• Title/Summary/Keyword: Complex Formation

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Biotreatment Technologies for Air Pollution Control (생물학적 처리기술을 이용한 대기오염 제어)

  • Won, Yang-Soo
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.1-15
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    • 2007
  • Biological treatment is a relatively recent air pollution control technology in which off-gases containing biodegradable odors and volatile organic compounds(VOCs) are vented through microbes. It is a promising alternative to conventional air pollution control methods. Bioreactors for air pollution control have found most of their success in the treatment of dilute and high flow waste air streams containing VOCs and odor compounds. They offer several advantages over traditional technologies such as incineration or adsorption. These include lower treatment costs, absence of formation of secondary pollutants, no spent chemicals, low energy demand and low temperature treatment. The three most widely used technologies are described, namely biofiltration, biotrickling filtration, bioscrubbing. The most widely used bioreactor for air pollution control is biofilter, but it has several limitations. In the past years major progress has been accomplished in the development of vapor phase bioreaction systems, for solving problems of biofilter. Biotrickling filters are more complex than biofilters, but are usually more effective, especially for the treatment of compounds which are difficult to degrade or compounds that generate acidic by-products. This, paper reviews fundamental and theoretical/practical aspect of air pollution control in biofilter, biotrickling filter and bioscrubber, focusing more extensively on biotrickling filtration. Special emphasis is given to the operating parameters and the factors influencing performance for air pollution control, and cost estimation in biotreatment technologies.

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Antimicrobial and Antioxidative Activities of Solvent Fraction from Humulus japonicus (환삼덩굴의 용매분획별 항균성 및 항산화성)

  • Park, Seung-Woo;Woo, Cheol-Joo;Chung, Shin-Kyo;Chung, Ki-Taek
    • Korean Journal of Food Science and Technology
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    • v.26 no.4
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    • pp.464-470
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    • 1994
  • The biological activities of Humulus japonicus were extracted by water and methanol. Methanol was better solvent than water in the extraction for antimicrobial activities against six different species of bacteria and two yeasts. The methanol extract was systematically fractionated with various organic solvents which have different polarities. From the result of antimicrobial activities against six species of bacteria and two species of yeasts, methanol extract was superior to water extract. The methanol extract of Humulus japonicus showed antimicrobial activity against the all species of microorganisms tested except Escherichia coli . The butanol fraction of methanol extract showed antimicrobial effect on the all species tested. The minimal inhibition concentration(MIC) of the butanol fraction on the growth of microorganisms was ranged between $0.1{\sim}0.4%$. The water extract of Humulus japonicus did not show inhibition of the activity of trypsin but methanol extract showed inhibitory activity. The chloroform fraction of methanol extract showed comparatively higher trypsin inhibitory activity than other fractions. The concentration of 50% inhibition$(IC_{50})$ by chloroform fraction was 1.0 mg/ml. Enzyme-inhibitor complex formation was above 90% of the while for 20 min. It was revealed that methanol extract of Humulus japonicus inhibited peroxide production of lard and soybean oil as substrate by antioxidative test. The chloroform fraction of methanol extract had the highest activity. When 0.2% of chloroform fraction was added, induction period of soybean oil and lard were extended 15, 9 days, respectively.

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REE Mineralization of Quy Hop Area in Nghe An Province, Northern Vietnam (베트남 북부 네안성 뀌홉지역 희토류 광화작용)

  • Lee, Jae-Ho;Jin, Kwang-Min;Heo, Chul-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.3
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    • pp.193-213
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    • 2018
  • Soil geochemical exploration to check anomalies related to mineralization was carried out targeting around Quy Hop area within Nghe An province, Northern Vietnam. The interval of sampling are horizontal 250 m with 13 line and longitudinal 300 m with 25 line, resulting in 325 soil samples. Based on the result of soil geochemical exploration, the pitting survey was carried out targeting the grid point with high TREO content, resulting in 73 soil samples within 8 pits. The geology of the survey area are consisted of Ban Chieng biotite granite complex intruding Bu Khang formation comprising of schist, gneiss and limestone. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. By ICP-MS result of soil samples, total REE oxide content of background amount is about 1.4 times of crustal abundance, depleting the light rare earth (about 0.2 times) and enriching the heavy rare earth (about 1.5 times). By ICP-MS result of pit soil samples, we identified TREO more than 1,000 ppm in 6 pits. It may be considered that REE ore bodies may develop in NE-SW direction, compared with the geochemical results of Quy Chau area.

Morphological Characteristics of Ocean Core Complexes (OCC) in Central Indian Ridge Using High-Resolution Bathymetry and Backscatter Intensity Data from a Deep-Towed Vehicle (심해예인 고해상도 수심 자료와 후방산란 강도 자료를 이용한 인도양 중앙해령 내 Ocean Core Complex 구조의 지형적 특성 분석)

  • Hwang, Gyuha;Kim, Seung-Sep;Son, Seung Kyu;Kim, Jonguk;Ko, Youngtak
    • Ocean and Polar Research
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    • v.42 no.1
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    • pp.49-61
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    • 2020
  • We analyzed the morphological characteristics of OCC (Ocean Core Complexes) in the middle part of the Central Indian Ridge (MCIR) using high-resolution geophysical data recorded on the Deep-Tow SideScan Sonar IMI-30 system. In terms of slope-gradient variations calculated from the high-resolution bathymetry data, the normal faults formed by seafloor spreading were associated generally with slopes > 30° and resulted in high backscatter intensities, which reflect more topographic effects than acoustic medium variation. However, the areas associated with gentle slopes < 10° tend to show the backscatter intensities reflecting the acoustic characteristic of the medium. We show that the detachment faults exposing the OCCs were initiated with high-angle normal faults (58°) exhibiting outward and inward dips of a breakaway zone. In order to examine the spatial distribution of OCC structures, we characterized the transition from magmatic-dominant seafloor with abyssal hills to tectonic-dominant seafloor with OCC using the down-slope direction variation. The slope direction of the seafloor generally tends to be perpendicular to the ridge azimuth in the magmatic-dominant zone, whereas it becomes parallel to the given ridge azimuth near the OCC structures. Therefore, this spatial change of seafloor slope directions indicates that the formation of OCC structures is causally associated with the tectonic-dominant spreading rather than magmatic extension. These results also suggest that the topographical characteristics of seafloor spreading and OCC structures can be distinguished using high-resolution geophysical data. Thus, we propose that the high-resolution bathymetry and backscatter intensity data can help select potential areas of exploitation of hydrothermal deposits in MCIR effectively.

Effect of Saline Concentrations on Biological Nitrification in Batch Reactor

  • Lee, Young Joon;Nguyen, Viet Hoang;Nguyen, Hong Khanh;Pham, Tuan Linh;Kim, Gi Youn
    • Journal of Integrative Natural Science
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    • v.4 no.2
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    • pp.103-112
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    • 2011
  • This study was carried out on 4 batch reactors to determine the specific ammonium oxidizing rate (SAOR), specific nitrate forming rate (SNFR) and inhibitory degree of nitrifying activities with saline concentrations. Under salt free condition ammonia was consumed during the reaction period within 200 min. When the salt level increased to 10, 20 and 30 g $NaClL^{-1}$ in reactor, ammonia depletion took 250, 300 and above 350 min, respectively. During concentration above 10 g $NaClL^{-1}$, there was nitrite accumulation. Also, at 30 g $NaClL^{-1}$ ammonia did not depleted and $NO_2{^-}$-N accumulated until the final reaction. Nitrate formation rates decreased with increasing salt concentration. SAOR and SNFR showed a decreasing trend as salinity concentrations were increased. The SAOR was reduced from 0.2 to 0.08 mg $NH_4{^+}$-N $g^{-1}VSS\;day^{-1}$ as the salt concentration increased from 0 to 30 g $NaClL^{-1}$. Similarly, the SNFR decreased from 0.26 kg $NO_3{^-}$-N $kg^{-1}VSS\;day^{-1}$ at saline free to 0.1 kg $NO_3{^-}$-N $kg^{-1}VSS\;day^{-1}$ at saline 30 g L-1. A severe inhibition of nitrifiers activity was observed at increased salt concentrations. The inhibition ratio of specific ammonium oxidation rates were 17, 47 and 60% on the reactor of 10, 20 and 30 g $NaClL^{-1}$ added, respectively. The inhibition ratio of specific nitrate forming rates also were inhibited 30, 53 and 62% on the reactor of 10, 20 and 30 g $NaClL^{-1}$ added, respectively. As the salinity concentrations increased from 0 to 30 mg $NaClL^{-1}$, the average MLSS concentration increased from 1,245 to 1,735 $mgL^{-1}$. The SS concentration of supernatant in reactor which settled about 30 minutes was not severely difference between concentration of salt free reactor and one of those high salt contained reactors.

Citrate Complexes of Alkaline Earth Metals in Aqueous, Acetone-Water and Ethanol-Water Solutions (수용액, 물-아세톤 및 물-에탄올 혼합 용매 내에서 형성되는 알칼리토류금속의 시트르산 착물)

  • Choi, Sang-Up;Pae, Young-Il;Jae, Won-Mok
    • Journal of the Korean Chemical Society
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    • v.14 no.1
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    • pp.65-74
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    • 1970
  • Formation of the complexes of alkaline earths with citrate ions in aqueous, acetone-water and ethanol-water solutions was studied at room temperature by the equilibrium exchange technique. This technique involved the measurements of distribution of radioactivity between cation exchange resin and solution phase after the radioactive metal ions were equilibriated with the cation exchange resin in the presence of citrate ions ($Cit^{3-}$) of varying concentrations. The pH of the solutions was controlled to 7.2-7.5, and the ionic strength of the solutions was kept at 0.10-0.12. The present study revealed that both barium and strontium ions formed the one to one citrate complexes, $[M Cit]^-$ in all solvent systems examined. It was also observed that calcium ions formed the one to one citrate complex in aqueous solution. In acetone-water and ethanol-water solutions, however, calcium ions were observed to form both one to one and one to two complexes, $[Ca Cit]^-$ and $[Ca\;Cit_2]^{4-}$. The results of the present study indicated also that relative stabilities of the complexes increased in the order; $Ba^{++}\;<\;Sr^{++}\;<\;Ca^{++}$, and in the order of increasing concentration of the organic components in the mixed solvent systems.

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Abberant Root Morphology in the Permanent First Molars : Case Reports (제1대구치에서 관찰되는 비정형적 치근형태에 대한 증례보고)

  • Lee, Eunkyoung;Kim, Youngjin;Kim, Hyunjung;Nam, Soonhyeun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.42 no.2
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    • pp.172-179
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    • 2015
  • The developmental mechanism of root formation is a complex process. Hereditary and environmental factors may affect the morphology of the developing root. A total of 12 cases was presented with permanent first molars with abberant root morphology. Clinically, these teeth appeared as a normal crown. However, radiographically, the root was slender, twisted and characterized by irregular lengths. In addition, root trunk length was shorter and pulp chamber was obliterated. In these cases, periapical radiolucency and loss of lamina dura were often observed. In 6 cases, an abnormal root of the primary second molars were also present, as well as root malformation of permanent first molars. In 3 cases, permanent central incisors also had a dysmorphic crown. These cases almost all had medical history, such as premature birth, brain infection or congenital heart disease in infants. The present paper describes cases of permanent first molars with an abnormal root that are rarely reported in literature. This case may intensify the variation in the permanent first molar and is intended to reinforce the clinician's awareness of rare morphology of the roots.

Electronic Structure of Iron and Molybdenum in $Li_2FeMoO_4Cl$ and Its Crystal Symmetry ($Li_2FeMoO_4Cl$의 결정구조와 Fe 및 Mo의 전자구조 연구)

  • Choy, Jin-Ho;Park, Nam-Gyu;Chang, Soon-Ho;Park, Hyung-Ho
    • Journal of the Korean Chemical Society
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    • v.39 no.6
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    • pp.446-452
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    • 1995
  • Lithium intercalates, $Li_xFeMoO_4Cl$ ($1{\leq}X{\leq}2$) prepared by electrochemical lithiation of $FeMoO_4Cl$ crystallizes in monoclinic structure for all x values as revealed by x-ray diffraction and galvanostatic discharge experiments. According to the x-ray photoelectron spectroscopic study, Fe(III) is at first reduced to Fe(II) upon lithium intercalation with the x domain of $0{\leq}X{\leq}1$, where the crystal symmetry is changed from tetragonal to monoclinic. On the other hand, Mo(VI) is reduced to lower valent state upon further lithium intercalation ($1{\leq}X{\leq}2$), where no crystal symmetry transformation and reduction of Fe(II) to lower valent state are observed. The Mo 3d spectrum for $Li_2FeMoO_4Cl$ appears as a complex shape, but can be deconvoluted into the three sets of the doublet on the basis of Gaussian function, those which correspond to Mo(VI), Mo(V) and Mo(IV) states, respectively. The mixed valent states of molybdenum after further lithiation may be due to a competitive reaction between the formation of Mo(V) and its disproportionation to Mo(IV) and Mo(VI).

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A Comparison Study on Kyedan of Korea Buddhist Temple and Kyedandokyung (한국(韓國) 불교사원(佛敎寺院)의 계단(戒壇)과 계단도경(戒壇圖經)의 비교(比較) 연구(硏究))

  • Park, Eon-Kon;Lee, Jae-In;Choi, Hyo-Sik
    • Journal of architectural history
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    • v.16 no.2
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    • pp.99-118
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    • 2007
  • Kyedan(戒壇) is an altar to perform a rite of Buddhist Initiation which gives Precept to a Buddhist monk. Sometimes it is called the Place of Precept and Mandala by Sanskrit. In this study, the Sutra of the Tang(唐) Dosun(道宣) regarding First Kyedan of Jetavana-anathapindasyarama(祇園精舍), which was the first temple such as, Kyedandokyung(戒壇圖經), Kiwonsadokyung(祇洹寺圖經), Sabunyul(四分律) were analyzed to find out original form and layout. Ultimately, the study was intended to examine the spatial formation-principle by comparing with Kyedan Temple. The results of this study could be summarized as below. First. Except for Kyedan in Bakryensa, the height of lower stone plate of Buddhist Bell-Shaped Stupa of Korean Kyedan is higher than three storied Kyedan that described in Kyedandokyung. Second. Buddhist Bell-Shaped Stupa above Kyedan was presumed that embodied image of Bell Pedestal and symbolism of overturned-bowl were combined together, when Kyedandokyung and Kiwonsadokyung were referred. It could be examined by the existence of stone lantern. Third. In Korea, the rite of Buddhist initiation that gives Precept in Kyedan has been considered impossible. However, when the rite was conducted, there was a possibility to establish wood stair. It is because that the Buddhist Stupa of Silleuuksa(神勒寺) and Woljeongsa(月精寺), which reflected the image of Kyedan had stone stair. Fourth, The method to build Kyedan of Dosun divided into Large Region and Small Region was applied to the method to construct Stone terrace behind Jeongmyeolbogung(寂滅寶宮) like Tongdosa(通度寺) and complete Kyedan on the stone terrace. In other words, Jeongmyeolbogung became Kyedanwon(戒壇院) and Kyedan, itself became Small Region. The area of Stone terrace became Large Region and naturally, they constituted an Institution. Fifth, Korean Kyedan which is consist of Jeongmyeonlbogung and Kyedan is a Korean original composition principles of Kyedangaram(戒壇伽藍) that can satiate all the functions of Kyedan as a religious subject and the place of the rite of Buddhist initiation, as it had complex of Outdoor Kyedan, which was suggested by the sutra of Dosun and Institution of Kyedan.

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A Newer Short Synthesis of dl-Muscone(Ⅰ) (새로운 짧은 경로로의 dl-Muscone 합성(Ⅰ))

  • Im, D.S.;Shin, D.H.;Park, D.K.
    • Journal of the Korean Chemical Society
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    • v.40 no.4
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    • pp.243-248
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    • 1996
  • New routes have been developed for the practical syntheses of dl-Muscone(1) employing cyclopentadecanone(2) as the starting material. In this experiment, addition of bromine to cyclopentadecanone in dried E. Ether solution with a trace of $AlCl_3$ as the catalyst were produced 2-bromocyclopentadecanone(3). This process was enhanced formation of regioselective enolate anion at $C_2$ position. 2-Bromocyclopentadecanone was put into $Li_2CO_3$-LiBr-DMF solution at 140∼150$^{\circ}C$, were produced trans- and cis-2-cyclopentadecen-1-one(4) mixture. Other by-products were reduced by control of reaction temperature and time. Trans- and cis-2-cyclopentadecen-1-one(4) mixture was directly put into dried E. Ether solvent and induce to react dropwise with $CH_3MgBr-Cu_2Cl_2$ complex, all of them got into 1,4-addition, dl-Muscone (1) was formed as the result. Conculsion, through three steps procedure from cyclopentadecanone(2) to dl-Muscone(1), the pure dl-Muscone was obtained with the high proportion of 85%, and synthetic cost was able to be much lower than any other conventional methods as there were no chemical separating steps.

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