• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.366-370
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• 2016

A platinum(II) pincer complex composed of two six-membered fused metallacycles was directly synthesized using 1,3-bis(2-pyridyloxy)benzene and $K_2PtCl_4$. The structure of the complex was elucidated via NMR and X-ray crystallography analysis. The stable complex was formed due to the six-membered fused cycle structure around the Pt(II) center which reduced the bond angle strain. The complex was applied to the silylcyanation reaction of aldehydes and imines and showed an efficient catalytic activity with 99% yield.

• Bulletin of the Korean Chemical Society
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• v.22 no.4
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• pp.379-382
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• 2001

A new ligand containing the long aliphatic hydrocarbon chain, dipyridylstearylamine (dps) and its copper(Ⅱ) complex, Cu(dps)(NO3)2 have been prepared. The copper complex was characterized structurally and spectroscopically. The XRD crystal structure of the copper complex reveals that copper is octahedrally coordinated by dps and two nitrato ligands. The nitrato groups ligate asymmetrically to the copper. Crystal data are P1bar, a=8.249(2), b=10.416(3), $c=20.915(4)\AA$, $\alpha=86.54(2)$, $\beta=84.026(2)$, $\gamma=72.32(2)^{\circ}$, V=1702.7(7) $\AA3$ , Z=2, ${\lambda}$(Mo $K\alpha)=0.71073\AA$, $\mu=0.689$ mm-1 , T=293(2) K, R=0.0560 for 3529 reflections. The dps and the copper complex are stable in the air and the copper complex exhibits features of typical of other copper(Ⅱ) complexes containing dipyridylamine-based ligand.

• Journal of KSNVE
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• v.4 no.2
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• pp.155-161
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• 1994

The dynamic behavior of a complex mechanical structure can be identified by dividing the structure into a series of smaller structure, called sub- structure and by studying the dynamic characteristics of these components. Generally, the dynamic characteristics of mechanical structure are strongly affected by the properties of joint parameters. In this paper, to identify the dynamic characteristics of mechanical structure, and experimental identification method in which directrly measured frequency response function(FRF) is used is considered. The method does not use the procedure of complex matrix calculation but use that of real matrix calculation. To confirm this method, computer simulation is performed by using frequency response function mixed with noise, and the experimental study is performed about the simple structure. The dynamic characteristics of joint parameters and identified more accurately than in using the prcedure of complex matrix calculation.

• Analytical Science and Technology
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• v.20 no.5
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• pp.448-451
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• 2007

A new bis(dicyclohexylammonium) chromate dihydrate complex, $[(C_6H_{11})_2NH_2]_2[CrO_4]{\cdot}2H_2O$, (I), has been synthesized and its structure analyzed by FT-IR, EDS, elemental analysis, ICP-AES, and single crystal X-ray diffraction methods. The Cr(VI) complex (I) is tetragonal system, I${\bar{4}}$2d space group with a = 12.5196(1), b = 12.5196(1), c = $17.3796(3){\AA}$, a = ${\beta}$ = ${\gamma}$ = $90^{\circ}$, V = $2724.09(6){\AA}^3$, Z = 4. The crystal structure of complex (I) consists of tetrahedral chromate $[CrO_4]^{2-}$ anion, two organic dicyclohexylammonium $[(C_6H_{11})_2NH_2]^+$ cations and two lattice water molecules. The chromate anion and protonated dicyclohexylammonium cation is mainly constructed through the ionic bond. The cyclohexylammonium rings of the dicyclohexylammonium cation take the chair form and vertical configuration with each other. The N-H${\cdot}$O and O-H${\cdot}$O hydrogen bond networks between the $N_{dicyclohexylammonium}$, $O_{water}$ and $O_{chromate}$ atom lead to self-assembled molecular conformation and stabilize the crystal structure.

• Bulletin of the Korean Mathematical Society
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• v.50 no.6
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• pp.2089-2101
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• 2013

The aim of this paper is to introduce the notion of Lie recurrent structure Jacobi operator for real hypersurfaces in non-flat complex space forms and to study such real hypersurfaces. More precisely, the non-existence of such real hypersurfaces is proved.

• Bulletin of the Korean Mathematical Society
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• v.45 no.3
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• pp.495-507
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• 2008

In this paper we give a complete classification of real hyper-surfaces in complex two-plane Grassmannians $G_2({\mathbb{C}}^{m+2})$ with commuting structure Jacobi operator $R_{\xi}$ and another geometric condition.

• Journal of applied mathematics & informatics
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• v.39 no.3_4
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• pp.327-338
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• 2021

In this paper, we have introduced a new notion of recurrent structure Jacobi of real hypersurfaces in complex hyperbolic two-plane Grassmannians G^*₂(ℂ^m+2). Next, we show a non-existence property of real hypersurfaces in G^*₂(ℂ^m+2) satisfying such a curvature condition.

• The Pure and Applied Mathematics
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• v.28 no.3
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• pp.247-252
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• 2021

Let M be a real hypersurface in a complex space form M_n(c), c ≠ 0. In this paper, we prove that if (∇_Xϕ)Y + (∇_Yϕ)X = 0 holds on M, then M is a Hopf hypersurface, where ϕ is the tangential projection of the complex structure of M_n(c). We characterize such Hopf hypersurfaces of M_n(c).

• Bulletin of the Korean Mathematical Society
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• v.59 no.4
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• pp.801-810
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• 2022

In this paper, we prove that any orthogonal almost complex structure on a warped product manifold of any oriented closed surface and a round 4-sphere for a concircular warping function on the sphere is never integrable. This gives a partial answer to Calabi's problem.

• Honam Mathematical Journal
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• v.31 no.2
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• pp.185-201
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• 2009

Let M be a real hypersurface with almost contact metric structure $({\phi},{\xi},{\eta},g)$ of a nonflat complex space form whose structure Jacobi operator $R_{\xi}=R({\cdot},{\xi}){\xi}$ is ${\xi}$-parallel. In this paper, we prove that the condition ${\nabla}_{\xi}R_{\xi}=0$ characterize the homogeneous real hypersurfaces of type A in a complex projective space $P_n{\mathbb{C}}$ or a complex hyperbolic space $H_n{\mathbb{C}}$ when $g({\nabla}_{\xi}{\xi},{\nabla}_{\xi}{\xi})$ is constant.