• Title/Summary/Keyword: Complex oil

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A Study on Effects of Oil Contaminated Soil on the Growth of Plant (유류오염토양이 식물식생에 미치는 영향에 관한 연구)

  • Choi, Min-Zoo;Kim, Joo-Young;Kim, Jung-Hoon;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.15 no.1
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    • pp.50-56
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    • 2010
  • Oil contamination soil has been one of the most environmental social issues for decades in the inside and outside of country. The law of soil environmental preservation was carried out in the 1990s and the government controlled not only soil environment management and the remediation of contaminated soil but also promoted the development of remedial technology and cleanup business of contaminated soil by national policy. In addition to agriculture areas, the main oil contaminated sites are a gas station, oil reservoir, petro-chemical complex, site of railway carriage base and military camp. The contamination-frequency of agriculture area and effect sites are low but it has significantly important area on account of producing food for human beings. Therefore, we should be concerned about oil contamination damage of agriculture area. The oil contamination damage of agriculture area influenced drop of birth and breeding since the oil directly adheres to seeds and farm products even diffusion of contaminated soil to cultivation area. The studies of the crops and the food vegetation has not enough detailed data caused by the incident of oil contamination. This study investigated the effect of oil in germination and growth of selected plant seeds. In this study, we try to verify whether the oil contamination by accidents on farmland influenced the damage of farm produce and the mutual relation both oil contaminated soil or the vegetation of crops. The impact of oil on plant development was followed by phytotoxicity assessments. The plants exhibited visual symptoms of stress, growth reduction and perturbations in developmental parameters. The increase of the degree of pollution induced more marked effects in plants, likely because of the physical effects of oil. The relationships between the phytotoxicity contents of plants and growth reduction suggest a chemical toxicity of fuel oil. In addition, while cleaned up the contaminated soil under the standard of contaminated soil we examined it was suitable for region standard and it may have practical possibility for fill material of construction of afforestation and molding soil of landfill.

Elimination of Saturated Fatty Acids, Toxic Cyclic nonapeptide and Cyanogen Glycoside Components from Flax Seed Oil

  • Choi, Eun-Mi;Kim, Jeung-Won;Pyo, Mi-Kyung;Jo, Sung-Jun;Han, Byung-Hoon
    • Biomolecules & Therapeutics
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    • v.15 no.1
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    • pp.65-72
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    • 2007
  • Flax seed(Linseed, Linum usitatissimum L.) and its oil, a richest source of alpha-linolenic acid(ALA)(${\omega}-3$), contain saturated fatty acids, neurotoxic cyanogen glycosides and immuno-suppressive cyclic-nonapeptides. Present paper describes the development of two chemical processes, Process-A and -B, to remove saturated fatty acids and to destroy cyclic nonapeptides and cyanogen glycosides from flax seed oil. Process-A consists of three major steps, i.e., extraction of fatty acid mixture by alkaline saponification, removal of saturated fatty acid by urea-complexation, and triglyceride reconstruction of unsaturated fatty acid via fatty acyl-chloride activation using oxalyl chloride. Process-B consists of preparation of fatty acid ethyl ester by transesterification, elimination of saturated fatty acid ester by urea-complexation, and reconstruction of triglyceride by interesterification with glycerol-triacetate (triacetin). The destruction of lipophilic cyclic nonapeptide during saponification or transesterification processes could be demonstrated indirectly by the disappearance of antibacterial activity of bacitracin, an analogous cyclic-decapeptide. The cyanogen glycosides were found only in the dregs after hexane extraction, but not in the flax seed oil. The reconstructed triglyceride of flax seed oil, obtained by these two different pathways after elimination of saturated fatty acid and toxic components, showed agreeable properties as edible oil in terms of taste, acid value, iodine and peroxide value, glycerine content, and antioxidant activity.

Basic Experimental Study on the Application of Biofuel to a Diesel Engine (바이오연료의 엔진 적용을 위한 실험적 기초연구)

  • Yeom, Jeong-Kuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.11
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    • pp.1163-1168
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    • 2011
  • Compared with the spark-ignition gasoline engine, the compression-ignition diesel engine has reduced fuel consumption due to its higher thermal efficiency. In addition, this reduction in the fuel consumption also leads to a reduction in $CO_2$ emission. Diesel engines do not require spark-ignition systems, which makes them less technically complex. Thus, diesel engines are very suitable target engines for using biofuels with high cetane numbers. In this study, the spray characteristics of biofuels such as vegetable jatropha oil and soybean oil were analyzed and compared with those of diesel oil. The injection pressures and blend ratios of jatropha oil and diesel oil (BD3, BD5, and BD20) were used as the main parameters. The injection pressures were set to 500, 1000, 1500, and 1600 bar. The injection duration was set to $500{\mu}s$. Consequently, it was found that there is no significant difference in the characteristics of the spray behavior (spray angle) in response to changes in the blend ratio of the biodiesel or changes in the injection pressure. However, at higher injection pressures, the spray angle decreased slightly.

Complexation and Properties of Omeprazole with Hydroxypropyl-$\beta$-cyclodextrin (오메프라졸과 Hydroxypropyl-$\beta$-cyclodextrin의 포접화합물의 형성과 특성)

  • 이계주;황성주;이기명
    • YAKHAK HOEJI
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    • v.37 no.4
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    • pp.331-340
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    • 1993
  • Inclusion complex of omeprazole(OMZ) with hydroxypropyl-$\beta$-cyclodextrin(HP-$\beta$-CD) was prepared by freeze-drying method. The complexation was confirmed by means of UV, CD, IR, DSC, XRD and $^{1}$H-NMR spectra. The benzimidazole moiety of OMZ might be found to be included into the cavity of HP-$\beta$-CD and the inclusion complex appeared to be $A_{L}$ type. The stoichiometric ratio of OMZ : HP-$\beta$-CD was found to be 1:1, and the stability constants of the inclusion complex by solubility and UV method were about 34 and 45 M$^{-1}$, respectively. The dissolution of OMZ was significantly enhanced from powder and. yablet of OMZ-HP-$\beta$-CD complex when compared to those of OMZ alone, and oil-to-water partition coefficient of OMZ-HP-$\beta$-CD complex was significantly higher than that of OMZ alone. Therefore, it was expected that the bioavailability of OMZ could be improved markedly by inclusion complexation of OMZ with HP-$\beta$-CD.

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Effect of Pine Needle Extract on Fe ion and Active Oxygen Related Lipid Oxidation in Oil Emulsion (Fe ion과 활성산소 관련 지방산화반응에 미치는 솔잎 추출물의 영향)

  • 김수민;조영석
    • Food Science and Preservation
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    • v.6 no.1
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    • pp.115-120
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    • 1999
  • This study was carried out to investigate the effect of Pine needle extract on lipid oxidation and free radical reaction in iron sources reacted with active oxygen species. The results were summarized as follow; The pine needle extracts didn`t show a distinct effect on reduction of lipid oxidation if the iron ion didn`t exist in oil emulsion. The pine needle extracts played role as a strong chelating agents to bind iron ion if Ferrous iron(Fe\ulcorner) exist in oil emulsion. Ferric iron(Fe) was lower effect than Ferrous iron(Fe) on free radical reaction in oil emulsion. And also, the Fe\ulcorner reacted with pine needle extract did not show distinct effect on free radical reaction, compared to Fe\ulcorner reacted with pine needle extract. And also, Pine needle extracts reacted with H\ulcornerO\ulcorner were tended to show a low oxygen scavenging ability in case of H\ulcornerO\ulcorner only was existed, compared to those of H\ulcornerO\ulcorner + Fe\ulcorner complex. Pine needle extracts were the most powerful Fe\ulcorner binding agents, compared to other strong synthetic antioxidants such as EDTA and DTPA.

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Structural Design and Construction of High-rise Building to Feature the High-performance Oil Dampers for Vibration Control - Hibiya Mitsui Tower -

  • Kato, Takashi;Hara, Kenji;Tanaka, Hiroyuki
    • International Journal of High-Rise Buildings
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    • v.8 no.3
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    • pp.229-234
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    • 2019
  • This report introduces the structural design of Hibiya Mitsui Tower built in Tokyo Midtown Hibiya. The upper part of this tower is used for offices and the lower portion is for commercial facilities and a cinema complex which need the large open spaces. The 192m-high building has 35 floors above ground and 4 below ground. The structure is a steel frame using CFT columns to feature the high-performance oil dampers and the buckling restrained braces for vibration control. First, an outline of the structural design of this building is presented. Second, we introduce the transfer frame adopted to realize the large open spaces in the lower part, and the long column supporting the corner part of the high-rise building to avoid making a shade on the adjacent Hibiya Park, which are the feature of this building. Finally, we present an outline of the latest highly efficient semi-active oil dampers adopted in this building, and the vibration responses of this tower.

Analysis of Greenhouse Gas Reduction according to Different Scenarios of Zero Food Waste Residential Buildings (음식물류폐기물 제로화 주거단지 구축 시나리오별 비용 및 환경효과 분석)

  • Oh, Jeong-Ik;Yoon, Eun-Joo;Park, Ire;Kim, Yeong-Min
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.7
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    • pp.353-363
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    • 2016
  • In this study, traditional treatment scenario of food wastes that collected and transported food waste is recycled in large treatment facilities and suggested treatment scenario of onsite zero discharge system that food waste is treated in housing complex were supposed. The scenarios were compared and analyzed by capital expenditure, oil consumption, $CO_2$ emission quantity, operating expenditure and management expenses. The capital expenditure, oil consumption and $CO_2$ emission quantity of small scale dispersion dealing method is the lowest compared to traditional treatment method. As a results, it is possible to obtain the effect that operating expenditure was reduced by 91% and management expenses was reduced by 40% with suggested treatment method. The treatment method that have low capital expenditure is tend to lower oil consumption and $CO_2$ emission quantity. The small scale dispersion dealing method have the lowest capital expenditure, oil consumption and $CO_2$ emission quantity and the linked method with sewage treatment have the highest expenditure and $CO_2$ emission quantity. Eventually, the optimal model of onsite zero discharge system in housing complex is small scale dispersion dealing method.

High-rise Reinforced-concrete Building Incorporating an Oil Damper in an Outrigger Frame and Its Vibration Analysis

  • Omika, Yukihiro;Koshika, Norihide;Yamamoto, Yukimasa;Kawano, Kenichi;Shimizu, Kan
    • International Journal of High-Rise Buildings
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    • v.5 no.1
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    • pp.43-50
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    • 2016
  • The reinforced-concrete multi-story shear-wall structure, which can free a building from beams and columns to allow the planning of a vast room, has increasingly been used in Japan as a high-rise reinforced-concrete structure. Since this structural system concentrates the seismic force onto multi-story shear walls inside, the bending deformation of the walls may cause excessive deformation on the upper floors during an earthquake. However, it is possible to control the bending deformation to within a certain level by setting high-strength and rigid beams (outriggers) at the top of the multi-story shear walls; these outriggers restrain the bending behavior of the walls. Moreover, it is possible to achieve high energy dissipation by placing vibration control devices on the outriggers and thus restrain the bending behavior. This paper outlines the earthquake response analysis of a high-rise residential tower to demonstrate the effectiveness of the outrigger frame incorporating vibration control devices.

A Study of Flow Pattern around the Two-Dimensional Dual Subsea Pipeline on Sea Bottom (해저면에 설치된 2차원 복합해저관로 주위의 유동특성에 관한 실험적 연구)

  • 나인삼;조철희;정우철;김두홍
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2001.10a
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    • pp.122-127
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    • 2001
  • As pipelines are often used to transport gas, oil, water and oil products, there are more than one pipeline installed in the offshore field. The size and space of pipelines are various depending on the design specifications. The pipelines are to be designed and installed to secure the stability to external loads during the installation and operation period. The flow patterns are very complex around the pipelines being dependent on incoming flow velocity, pipelines size and space. To investigate the flow patterns, number of experiment are conducted with visualization equipment in a circulating water channel. The flow motion and trajectory were recorded from the laser reflected particles by camera. From the experiment the flow patterns around spaced pipelines were obtained. Also pressure gradient was measured by mano-meter to estimate the hydrodynamic forces on the behind pipeline. The results show that the various sizes and spaces can be affected in the estimation of external load. The complex flow patterns and pressure gradients can be effectively used in the understanding of flow motion and pressure gradient.

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Enhancement of Compatibility between Ultrahigh-Molecular-Weight Polyethylene Particles and Butadiene-Nitrile Rubber Matrix with Nanoscale Ceramic Particles and Characterization of Evolving Layer

  • Shadrinov, Nikolay V.;Sokolova, Marina D.;Okhlopkova, A.A.;Lee, Jungkeun;Jeong, Dae-Yong;Shim, Ee Le;Cho, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3762-3766
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    • 2013
  • This article examines the modification of surface properties of ultrahigh-molecular-weight polyethylene (UHMWPE) with nanoscale ceramic particles to fabricate an improved composite with butadiene-nitrile rubber (BNR). Adhesion force data showed that ceramic zeolite particles on the surface of UHMWPE modulated the surface state of the polymer and increased its compatibility with BNR. Atomic force microscopy phase images showed that UHMWPE made up the microphase around the zeolite particles and formed the evolving layer with a complex interface. The complex interface resulted in improvements in the mechanical properties of the composite, especially its low-temperature resistance coefficients, thereby improving its performance in low-temperature applications.