• Title/Summary/Keyword: Comparison of reducing characteristics

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Reaction of Lithium Cyanoaluminum Hydride with Selected Organic Compounds Containing Representative Functional Groups. Comparison of Reducing Characteristics between Lithium and Sodium Cyanoaluminum Hydrides

  • Cha, Jin-Soon;Yu, Se-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1588-1592
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    • 2009
  • Lithium cyanoaluminum hydride (LCAH) was prepared by the metal cation exchange reaction of sodium cyanoaluminum hydride with lithium chloride in tetrahydrofuran. The reducing characteristics of LCAH were explored systematically by the reaction with selected organic compounds containing representative functional groups under the standardized conditions (tetrahydrofuran, 0 ${^{\circ}C}$). The reducing ability of LCAH was also compared with of the sodium derivative, sodium cyanoaluminum hydride (SCAH). Generally, the reducing behavior of LCAH resembles that of SCAH closely, but the reactivity of LCAH toward representative organic functional groups appeared to be stronger than that of SCAH. Thus, the regent reduces carbonyl compounds, epoxides, amides, nitriles, disulfides, carboxylic acids and their acyl derivatives to the corresponding alcohols or amines, at a relatively faster rate than that of SCAH. The cyano substitution, a strong election-withdrawing group, diminishes the reducing power of the parent metal aluminum hydrides and hence effects the alteration of their reducing characteristics.

Characteristics Analysis of Short Flux Path Switched Reluctance Motor

  • Ahn, Jin-Woo
    • Journal of international Conference on Electrical Machines and Systems
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    • v.1 no.2
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    • pp.38-45
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    • 2012
  • A novel kind of switched reluctance motor (SRM) with short flux path is proposed in this paper. Phase excitation in the SRM gives short flux paths, hence reducing the magnetomotive force required to drive the machine, resulting in significant reduction of copper wire and core losses compared to the typical SRM with diametric circulation of magnetic flux. To verify the performance, the characteristics analysis of a double-stator SRM, a 6/5 SRM with C-core structure, and a 4/5 two-phase SRM, which all have short flux paths, and a comparison with conventional SR motors are executed. The comparison demonstrates that the proposed motor offers some advantages in terms of torque and efficiency.

Selective Reduction of Carbonyl and Epoxy Compounds Using Aluminum, Boron and Other Metal Reagents. Comparison of Reducing Characteristics between the Meerwein-Ponndorf-Verley Type Reduction and Metal Complex Hydrides Reduction: A Review

  • Cha, Jin-Soon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2162-2190
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    • 2007
  • The newly-developed Meerwein-Ponndorf-Verley (MVP) type reagents using aluminum, boron and other metals for reduction of organic functional groups such as carbonyl and epoxy compounds have been surveyed. highlighted and reviewed in this account are the appearance of new MPV type reagents and their application to the selective reduction of organic functions. Finally, this account emphasizes the distinct contrast in the reducing characteristics existed between metal hydride reagents and MPV reagents, and compares their usefulness in organic synthesis.

Reaction of Thexylalkoxyboranes with Selected Orgnic Compounds Containing Representative Functional Groups Comparison of Reducing Characteristics of the Alkoxy Derivatives

  • 차진순;장석원;권오운;전중현
    • Bulletin of the Korean Chemical Society
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    • v.19 no.2
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    • pp.243-249
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    • 1998
  • The reaction of alcohol with a solution of thexylborane (ThxBH2) in tetrahydrofuran (THF) provides a new class of mild and selective reducing agents, thexylalkoxyboranes (ThxBHOR: R=Et, i-Pr, i-Bu, s-Bu, t-Bu, Ph). In order to elucidate the effect of the alkoxy group in reduction reactions, the reducing power of ThxBHOR toward selected organic compounds containing representative functional groups under practical conditions (THF, 25°, the quantitative amount of reagent to compound) has been investigated. Generally, the reactivity of ThxBHOR is largely dependent upon the alkoxy substituent. ThxBHOR can be synthesized from a variety of alcohols, thus allowing control of the steric and electronic environment of these reagents.

Comparison of iron loss characteristics between thin-gauged grain-oriented 3% Si-Fe sheets and commercial 0.3 mm-thick grain-oriented electrical sheets (극박 방향성 규소강판과 상용 방향성 규소강판의 철손특성 비교)

  • Cho, Seong-Soo;Kim, Sang-Beom;Soh, Joon-Young;Chae, U-Gyu;Han, Sang-Ok
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.2009_2010
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    • 2009
  • Thin-gauged 3% Si-Fe sheets having a high magnetic induction of over 1.9 T have been developed for the purpose of applications where operation frequency is higher than power frequency. In order to clarify requirements of iron loss characteristics for the applications, iron loss characteristics of the newly developed strip were investigated by iron loss separation method and were compared with those of commercially produced 0.3 mm-thick electrical sheets. In case of relatively high excitation induction(1.7 T) and low frequency(60 Hz), reducing hysteresis loss is effective to decrease total iron loss. In case of relatively low excitation induction(1.0 T) and high frequency(1 kHz), reducing eddy-current loss is effective by decreasing thickness and grain size to improve total iron loss.

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Refinement of Low-grade Clay using Iron-reducing Bacteria [I] : Comparison of Traditional Ripening and Biotechnological Ripening (철환원세균을 이용한 저품위 점토의 개량[I] : 전통적 수비법과 생물공학적 숙성법의 비교)

  • 류희욱;조경숙;김민주;강석영;최희락
    • KSBB Journal
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    • v.15 no.2
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    • pp.201-207
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    • 2000
  • The traditional ripening method of clay was analyzed. An advanced refining method of clay using enrichment cultures of iron r reducing bacteria was developed. After the traditional ripening, the whiteness of the clay was increased due to removal of | iron impurities by inhabitant dissilmaltien with iron reducing bacteria. Other characteristics of the refined clay such as v viscosity, plasticity, and strength were also improved by iron reducing bacteria. An advanced method of clay refinement with a anaerobic enrichment cultivation of iron reducing bacteria supplemented with an extra carbon source such as glucose was s suggested. When the clay was treated by the advanced method. the refinement time could be reduced to 1/6 of that r required by the traditional method. The physical properties of the refined clay by the advanced method were better than t those of the traditionally refined clay.

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Modified Direct Torque Control System of Five Phase Induction Motor

  • Kim, Nam-Hun;Kim, Min-Huei
    • Journal of Electrical Engineering and Technology
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    • v.4 no.2
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    • pp.266-271
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    • 2009
  • In this paper, improved direct torque control(DTC) of five-phase induction motor(IM) is proposed. Due to the additional degrees of freedom, five-phase IM drives present unique characteristics. One of them is the ability of enhancing the torque producing capability of the motor. Also five-phase motor drives possess many others advantage compared with the traditional three-phase motor drives. Such as, reducing the amplitude and increasing of frequency of torque pulsation, reducing amplitude of current per phase without increasing the voltage per phase and increasing the reliability. The direct torque control method is advantageous when it is applied to the five-phase IM. Because the five-phase inverter provides 32 space vectors in comparison to 8 space voltage vectors by the three-phase inverter. The 32 space voltage vectors are divided into three groups according to their magnitudes. The characteristics and dynamic performance of traditional five-phase DTC are analyzed and new DTC for five-phase IM is proposed. Therefore, a more precise flux and torque control algorithm for the five-phase IM drives can be suggested and explained. For presenting the superior performance of the pro-posed direct torque control, experimental results is presented using a 32 bit fixed point TMS320F2812 digital signal processor

Comparative Study of Architectural Conceptions Between the East and the West

  • Lee, Jaehoon
    • Architectural research
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    • v.23 no.3
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    • pp.49-54
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    • 2021
  • In contemporary modern architecture, it can be said that Western modern architecture, which has advanced in technology and ideology, is leading the world architecture today. However, because it is pointed out that modern architecture, mainly represented by Western architecture nowadays, is based on the crystal of Western civilization's consumption and capitalist culture, and because it seems not absolute for the eternal sustainable development of the Earth and happiness of Humankind, it is assumed that the new conceptions of Architecture should include the cultural, ecological and environmental characteristics of the region. So because it is thought that the latent characteristics of East Asian architecture including China, Japan and Korea has the advantage of reducing the deficiency of Western modern architecture and contributing to human civilization, this study was written to find a new direction of architecture by finding the differences of architectural characteristics(intrinsic and extrinsic) in the interior of the architectural result through comparison between the Eastern and Western architecture.

Comparison of Some Characteristics Relevent to Yukwa (Fried Rice Cookie) made from Different Waxy Rice Cultivars (찰벼품종을 달리하여 제조한 유과의 품질 특성 비교)

  • 최영희;강미영
    • Journal of the East Asian Society of Dietary Life
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    • v.10 no.1
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    • pp.71-76
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    • 2000
  • This study was carried out in order to investigated the degree of expansion, textural and sensory characteristics of Yukwa made from various cultivars of waxy rice, With 5 varieties of waxy rice and a nonwaxy rice, Yukwa were prepared by the standardized method that had been established optimum preparation conditions. Yukwa made from Shinsunchalbyeo and Whasunchal showed lower degree of expansion than Hangangchalbyeo and IR 29, but showed higher crispness and softer texture among tested waxy rice cultivars. Sensory characteristics of these cultivars showed high score in flavor, crispness and preference. Whasunchalbyeo and Shinsunchalbyeo were appropriate varieties for Yukwa preparation and they were both short grain in length/width. Whasunchalbyeo has the highest score of water uptake and reducing sugar content in Key word.

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