• Title/Summary/Keyword: Complete Mixture

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Analysis of Organochlorine Pesticide, in the Presence of Polychlorinated Biphenyls(PCBs) I. Florisil Column Separation of the Pesticides-PCBs Mixture (Polychlorinated Biphenyls(PCBs) 존재하에 유기염소계 살충제의 잔류분 분석 1. Florisil Column에 의한 농약과 PCBs의 분리)

  • Park C. K.;Lee C. Y.;Park R. D.
    • Korean journal of applied entomology
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    • v.16 no.4 s.33
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    • pp.221-227
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    • 1977
  • Polychlorinated Biphenyls (PCBs) interfere with gas chromatographic analysis of multiple organochlorine pesticide residues. In the present work, existing Florisil column chromatographic method has been modified as to improve separation of organochlorine pesticides and their metabolites from PCBs. It was amply demonstrated that separation of $\alpha-BHC,\; \gamma-BHC$ Heptachlor epoxide Dieldrin, p.p-DDD, p.p'-DDT from PCBs such as Aroclor 1254 is complete and recovery of the pesticides is found quantitative. Aldrin and Heptachlor in the Aroclor eluant can be separately analyzed by comparison of the chromatographic pattern of standard Aroclor 1254 with that of Aroclor 1254 a dmixed with the two pesticides. The Florsil column technique can be utilized in the routine evaluation of the organochlorine pesticide residues by gas chromatography.

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Study on Backfire for a Two-Stroke Hydrogen Fueled Free-Piston Engine with Loop Scavenging (루프소기방식을 갖는 2행정 프리피스톤 수소기관의 역화에 관한 연구)

  • Cho, Kwan-Yeon;Byun, Chang-Hee;Back, Dae-Ha;Lee, Jong-Tae
    • Journal of Hydrogen and New Energy
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    • v.21 no.6
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    • pp.487-492
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    • 2010
  • For developing a two-stroke free-piston hydrogen engine with high efficiency and low emission, determination of the scavenging type is one of the most important factor. In this research, backfire characteristics for loop scavenging were analyzed with the number of piston crevice volume and piston expansion speed. Rapid Compression Expansion Machine, RCEM was used for combustion research of the free piston $H_2$ engine in the experiment. As the results, it was shown that although backfire occurring in a loop scavenging type can be partially controled by a complete exhaust of burned gas, possibility of backfire basically exist due to the structure which piston crevice volumes contact with fresh mixture in a scavenging port. However, a loop scavenging may be considered as combustion chamber of a free piston $H_2$ engine from the point of view that backfire does not occur nearby lean equivalence ratio obtained high thermal efficiency. It was also analyzed that an advances of backfire occurrence timing with increase of the fuel-air equivalence ratio were due to promotion of flame propagation into piston crevice volumes by decrease of the quenching distance.

Chromatographic Separation of Hydrogen Isotopes by Deactivated Alumina Stationary Phase (비활성 알루미나 고정상을 이용한 수소동위원소의 크로마토그래피 분리)

  • Kim, Kwang Rag;Lee, Sung Ho;Kang, Hee Suk;Chung, Hongsuk;Sung, Ki Woung
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.121-128
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    • 1998
  • In fields of operating or handling a hydrogen isotope facility, and of the technology for nuclear fusion source management, gas chromatography has been used as one of the practical techniques lot separation and enrichment of hydrogen isotopic gases including tritium. Chromatographic separation experiments of the hydrogen isotope mixture (hydrogen, deuterium and tritium) were carried out by use of a commercially available gas chromatograph. An aliquot of gas sample was injected by a specially designed vacuum sampler into the stream of inert carrier gas which went through the separation column under liquid nitrogen temperature. The complete separation of hydrogen isotopic molecules was observed with an alumina adsorbent partially deactivated by coating with 10% manganese chlorine. In addition, fairly good separation conditions were obtained without any appearance of nuclear spin isomers with shorter retention time, which would be available for the practical applications of the hydrogen isotope separation and enrichment.

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A Study on the Development of Analytical Methods and Behaviors of Environmental Pollutants(II) : Optimization for Separation of Alkylphenols by Reversed-Phase Liquid Chromatography (환경 오염물질의 정량법 개발과 거동에 관한 연구(II) : 역상 액체 크로마토그래피에서 알킬페놀류의 분리 최적화)

  • Lee, Dae Woon;Lee, Yong-Ju;Park, Young Hun;Kim, Ho Seob
    • Analytical Science and Technology
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    • v.7 no.1
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    • pp.25-31
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    • 1994
  • As for analytes which did not represent the differences of the selectivity on the stationary and mobile phase, secondary chemical equilibrium theory was applied to study pH effects on the separation of alkylphenols. Mobile phase was consisted of an aqueous sodium carbonate-bicarbonate buffer and acetonitrile. The maximum selectivity for adjacent peak pairs was predicted from those values of $k^{\prime}_{HA}/k^{\prime}_{A-}$ and ${\Delta}pK$. The optimum pH determined by this method was 11.18 pH and solvent selectivity were considered at the same time to invoke the full range of selectivity effects possible for separations. Quaternary mixture composed of methanol, acetonitrile, tetrahydrofuran and water was adjusted to optimum pH 11.18. As the statistical simplex technique of an overlapping resolution map (ORM) was used to predict the optimized solvent system. The optimum solvent, which gives complete separation of alkylphenols, was determined as follws MeOH : ACN : THF = 14.4 : 81.8 : 2.8.

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The development and the characteristics of environmentfriendly sinker for octopus drift-line (문어흘림낚시용 친환경 봇돌의 개발과 그 특성)

  • An, Young-Il;Yoon, Sang-Ok
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.44 no.3
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    • pp.184-193
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    • 2008
  • For environment-friendly fishery, the lead sinkers of octopus drift line were developed with the environmentfriendly sinker, and their characteristics and performance were investigated. To make the environmentfriendly sinker, the hydrate ceramic material was developed, and to increase the weight and strength, the iron power was added to it. The fishing hook was machine-made, and standardized, by using 60cm iron wire. For the manufacture of the sinker, the first, the mold was made, and then, hydrate ceramic material and water were quantitatively mixed. The mixture was poured into the mold prepared with a fishing hook already inserted, and had hardened for several hour, before it was taken out of the mold as a complete sinker. The sinkers were made in the 8 types ranging in weight from 150 to 500g, and their specific gravities were diverse from 2.871 to 6.637, which was 0.19 to 0.44 times lower than that of lead. The movement of the environment-friendly sinker by flume tank was possible in the weaker current speed than the similar lead sinker. In the coastal fishing grounds of Gangwon province, the comparison of catching efficiency was made between the improved fishing gears composed of the environment-friendly sinkers and artificial baits, and the current used fishing gears of lead sinkers and pig-fat baits. The result showed the tendency in which the improved fishing gears caught the bigger octopuses than the current used fishing gears. In the quantity and number of the fish catch per unit fishing gear, the improved fishing gear showed a little more catch than the current used fishing gear, regardless of the fishing area. However, the number of the improved fishing gears lost during fishing operation was similar to that of the current used fishing gears.

A Study on the Fabrication of Reinforced Reaction Bonded Alumina Ceramics (반응결합 강화 알루미나세라믹스의 제조에 관한 연구)

  • 김일수;강민수;박정현
    • Journal of the Korean Ceramic Society
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    • v.35 no.4
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    • pp.311-318
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    • 1998
  • The reaction bonded alumina ceramics with reinforced particles which have low shrinkage were pro-duced by blending of SiC or TiC or ZrO2 powders to the mixture of Al metal and Al2O3 powder. The powd-ers were attrition milled isostantically pressed and preheated tio 110$0^{\circ}C$ with a heating rate of $1.5^{\circ}C$/min The specimens were then sintered at the temperature range 1500 to 1$600^{\circ}C$ for 5 hours with a heating rate of 5$^{\circ}C$/min. The specimens showed 5-9% weight gain and 2-9% dimensional expansion through the complete oxidation of Al after preheating up to 11--$^{\circ}C$ the overall dimensional change of the specimens after the reaction sintering at 1500-1$600^{\circ}C$ was 6-12% The maximum densities were 92% theoretical. The fine grain-ed(average grain size :0.4 ${\mu}{\textrm}{m}$) microstructure were observed in the specimen with ZrO2 and SiC. But the microstructure of specimen with TiC was relatively coarse.(average grain size : 2.1 ${\mu}{\textrm}{m}$) The mullite phase was formed by the reaction of Al2O3 and SiO2 in a specimen with SiC. In the TiC contained specimen TiC was oxidized into TiO2 and finally reacted with Al2O3 to form Al2TiO5 during sintering.

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A Study on the RDF fuel mixing with household and organic wastes (생활(生活)쓰레기 및 유기성폐기물(有機性廢棄物) 혼합(混合)에 따른 RDF 연료화(燃料化)에 관한 연구(硏究))

  • Ha, Sang-An;You, Mi-Young;Kim, Dong-Kyun;Wang, Jei-Pil
    • Resources Recycling
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    • v.20 no.5
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    • pp.52-57
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    • 2011
  • This study was conducted to examine the possibilities to utilize the mixture of domestic and organic wastes from B-city as a fuel. All types of mixing ratio for uncarried waste, sludge cake, and food waste were found 10 generate heating value with 6,000 kcal/kg, and in case of sludge cake the concentration of toxic substance produced was found to be decreased as air-fuel ratio and temperature were increased. It was noted that toxic gases such as CO, NOx, and SOx were observed below concentration of emission standard, and temperature inside the incinerator was stabilized at 2 of air-fuel ratio and 800$^{\circ}C$. It was observed that a heating value of 6000 kcal/kg generated using RDF(Refuse Derived Fuel) was appropriate to utilize a fuel if a complete combustion was attained.

Characterization of a Toxin isolated from Bacillus thuringiensis var. alesti and Its Toxicity to the Silkworm, Bombyx mori (Bacillus thuringiensis var. alesti로부터 분리된 독소의 성상과 누에에 대한 독성)

  • 이영근;조용섭;임종성
    • Journal of Sericultural and Entomological Science
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    • v.17 no.1
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    • pp.55-62
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    • 1975
  • In the studies of characterization of crystal prototoxin isolated from Bacillus thuringinensis var. alesti and its bioassay to the silkworm larvae, Bombyx mori L., the following results were obtained. 1. The complete lysis of bacteria grown on the nutrient agar at 30$^{\circ}C$ in an incubator took 30 days, but the period could be reduced by a half in a devised broth media in a fermentation jar. 2. The protein toxin extracted directly from a mixture of crystals and spores without separation of crystals and spores was pure as same as the protein toxin extracted from only crysals separated. 3. By SLS polyacrylamide gel electrophoresis of prototoxin released from crystals in alkali (pH 9.5) three different proteins in molecular weights of 120,000, 87,000, 74,000 were separated. 4. In the bioassay of the toxin to the silkworm larvae, LD$\sub$50/ per gram of the larvae in the 4th instar was 0.080 $\mu\textrm{g}$.

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Influence of Sunflower Whole Seeds or Oil on Ruminal Fermentation, Milk Production, Composition, and Fatty Acid Profile in Lactating Goats

  • Morsy, T.A.;Kholif, S.M.;Kholif, A.E.;Matloup, O.H.;Salem, A.Z.M.;Elella, A. Abu
    • Asian-Australasian Journal of Animal Sciences
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    • v.28 no.8
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    • pp.1116-1122
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    • 2015
  • This study aimed to investigate the effect of sunflower seeds, either as whole or as oil, on rumen fermentation, milk production, milk composition and fatty acids profile in dairy goats. Fifteen lactating Damascus goats were divided randomly into three groups (n = 5) fed a basal diet of concentrate feed mixture and fresh Trifolium alexandrinum at 50:50 on dry matter basis (Control) in addition to 50 g/head/d sunflower seeds whole (SS) or 20 mL/head/d sunflower seeds oil (SO) in a complete randomized design. Milk was sampled every two weeks during 90 days of experimental period for chemical analysis and rumen was sampled at 30, 60, and 90 days of the experiment for ruminal pH, volatile fatty acids (tVFA), and ammonia-N determination. Addition of SO decreased (p = 0.017) ruminal pH, whereas SO and SS increased tVFA (p<0.001) and acetate (p = 0.034) concentrations. Serum glucose increased (p = 0.013) in SO and SS goats vs Control. The SO and SS treated goats had improved milk yield (p = 0.007) and milk fat content (p = 0.002). Moreover, SO increased milk lactose content (p = 0.048) and feed efficiency (p = 0.046) compared to Control. Both of SS and SO increased (p<0.05) milk unsaturated fatty acids content specially conjugated linolenic acid (CLA) vs Control. Addition of SS and SO increased (p = 0. 021) C18:3N3 fatty acid compared to Control diet. Data suggested that addition of either SS or SO to lactating goats ration had beneficial effects on milk yield and milk composition with enhancing milk content of healthy fatty acids (CLA and omega 3), without detrimental effects on animal performance.

Outcome of Regenerative Endodontic Treatment for an Avulsed Immature Permanent Tooth: A Case Report (완전 탈구된 미성숙 영구치의 치수재생치료 증례 보고)

  • Park, Nakyoung;Song, Jihyun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.45 no.2
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    • pp.250-256
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    • 2018
  • Dental avulsion, defined as the complete displacement of a tooth from the alveolar bone with consequent loss of the blood and nerve supply, was reported as one of the most severe dental injuries. Avulsion can cause tissue ischemia, which leads to pulp necrosis. Apexification is a conventional treatment method that induces an apical calcified barrier in immature roots with pulp necrosis. However, root development characterized by an increase in the root thickness and length cannot be achieved by apexification. The purpose of this case report was to describe the radiographic and clinical outcomes of regenerative endodontic treatment for the avulsed and necrosed permanent tooth with an immature root after replantation in a 5-year-old girl; the treatment was performed using a mixture of ciprofloxacin, metronidazole and cefaclor, CollaTape and Biodentine.