• Journal of the Korean Ceramic Society
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• v.21 no.3
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• pp.231-238
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• 1984

Heavy metal fluoride glasses exhibit considerable promise as high transparency materials from the UV to the IR. These glasses are prepared by fusion of the mixture of metal fulorides($ZrF_4$, $BaF_2$, $LaF_3$ etc) at 800-1, 00$0^{\circ}C$ under the inert$(N_2)$ or reactive ($CCl_4$, $Cl_2$) atmosphere following the casting into glass on cooling. Infrared absorption at the 3, 400 cm-1 -OH peak has been measured as a function of thickness for several ZrF-$BaF_2$-LaF and $HfF_4$-$BaF_2$-$LaF_3$ glasses to separate contributions from bulk and surface -OH. For glasses melted under $CCl_4$ reactive atmosphere the peak is due almost entirely to surface-OH. and melting in a closed reactor was best for removing -OH. In ambient atmosphere the -OH peak exhibited no time dependence over a 30 d period indicating a very small rate of surface attack by atmospheric H2O. Removal of -OH absorption processing was generally easier and more complete for the $BaF_2$/ThF4-glasses than for the $ZrF_4$-or $HfF_4$-based glasses.

• Journal of the Korean Wood Science and Technology
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• v.14 no.3
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• pp.43-46
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• 1986

A stainless steel autoclave reactor, which is the property of Pacific Northwest Laboratories(PNL) and located in PNL, was acted for pyrolysis and gasification of sawdust, ricestraw, and ricehusk. The initial reaction temperature of this reactor was 300$^{\circ}C$, and up to 500$^{\circ}C$ to complete pyrolysis and gasification reaction. The maximum exerted pressure on this reactor was 800 psig. In order to examine the effect of catalyst on reaction temperature, $K_2CO_3$, and nickel/alkali carbonate catalyst mixture were also used. The experimental results obtained with this reactor indicated that good yields of methane-rich gas(exceeding 40% methane) can be produced. The product gas mixtures were also identified to be CO. $CO_2$, $C_2H_4$, and $CH_3CHO$ etc. by Gas Chromatography and Mass Spectrometer.

• International Journal of Automotive Technology
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• v.2 no.2
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• pp.39-45
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• 2001

Hydrogen is seen as one of the important energy vectors of the next century. Hydrogen as a renewable energy source, provides the potential for a sustainable development particularly in the transportation sector. Hydrogen driven vehicles reduce both local as well as global emissions. The laboratory of transporttechnology (University of Gent) converted a GM/Crusader V-8 engine for hydrogen use. Once the engine is optimised, it will be built in a low-floor midsize hydrogen city bus for public demonstration. For a complete control of the combustion process and to increase the resistance to backfire (explosion of the air-fuel mixture in the inlet manifold), a sequential timed multipoint injection of hydrogen and an electronic management system is chosen. The results as a function of the engine parameters (ignition timing. injection timing and duration, injection pressure) we given. Special focus is given to topics related to the use of hydrogen as a fuel: ignition characteristics (importance of electrode distance), quality of the lubricating oil (crankcase gases with high contents of hydrogen), oxygen sensors (very lean operating conditions), noise reduction (configuration and length of inlet pipes). The advantages and disadvantages of a power regulation only by the air to fuel ratio (as for diesel engines) against a throttle regulation (normal gasoline or gas regulation) are examined. Finally the goals of the development of the engine are reached: power output of 90 kW, torque of 300 Nm, extremely low emission levels and backfire-safe operation.

• Journal of Animal Environmental Science
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• v.5 no.1
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• pp.29-36
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• 1999

This study was conducted to determine the effects of dietary swine manure and food waste on feeding and drinking behaviours in broiler chicks. A total of 240 birds with 40g of initial weight were randomly assigned in the 8$\times$3 randomized complete block design and 10 birds per replicate. Extrusion recycled feeds(ERF) were prepared by extruding a mixture of 40% swine manure+40% food waste(FW)+20% corn. The birds assigned to one of the 8 dietary regimens; 0, 10, 30, 40% ERF of 20, 40, 60% FW in the place of a commercial boiler starter diet. Video recording were made after one week of adaptation period to the regimen. The tapes were played in a slow motion to examine feeding and drinking behaviour. Feeding and drinking times were greater in the day time at the night. Feeding times peaked at 4 hour intervals. Drinking time increased about 2 times on FW feeding compared to the other treatment groups. The results indicated that feeding and drinking behaviour could be influenced by the dietary regimens and that FW feeding increased drinking. The data also suggested that the FW could replace within 40% of broiler starter diet.

• Bulletin of the Korean Chemical Society
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• v.28 no.9
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• pp.1467-1471
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• 2007

The green-emitting CeMgAl11O19:Tb (CMAT) phosphor has been prepared at 1200 °C by the simple solid-state reaction using AlF3 as a self-flux. This preparation temperature is much lower than those (1500-1700 °C) for conventional solid-state reaction and spray pyrolysis method. In particular, the complete process to produce high-quality phosphor particles was carried out through the single-step heat treatment of the mixture of corresponding oxide-type metal sources. An addition of AlF3 as a self-flux significantly decreased the crystallization temperature of CMAT with plate-like shape. The particle morphology could be controlled from plate-like to spherical by using H3BO3 as an additional flux. Thus, an optimal morphology and luminescence characteristics of CMAT were achieved when both AlF3 and H3BO3 fluxes were simultaneously used. Compared with conventional solid-state process, which is accompanied by the calcination step(s), and other alternative liquid solution techniques such as sol-gel method and spray pyrolysis, no use of active precursors and liquid media that are harmful to the environment is a distinctive advantage for the industrial purpose.

• International Journal of Concrete Structures and Materials
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• v.3 no.1
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• pp.71-77
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• 2009

A theoretical model of multiple cracking failure mechanism is proposed herein for fiber reinforced high performance Cementitious composites. By introducing partial debonding energy dissipation on non-first cracking plane and fiber reinforcing parameter, the failure mechanism model of multiple cracking is established based on the equilibrium assumption of total energy dissipation on the first crack plane and non-first cracking plane. Based on the assumption of the first crack to be the final failure crack, energy dissipation terms including complete debonding energy, partial debonding energy, strain energy of steel fiber, frictional energy, and matrix fracture energy have been modified and simplified. By comparing multiple cracking number and energy dissipations with experiment results of the reference's data, it indicates that this model can describe the multiple cracking behavior of fiber reinforced high performance cementitious composites and the influence of the partial debonding term on energy dissipation is significant. The model proposed may lay a foundation for the predictions of the first cracking capacity and post cracking capacity of fiber reinforced high performance cementitious composites and also can be a reference for optimal mixture for construction cost.

• Advances in environmental research
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• v.2 no.4
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• pp.261-277
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• 2013

The degradation of alachlor has been investigated using sonolysis (US), photocatalysis (UV) and sonophotocatalysis (US/UV) using three photocatalyst viz. $TiO_2$ (mixture of anatase and rutile), $TiO_2$ (anatase) and ZnO. The effect of photocatalyst loading on the extent of degradation of alachlor has been investigated by varying $TiO_2$ (both types) loading over the range of 0.01 g/L to 0.1 g/L and ZnO loading over the range of 0.05 g/L to 0.3 g/L. The optimum loading of the catalyst was found to be dependent on the type of operation i.e., photocatalysis alone or the combined operation of sonolysis and photocatalysis. All the combined processes gave complete degradation of alachlor with maximum rate of degradation being obtained in the case of sonophotocatalytic process also showing synergistic effect at optimized loading of photocatalyst. About 50% to 60% reduction in TOC has been obtained using the combined process of sonophotocatalysis depending on the operating conditions. The alachlor degradation fitted first order kinetics for all the processes under investigation. It has been observed that the $TiO_2$ (mixtrure of anatase and rutile) is the most active photocatalyst among the three photocatalysts studied in the current work. The effect of addition of radical enhancers and scavengers on sonophotocatalytic degradation of alachlor has been investigated in order to decipher the controlling mechanism. The alachlor degradation products have been identified using LC-MS method.

• Journal of ILASS-Korea
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• v.13 no.1
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• pp.1-8
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• 2008

It was investigated how fuel injection timing - early injection and later injection - in conjunction with throttle open rate effect the fuel-air mixing characteristics, Engine power, combustion stability and emission characteristics on a DI CNG spark Engine and control system that had been modified and designed according to the author's original idea. It was verified that the combustion characteristics were changed according to fuel injection timings and Engine conditions determined by different throttle open rates and rpm. It was found that the combustion characteristics greatly improved at the complete open throttle rate with an early injection timing and at the part throttle rate with a late injection timing. Combustion duration was governed by flame propagation duration in a late injection timing and by an early flame development duration in an early injection timing. As the result, we discovered that combustion duration is shortened, lean limit is improved, air-fuel mixing conditions controlled, and emissions reduced through control of fuel injection timing according to change of the throttle open rate.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.466-471
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• 2004

In gas turbines, excess air for combustion is available and therefore lean premixed combustion is the most promising approach to the significant reduction of thermal NOx emissions. At lean conditions, however, flame stability is inherently worse and hence combustion tends to be incomplete. Efforts have been devoted toward extending the operating range of complete combustion at leaner conditions. One of them is the lean-lean two-stage combustion where lean to ultra-lean secondary mixtures are mixed with the hot burned gas from the primary stage. Conventional flame combustion or flameless reaction are initiated depending on the conditions of the secondary zone. In the first part of the present study, the effects of fuel injection on the emissions and flame stability were investigated for a single tubular flame, In the second part, the emissions and flame stability were studied for a two-stage combustor with secondary mixture injected through the tangential slots on a cylindrical combustor wall. The effects of the ratio of air flow rates to the primary and secondary zones on the emissions and combustion characteristics were investigate.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.62-68
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• 2004

A comprehensive numerical analysis has been carried out for both non-reacting and reacting flows in a scramjet engine combustor with and without a cavity. The theoretical formulation treats the complete conservation equations of chemically reacting flows with finite-rate chemistry of hydrogen-air. Turbulence closure is achieved by means of a k-$\omega$ two-equation model. The governing equations are discretized using a MUSCL-type TVD scheme, and temporally integrated by a second-order accurate implicit scheme. Transverse injection of hydrogen is considered over a broad range of injection pressure. The corresponding equivalence ratio of the overall fuel/air mixture ranges from 0.167 to 0.50. The work features detailed resolution of the flow and flame dynamics in the combustor, which was not typically available in most of the previous studies. In particular, the oscillatory flow characteristics are captured at a scale sufficient to identify the .underlying physical mechanisms. Much of the flow unsteadiness is related not only to the cavity, but also to the intrinsic unsteadiness in the flow-field. The interactions between the unsteady flow and flame evolution may cause a large excursion of flow oscillation. The roles of the cavity, injection pressure, and heat release in determining the flow dynamics are examined systematically.