• 제목/요약/키워드: Complex I

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염료감응 태양전지의 성능을 위한 녹말의 영향 (Influence of starch on the performance of dye-sensitized solar cells)

  • 정영삼;배준석;정원철;김동환;윤수용;김서현
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.51-51
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    • 2011
  • 1991년 스위스연방기술원(EPFL) 화학과 교수 Michae Gratzel이 발명한 염료감응 태양전지 (DSSC)는 값싼 원료와 저가공비 면에서 가장 경쟁력 있는 기술의 하나로 큰 기대를 받고 있다. 염료감응 태양전지의 특징은 전극기판의 재료나 염료를 바꿈으로서 형상이나 색체에 다양성을 갖도록 할 수 있다. 일반적인 염료감응 태양전지의 원리는 태양광이 염료 분자에 흡수, 염료는 여기상태가 되어 전자를 n형 반도체인 $TiO_2$의 전도대로 흘리고, 전자는 TCO전극으로 이동하여 외부 부하에 전기 에너지를 전달하고 상대전극으로 이동, 염료는 $TiO_2$에 전달한 전자 수만큼 전해질로부터 전자를 공급 받아 원래의 상태로 돌아가게 되는 원리에 의하여 발전된다. 전해질로는 $I^-/I_3^-$와 같이 산화-환원 종으로 구성되어 있으며, $I^-$ 이온의 source로는 LiI, NaI,이미다졸리움 요오드 등이 사용되며, $I_3^-$는 이온은 $I_2$를 용매에 녹여 생성시킨다. 전해질 매질은 acetonitrile과 같은 액체 또는 PVdF와 같은 고분자가 사용될 수 있다. 액체형의 경우 산화-환원 이온 종이 매질 내에서 신속하게 움직여 염료의 재생을 원활하게 도와주기 때문에 높은 에너지 변환 효율이 가능하지만, 전극 간의 접합이 완벽하지 못할 경우 누액의 문제를 가지고 있다. 반면, 고분자를 매질로 채택할 경우에는 누액의 염료는 없지만 산화-환원 종의 움직임이 둔화되어 에너지 변환 효율에 나쁜 영향을 줄 수 있다. 따라서 고분자 전해질을 사용할 경우에는 산화-환원 이온 종이 매질 내에서 신속하게 전달 될 수 있도록 설계하는 것이 필요하다. 본 연구는 염료감응 태양전지에서 가장 큰 문제가 되고 있는 고체 전해질의 산화-환원 이온 종이 매질 내에서 신속하게 전달 될 수 있도록 dimethylsulfoxide solvent 에 녹말 일정량을 녹여 Starch-$I_2$ complex 를 시켜주므로, 광 전압{\cdot}{\cdot}$전가 증가되었으며, 전지의 안정성이 향상되었다.

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은나노입자의 방사성 동위원소 운반체 적용 유효성 검증 연구 (Feasibility Study on Silver Nanoparticle Application to a Radioisotope Carrier)

  • 장범수;이주상;박해준;김화정;박상현
    • 방사선산업학회지
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    • 제5권3호
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    • pp.197-202
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    • 2011
  • In this study, an Ag-polyaniline-silica (Ag-PANI-silica) nanoparticle was evaluated as a radioisotope carrier. An Ag-PANI-silica nanoparticle was incubated in the $^{125}I$ solution for a duration of 24 hr to test its radioisotope absorptivity. During the incubation, radioactivity of the nanoparticle was measured at 3, 6, 12, and 24 hr. After a 24 hr incubation, $^{125}I$-Ag-PANI-silica nanoparticle was incubated in a fresh saline for a duration of 48 hr to check its stability. Additionally, the $^{125}I$-Ag-PANI-silica nanoparticle was injected to the ICR mouse to investigate its in-vivo distribution characteristics. The $^{125}I$ absorption yield of the Ag-PANI-silica nanoparticle was higher than 95% after a 6 hr incubation period in the $^{125}I$ solution. And $^{125}I$-Ag-PANI-silica was stable for 48 hr at 80% yield at room temperature. The SPECT/CT image of a mouse that received $^{125}I$-Ag-PANI-silica complex showed that the $^{125}I$-Ag-PANI-silica complex was distributed in the lung, stomach and thyroid at 30 min post injection. From these results, the Ag-PANI-silica nanoparticle has good radio-iodine carrying property and can be applicable for the purpose of diagnosis and therapy.

Structural basis of Ca2+ uptake by mitochondrial calcium uniporter in mitochondria: a brief review

  • Jiho, Yoo
    • BMB Reports
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    • 제55권11호
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    • pp.528-534
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    • 2022
  • Mitochondria are cellular organelles that perform various functions within cells. They are responsible for ATP production, cell-signal regulation, autophagy, and cell apoptosis. Because the mitochondrial proteins that perform these functions need Ca2+ ions for their activity, mitochondria have ion channels to selectively uptake Ca2+ ions from the cytoplasm. The ion channel known to play the most important role in the Ca2+ uptake in mitochondria is the mitochondrial calcium uniporter (MCU) holo-complex located in the inner mitochondrial membrane (IMM). This ion channel complex exists in the form of a complex consisting of the pore-forming protein through which the Ca2+ ions are transported into the mitochondrial matrix, and the auxiliary protein involved in regulating the activity of the Ca2+ uptake by the MCU holo-complex. Studies of this MCU holo-complex have long been conducted, but we didn't know in detail how mitochondria uptake Ca2+ ions through this ion channel complex or how the activity of this ion channel complex is regulated. Recently, the protein structure of the MCU holo-complex was identified, enabling the mechanism of Ca2+ uptake and its regulation by the MCU holo-complex to be confirmed. In this review, I will introduce the mechanism of action of the MCU holo-complex at the molecular level based on the Cryo-EM structure of the MCU holo-complex to help understand how mitochondria uptake the necessary Ca2+ ions through the MCU holo-complex and how these Ca2+ uptake mechanisms are regulated.

Incidence and Intensity of Root Disease Complex due to Nematode and Soilborne Fungal Pathogens in Mulberry (Morus alba L.)

  • Naik, Vorkady Nishitha;Sharma, Dinesh Dutta;Govindaiah, Govindaiah
    • International Journal of Industrial Entomology and Biomaterials
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    • 제16권2호
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    • pp.49-56
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    • 2008
  • A preliminary survey on the incidence and intensity of root disease complex (association of Meloidogyne incognita and root rot pathogens) was carried out in the sericultural areas of Karnataka. A total of 280 mulberry gardens were surveyed in 14 districts of Karnataka belonging to different types of soil (red sandy, red loamy and black cotton), farming systems (irrigated and rainfed), varieties (V-1, K-2, Local and S-13) and age of the plants (0-5, 5-10 and 10-15 years). It was observed that the association of M. incognita with Botryodiplodia theobromae and Fusarium solani causes the root disease complex in mulberry. Of the 280 gardens visited, 94 were infested with the disease complex and incidence was recorded as 33.6%. The higher intensity of root disease complex was observed when the root system had more than 100 galls/plant with infection of mixed population of B. theobromae and F. solani in sandy soil under irrigated farming. The 5-10 years old mulberry plantation with V-I variety was found to be most susceptible to root disease complex. Districts like Mysore, Kolar, Mandya, Tumkur, Chitradurga and Bangalore were observed as sensitive areas. Further, the wounds caused by M. incognita in mulberry roots favour the easy entry of root rot pathogens, which increased the severity of the disease very fast.

New Yeast Cell-Based Assay System for Screening Histone Deacetylase 1 Complex Disruptor

  • Jeon, Kwon-Ho;Kim, Min-Jung;Kim, Seung-Young
    • Journal of Microbiology and Biotechnology
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    • 제12권2호
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    • pp.286-291
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    • 2002
  • Histone deacetylase I (HDAC1) works as one of the components in a nucleosome remodeling (NuRD) complex that consists of several proteins, including metastasis-associated protein 1 (MTA1). Since the protein-protein interaction of HDAC1 and MTA1 would appear to be important for both the integrity and functionality of the HDAC1 complex, the interruption of the HDAC1 and MTA1 interaction may be an efficient way to regulate the biological function of the HDAC1 complex. Based on this idea, a yeast two-hybrid system was constructed with HDAC1 and MTA1 expressing vectors in the DNA binding and activation domains, respectively. To verify the efficiency of the assay system, 3,500 microbial metabolite libraries were tested using the paper disc method, and KB0699 was found to inhibit the HDAC1 and MTA1 interaction without any toxicity to the wild-type yeast. Furthermore, KB0699 blocked the interaction of HDAC1 and MTA1 in an in vitro GST pull down assay and induced morphological changes in B16/BL6 melanoma cells, indicating the interruption of the HDAC1 complex function. Accordingly, these results demonstrated that the yeast assay strain developed in this study could be a valuable tool for the isolation of a HDAC1 complex disruptor.

복잡지형의 대기확산모델 비교 (Comparison of Complex Terrain Dispersion Models)

  • 김영성;오현선
    • 한국대기환경학회지
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    • 제14권2호
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    • pp.81-94
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    • 1998
  • Six complex terrain dispersion models recommended by the U. S. Environmental Protection Agency were investigated using a hypothetical case in which a plume approaches complex terrain. The six models considered were Valley, CTSCREEN, COMPLEX 1, SHORTZ, RTDM, and CTDMPLUS, the latter four being closely studied. Highest concentrations were predicted for 48 receptors and plume behaviors were compared for stable and unstable meteorological conditions. Under stable conditions, ground-level concentrations were determined by the height of the plume centerline above the terrain. The concentrations estimated by SHORTZ and COMPLEX I were higher than those estimated by CTSCREEN, with CTDMPLUS predicting the lowest concentrations. In particular, the height of the lift midpoint, as well as the co.nterline of the plume, are important in the model calculation of CTDMPLUS. Under unstable conditions, the vertical dispersion plays a key role in determining ground -level concentrations. For this case, concentrations predicted by CTDMPLUS were the 'highest, whereas those predicted by SHORTZ were the lowest. Concentration distributions predicted by CTDMPLUS are quite similar to typical Gaussian distributions even on complex terrain, except for a slight shift of the plume centerline due to the of(tract of the geostrophic wind. In addition,24-hour average concentrations were estimated for comparison with results from the Valley model. Among the four models studied closely, CTDMPLUS predicted the lowest 24-hour average concentrations, but the concentrations estimated by Valley were lower than those estimated by CTDMPLUS.

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