• Title/Summary/Keyword: Complex Conductivity

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Dielectric Properties depending on Frequency in ITO/$Alq_3$/Al (ITO/$Alq_3$/Al의 주파수 변화에 따른 유전 특성)

  • Oh, Y.C.;Lee, D.K.;Kim, J.S.;Shin, C.G.;Lee, S.I.;Kim, C.H.;Kim, T.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.292-293
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    • 2006
  • We have Investigated dielectric properties depending on bias voltage in organic lightemitting diodes using 8-hydroxyquinoline aluminum($Alq_3$) as an electron transport and emissive material. We analyzed the dielectric properties of organic light emitting diodes using impedance characteristics measurement by the auto-balancing bridge technique and equivalent cirrcuit of ITO/$Alq_3$/Al. Impedance characteristics was measured complex impedance Z and phase ${\theta}$ in the frequency range of 40 [Hz] to $10^8$ [Hz]. We obtained complex electrical conductivity, dielectric constant, and loss tangent ($tan{\delta}$) of the device at room temperature. From these analyses, we are able to interpret a conduction mechanism and dielectric properties contributed by an interfacial and orientational polarization.

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Dielectric Properties depending on Frequency in Organic Light-emitting Diodes using $Alq_3$ (Alq3를 이용한 유기 발광 소자의 주파수에 변화에 따른 유전 특성)

  • Oh, Y.C.;Lee, D.K.;Chung, D.H.;Lee, H.S.;Park, G.H.;Kim, T.W.;Lee, J.U.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.293-294
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    • 2005
  • We have investigated dielectric properties depending on frequency in organic light -emitting diodes using 8-hydroxyquinoline aluminum ($Alq_3$) as an electron transport and emissive material. We analyzed the dielectric properties of organic light-emitting diodes using impedance of characteristics. impedance characteristics was measured complex impedance Z and phase $\Theta$ in the frequency range of 40 Hz to $10^8$ Hz. We obtained complex electrical conductivity, dielectric constant, and loss tangent (tan$\delta$) of the device at room temperature. From these analyses, we are able to interpret a conduction mechanism and dielectric properties contributed by an interfacial and orientational polarization.

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Fabrication of Ultra Thin Films with (N-docosyl pyridinium)-TCNQ(1:2) Complex by the Langmuir-Blodgett(LB) Method (Langmuir-Blodgett(LB)법을 이용한 (N-docosyl pyridinium)-TCNQ(1:2) 착체의 초박막 제작)

  • Kang, Hun;Kim, Yong-Tae;Jeong, Soon-Wook;Sohn, Byoung-Chung;Kang, Dou-Yol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1988.10a
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    • pp.54-57
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    • 1988
  • A film is fabricated by depositing several slices ultra thin films on a slide glass. The UV-absorbance outcomed on a multi-layered bulky ultra thin film with (N-docosyl pyridinium)-TCNQ (1:2) complex results tat the quantity of UV-absorbances becomes more linearly according to the number of layer becomes higher. In addition, it is found that the capacitance of this film gets smaller as the number of layer gets higher. Finally, the conductivity of this film is measured by the direction of the long axis of the TCNQ radical anion, and is resulted in a remarkably low value (about 1.66∼3.78 x 10$\^$-14/S/cm).

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Photosynthetic Response of Korean Ginseng under Saline Condition

  • Cho, Jin-Woong;Kim, Choong-Soo
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.2
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    • pp.100-104
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    • 2004
  • This study was conducted to investigate the effect of the salinity on growth, inorganic ion content, and photosynthetic rate ($\textrm{P}^{N}$) in Korean ginseng (Panax ginseng C.A. Meyer) with complex fertilizer (CF) and NaCl concentrations. The salinity was applied to plant using NaCl and CF, and controlled an EC as 0.0, 1.0, 2.0 and 3.0 dS $\textrm{m}^{-1}$. The salinity treated three times at 35, 42 and 49 d after transplanting. The leaf area in different electrical conductivity (EC) decreased only the higher NaCl 1.0 dS $\textrm{m}^{-1}$. The root growth increased with CF and especially, it was two times higher at 3.0 dS $\textrm{m}^{-1}$ than that of control. But the root growth sharply decreased with NaCl compared to CF. The light saturation point of Korean ginseng was around 100 $\mu\textrm{mol}\;\textrm{m}^{-2}\textrm{s}^{-1}$ photosynthetically active radiation (PAR), and $\textrm{P}^{N}$ increased as CF increased but decreased with NaCl especially at the late growth stage. The $\textrm{Na}^{+}$ content in Korean ginseng increased sharply with NaCl.

Dielectric Properties Depending on Temperature in Organic Light-emitting Diodes(ITO/$AIq_3$/AI) (유기 발광 다이오드(ITO/$AIq_3$/AI)의 온도 변화에 따른 유전 특성)

  • Oh, Y.C.;Lee, D.K.;Cho, C.N.;Ahn, J.H.;Jeong, Dong-Hui;Lee, S.I.;Kim, G.Y.;Kim, T.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.04a
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    • pp.74-75
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    • 2006
  • We have investigated dielectric properties depending on temperature in organic light-emitting diodes using 8-hydroxyquinoline aluminum ($Alq_3$) as an electron transport and emissive material. We analyzed the dielectric properties of organic light-emitting diodes using characteristics of impedance. he Impedance characteristics was measured complex impedance Z and phase $\theta$ in the temperature range of 10 K to 300 K. We obtained complex electrical conductivity, dielectric constant and loss tangent ($tan{\delta}$) of the device at room temperature. From these analyses, we are able to interpret a conduction mechanism and dielectric properties contributed by an interfacial and orientational polarization.

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Temperature Prediction of Underground Working Place Using Artificial Neural Networks (인공신경망을 이용한 심부 갱내온도 예측)

  • Kim, Yun-Kwang;Kim, Jin
    • Tunnel and Underground Space
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    • v.17 no.4
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    • pp.301-310
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    • 2007
  • The prediction of temperature in the workings for the propriety examination for the development of a deep coal bed and the ventilation design is fairly important. It is quite demanding to obtain precise thermal conductivity of rock due to the variety and the complexity of the rock types contiguous to the coal bed. Therefore, to estimate the thermal conductivity corresponding to this geological situation and complex gallery conditions, a computing program which is TemPredict, is developed in this study. It employs Artificial Neural Network and calculates the climatic conditions in galleries. This advanced neural network is based upon the Back-Propagation Algorithm and composed of the input layers that are acceptant of the physical and geological factors of the coal bed and the hidden layers each of which has the 5 and 3 neurons. To verify TemPredict, the calculated result is compared with the measured one at the entrance of -300 ML 9X of Jang-sung production department, Jang-sung Coal Mine. The difference between the results calculated by TemPredict ($25.65^{\circ}C$) and measured ($25.7^{\circ}C$) is only $0.05^{\circ}C$, which is less than the allowable error 5%. The result has more than 95% of very high reliability. The temperature prediction for the main carriage gallery 9X in -425 ML under construction when it is completed is made. Its result is $28.2^{\circ}C$. In the future, it would contribute to the ventilation design for the mine and the underground structures.

Photo-catalytic Activity of CNT-TiO2 Nano Complex Prepared from Titanium Oxysulfate and Carbon Nanotube by Hydrosis (황산티타늄과 탄소나노튜브로부터 가수분해로 제조된 CNT-TiO2 나노복합체의 광촉매활성)

  • Kim, Sang Jin;Jung, Min-Jung;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.58-62
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    • 2010
  • CNT-$TiO_{2}$ nano complexes were prepared from $TiOSO_4$ and multi-walled carbon nanotube (MWCNT) by hydrolysis. The CNTs were dispersed uniformly with anatase $TiO_{2}$ in the prepared $TiO_{2}$-CNT complexes. The increasing MWCNT ratio leads to increased crystalline carbon and O/Ti ratio. The decomposition degree of methylene blue was experienced according to UV radiation time for study adsorption and photocatalytic activity. The samples having high MWCNT ratio show high adsorption and photodegradation. The high specific surface area, functional group having oxygen, low band gap energy, high electric conductivity, high volume to surface ratio, uniform structure and properties of MWCNT assist photocatalytic activity of CNT-$TiO_{2}$ complex.

Syntheses and Characterization of Cr(III)-Hydrogensalicylato and -Hydroxonitrophenolato Tetraaza Macrocyclic Complexes

  • Byun, Jong-Chul;Yoon, Chang-Hoon;Mun, Dae-Hun;Kim, Ki-Ju;Park, Yu-Chul
    • Bulletin of the Korean Chemical Society
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    • v.27 no.5
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    • pp.687-693
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    • 2006
  • Chromium(III) complexes, cis-[Cr([14]-decane)$(HOC _6H _4COO) _2$]$ClO _4$ I and cis-[Cr([14]-decane)(OH) $(OC _6H _4NO _2)$]$ClO _4{\cdot}H _2O$ II ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) are synthesized and structurally characterized by a combination of elemental analysis, conductivity, IR and VIS spectroscopy, and X-ray crystallography. The complexes crystallizes in the monoclinic space groups, $C2 _1$/a in I and $P2 _1$/n in II. Analysis of the crystal structure of complex I reveals that central chromium(III) ion has a distorted octahedral coordination environment and two hydrogensalicylato ligands are unidentate to the chromium(III) ion via the carboxyl groups in the cis-position. For monomeric complex I the hydrogensalicylato coordination geometry is as follows: Cr-O(average) = 1.984(3) $\AA$;Cr-N range = 2.105(3)-2.141(4) $\AA$;C(24)-O(4) = 1.286(5) $\AA$;N(2)-Cr-N(4) (equatorial position) = 96.97(15)${^{\circ}}$; N(1)-Cr-N(3) (axial position) = 168.27(15)${^{\circ}}$; O(1)-Cr-O(4) = 85.70(13)${^{\circ}}$. The crystal structure of II has indicated that chromium(III) ion is six-coordinated by four secondary amines of the macrocycle, hydroxide anion and nitrophenolate anion.

Study on Design and Performance of Microwave Absorbers of Carbon Nanotube Composite Laminates (탄소나노튜브 복합재 적층판을 활용한 전파흡수체의 설계 및 성능에 대한 연구)

  • Kim, Jin-Bong;Kim, Chun-Gon
    • Composites Research
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    • v.24 no.2
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    • pp.38-45
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    • 2011
  • In this paper, we present an optimization method for the single Dallenbach-layer type microwave absorbers composed of E-glass fabric/epoxy composite laminates. The composite prepreg containing carbon nanotubes (CNT) was used to control the electrical property of the composites laminates. The design technology using the genetic algorithm was used to get the optimal thicknesses of the laminates and the filler contents at various center frequencies, for which the numerical model of the complex permittivity of the composite laminate was incorporated. In the optimal design results, the content of CNT increased in proportion to the center frequency, but, on the contrary, the thickness of the microwave absorbers decreased. The permittivity and reflection loss are measured using vector network analyzer and 7 mm coaxial airline. The influence of the mismatches in between measurement and prediction of the thickness and the complex permittivity caused the shift of the center frequency, blunting of the peak at the center frequency and the reduction of the absorbing bandwidth.

Environmental Impact Assessments along with Construction of Residential and Commercial Complex (주거단지 건설이 하천에 미치는 생태영향평가)

  • An, Kwang-Guk;Han, Jeong-Ho;Lee, Jae Hoon
    • Journal of Environmental Impact Assessment
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    • v.21 no.5
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    • pp.631-648
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    • 2012
  • The integrative ecological approaches of chemical assessments, physical habitat modelling, and multi-metric biological health modelling were applied to Gwanpyeong Stream within Gap-Stream watersheds to evaluate environmental impacts on the constructions of residential and commercial complex. For the analysis, the surveys conducted from 45 sites of reference streams within the Gap-Stream watershed and 3 regular sites during 2009 - 2010. Physical habitat health, based on the habitat model of Qualitative Habitat Evaluation Index(QHEI) declined from the headwaters(good - fair condition) to the downstream(poor condition). Chemical water quality, based turbidity and electric conductivity(EC), was degraded toward to the downstream, and especially showed abrupt increases, compared to the values of control streams(CS). Also, concentrations of chlorophyll-a in the downstreams were greater compared to the control stream(CS), indicating an eutrophication. Biological health conditions, based on the Index of Biological Integrity(IBI) using fish assemblages, averaged 19.3 which is judged as a fair condition by the biological criteria of the Ministry of Environment, Korea. The comparisons of model metric values in sensitive species and riffle-benthic species on the Maximum Species Richness Line(MSRL) of 45 reference streams indicated a massive disturbances in all sampling locations. Also, tolerance guild and trophic guild analyses suggest that dominances of tolerant species and omnivores were evident, indicating a biological degradation by habitat disturbances and organic matter pollutions. There was no distinct longitudinal variations of IBI model values from the headwater to the downstream in spite of slight chemical and habitat health gradients among the sampling sites. Overall, integrative ecological health(IEH) scores, based on the chemical, physical, and biological parameters, were low compared to the 45 reference streams due to physical and chemical disturbances of massive constructions of the residential and commercial complex. This stream, thus showed a tendency of typical urban streams which are disturbed in the chemical water quality, habitat structures, and biological integrity. Effective stream management plans and restoration strategies are required in this urban stream for improving integrative stream health.