ulcornerO\ulcorner were tended to show a low oxygen scavenging ability in case of H\ulcornerO\ulcorner only was existed, compared to those of H\ulcornerO\ulcorner + Fe\ulcorner complex. Pine needle extracts were the most powerful Fe\ulcorner binding agents, compared to other strong synthetic antioxidants such as EDTA and DTPA.

• 국제초고층학회논문집
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• 제8권3호
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• pp.229-234
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• 2019

This report introduces the structural design of Hibiya Mitsui Tower built in Tokyo Midtown Hibiya. The upper part of this tower is used for offices and the lower portion is for commercial facilities and a cinema complex which need the large open spaces. The 192m-high building has 35 floors above ground and 4 below ground. The structure is a steel frame using CFT columns to feature the high-performance oil dampers and the buckling restrained braces for vibration control. First, an outline of the structural design of this building is presented. Second, we introduce the transfer frame adopted to realize the large open spaces in the lower part, and the long column supporting the corner part of the high-rise building to avoid making a shade on the adjacent Hibiya Park, which are the feature of this building. Finally, we present an outline of the latest highly efficient semi-active oil dampers adopted in this building, and the vibration responses of this tower.

• 대한환경공학회지
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• 제38권7호
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• pp.353-363
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• 2016

본 연구에서는 공동주택 단지에서의 음식물류폐기물을 수거 이송하여 대용량처리시설에 자원화 혹은 재활용하는 기존 방식과 발생지인 공동주택 내에서 처리하는 제안 방식을 가상하여 차량수거방식, 자동집하방식, 자동집하처리방식, 소규모분산처리방식, 오수처리연계방식으로 시나리오를 설정하고 각 시나리오별 초기 투자비용, 석유 사용량, 이산화탄소 배출량, 음식물류폐기물 처리 운영비용, 입주자 부담 관리비를 비교 분석하였다. 기존처리 방식에 비해 제안하는 소규모분산처리방식이 초기 투자비용, 연간 석유사용량, 이산화탄소 배출량이 가장 낮았으며 적용, 도입 가능성이 높았다. 음식물류폐기물 처리 운영비용은 기존 처리방식과 비교하여 1톤당 334,465원(약 91%)이 절감되며 세대 당 월 1,500원인 입주자 부담 관리비용 또한 902원으로 약 40% 절감이 가능하다고 분석되었다. 각 시나리오별 초기 투자비용과 석유사용량, 이산화탄소 배출량을 비교한 결과, 초기 투자비용이 낮은 처리방식이 연료 사용량과 이산화탄소 발생량도 낮은 경향을 나타내었다. 초기 투자비용과 석유사용량, 이산화탄소 배출량이 가장 낮은 시나리오는 소규모분산처리방식이며 가장 높은 시나리오는 오수처리연계방식이었다. 연구의 공간적 범위를 공동주택 단지로 설정할 때 소규모분산처리방식이 음식물류폐기물 제로화 모델로서 가장 적합한 방식으로 판단된다.

• 국제초고층학회논문집
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• 제5권1호
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• pp.43-50
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• 2016

The reinforced-concrete multi-story shear-wall structure, which can free a building from beams and columns to allow the planning of a vast room, has increasingly been used in Japan as a high-rise reinforced-concrete structure. Since this structural system concentrates the seismic force onto multi-story shear walls inside, the bending deformation of the walls may cause excessive deformation on the upper floors during an earthquake. However, it is possible to control the bending deformation to within a certain level by setting high-strength and rigid beams (outriggers) at the top of the multi-story shear walls; these outriggers restrain the bending behavior of the walls. Moreover, it is possible to achieve high energy dissipation by placing vibration control devices on the outriggers and thus restrain the bending behavior. This paper outlines the earthquake response analysis of a high-rise residential tower to demonstrate the effectiveness of the outrigger frame incorporating vibration control devices.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2001년도 추계학술대회 논문집
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• pp.122-127
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• 2001

As pipelines are often used to transport gas, oil, water and oil products, there are more than one pipeline installed in the offshore field. The size and space of pipelines are various depending on the design specifications. The pipelines are to be designed and installed to secure the stability to external loads during the installation and operation period. The flow patterns are very complex around the pipelines being dependent on incoming flow velocity, pipelines size and space. To investigate the flow patterns, number of experiment are conducted with visualization equipment in a circulating water channel. The flow motion and trajectory were recorded from the laser reflected particles by camera. From the experiment the flow patterns around spaced pipelines were obtained. Also pressure gradient was measured by mano-meter to estimate the hydrodynamic forces on the behind pipeline. The results show that the various sizes and spaces can be affected in the estimation of external load. The complex flow patterns and pressure gradients can be effectively used in the understanding of flow motion and pressure gradient.

• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3762-3766
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• 2013

This article examines the modification of surface properties of ultrahigh-molecular-weight polyethylene (UHMWPE) with nanoscale ceramic particles to fabricate an improved composite with butadiene-nitrile rubber (BNR). Adhesion force data showed that ceramic zeolite particles on the surface of UHMWPE modulated the surface state of the polymer and increased its compatibility with BNR. Atomic force microscopy phase images showed that UHMWPE made up the microphase around the zeolite particles and formed the evolving layer with a complex interface. The complex interface resulted in improvements in the mechanical properties of the composite, especially its low-temperature resistance coefficients, thereby improving its performance in low-temperature applications.