• 제목/요약/키워드: Combustion product

검색결과 235건 처리시간 0.031초

Covalently-Bonded Solid Solution Formed by Combustion Synthesis

  • Ohyanagi, Manshi;Munir, Zuhair A.
    • The Korean Journal of Ceramics
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    • 제6권3호
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    • pp.250-257
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    • 2000
  • The feasibility of synthesizing SiC-AlN solid solution by field-activated combustion synthesis was demonstrated. At lower fields of 8-16.5V/cm, composites of AlN-rich and SiC-rich phases were synthesized, but at fields of 25-30 V/cm, the product was a 2H structure solid solution. Combustion synthesis of the solid solution by nitridation of aluminum with silicon carbide under a nitrogen gas pressure of 4-8 MPa was also investigated. The maximum combustion temperature and wave propagation velocity were found to be influenced by the electric field in the field-activated combustion synthesis, and by the green density and nitrogen pressure in the combustion nitridation. In both cases the formation of solid solutions is complete within seconds, considerably faster than in conventional methods which require hours.

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목재 가연물의 두께에 따른 화염연소와 훈소상태에서의 화재특성 (Fire Characteristics of Flaming and Smoldering Combustion of Wood Combustibles Considering Thickness)

  • 김성찬;남동군
    • 한국화재소방학회논문지
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    • 제29권4호
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    • pp.67-72
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    • 2015
  • 본 연구는 콘칼로리미터 실험을 통해 건축물 마감재와 가구소재로 널리 적용되는 목재 가공품의 화염연소와 훈소시 화재특성을 파악하고자 한다. 시험대상 목재 가연물은 MDF, 합판, 칩보드이며 $50kW/m^2$의 복사열유속을 시편에 가하여 점화를 유도하였다. 실험과정에서 화재특성을 나타내는 발열량, 연소가스 생성율, 유효연소율 등의 주요 인자를 가연물의 두께에 따라 정량화하였다. 실험결과 초기 평면방향의 화염전파와 후기 시편의 관통에 의한 화재확대로 인해 단위면적당 발열량에 대한 두 개의 피크점이 관측되었다. 화염연소시의 질량감소율이 훈소시에 비해 5배 이상 높게 나타난 반면에 훈소과정에서 CO 생성율은 화염연소에 비해 10배 이상 높게 측정되어 훈소시 높은 독성가스 생성율을 보였다. 본 연구는 목재 가연물의 화재성상을 이해하고 화재해석을 위한 물성자료로 활용될 수 있다.

산화제 과잉 예연소기 설계점 운영 특성 (Design Point Operating Characteristics of an Oxidizer Rich Preburner)

  • 문일윤;문인상;강상훈;하성업;이수용
    • 한국추진공학회지
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    • 제17권4호
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    • pp.81-88
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    • 2013
  • 케로신과 액체산소를 추진제로 하는 다단연소방식 액체엔진용 산화제 과잉 예연소기를 설계하여 설계점에서 연소시험을 수행하였다. 설계된 산화제 과잉 예연소기는 산화제 일부와 연료를 혼합헤드를 통해 연소실에 공급하여 연소시키고 나머지 산화제를 연소실 재생냉각채널을 거쳐 연소실 중앙의 분사공을 통해 연소실로 주입하여 기화시키는 형태로 최종적으로 연소압 20 MPa, 혼합비 60에서 작동한다. 혼합헤드에는 단일 와류형 분사기를 벌집형태로 배열하였으며 가스 온도 균일성 향상과 연소 안정성 향상을 위한 혼합링과 터빈까지의 배관을 고려한 노즐을 장착하였다. 설계점 연소시험에서 산화제 과잉 예연소기는 높은 연소 안정성과 생성가스의 균일한 온도분포를 보였다.

축열버너의 연소특성에 대한 실험적 연구 (An Experimental Study on Combustion Characteristics of Regenerative Gas Burner)

  • 양제복;김원배;노동순
    • 한국연소학회지
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    • 제5권1호
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    • pp.99-108
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    • 2000
  • Regenerative burner is a product of new combustion technology for realizing higher thermal efficiency and lower emissions, moreover utilizing very high preheated air temperature up to $1,000^{\circ}C$. In this study the experimental study was carried out to find out a combustion characteristics breaking the old combustion concept. From the variation of configuration of gas nozzle and hot test on the temperature distribution and NOx, CO, it was found out that the performance of regenerative burner was better than that of existing burner, mainly due to the effect of internal gas recirculation.

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첨가제가 담배 연기성분에 미치는 영향 (The Effect of Some Additives on the Components of Cigarette Smoke)

  • 나도영;제병권;이창국;조시형;이동욱
    • 한국연초학회지
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    • 제27권1호
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    • pp.40-50
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    • 2005
  • The influence of tobacco additives on the composition of the combustion products in mainstream smoke is discussed. The effect of additives on the chemical composition of smoke have been further evaluated in order to discover additives that would alter the chemical composition of smoke. Tobacco was uniformly treated at a 1-5$\%$ level with 8 classes of additives. Group M treated with alkali metal salt and group S, F, O give lower tar, nicotine and CO values than the control. Group AN treated with natural antioxidant gives higher tar and CO values than the control. The increases are most probably due to the high transfer rate of the ingredients to smoke. M3 and P1 reduced above the $50\%$ of TSNA from the smoke. M4 and P1 reduced above the $50\%$ of HCN from the smoke. These results suggest that tobacco additives alter pyrolysis or combustion product distribution and provide fundamental data to lead the development of a RRP(reduced risk product).

연소합성법에 의한 Plasma-arc Deposit 용 $Cr_3C_2$ 합성 및 특성에 관한 연구 (Synthesis and Characterization of $Cr_3C_2$ for Plasma-arc Deposit by Combustion Synthesis Process)

  • 장윤식;윤정아;이윤복;박성수;김인술;박흥채;오기동
    • 한국세라믹학회지
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    • 제33권11호
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    • pp.1285-1291
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    • 1996
  • Using Cr2O3 Al and graphite powders as starting materials Cr3C2 was synthesized by combustion synthesis process according to the following reaction : 3Cr3C2 +4C+6Allongrightarrow2Cr3C2 +3Al2O3. The synthesis was conducted at 2 atm in an argon atmosphere. in this study main-product was monolithic phase of Cr3C2 /Cr7C3 mixture and sub-product was slag state of $\alpha$-Al2O3. Single phase of Cr3C2 was obtained when crushed main-product was heat-treated at 120$0^{\circ}C$ for 3h in vacuum state with addition of 2.5wt% C. The obtained Cr3C2 powder can be used as plasma-arc deposit material because the flowability index of powder with the size of 9-50${\mu}{\textrm}{m}$ was 66.

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용액연소법으로 제조한 LaFeO3의 XPS 특성 (X-ray Photoelectron Spectroscopy Study of LaFeO3 Powders Synthesized by Solution Combustion)

  • 황연;강대식;박미혜;조성백
    • 한국재료학회지
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    • 제18권6호
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    • pp.313-317
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    • 2008
  • [ $LaFeO_3$ ] powders were synthesized using a method involving solution combustion, and the surface properties of these powders were examined by x-ray photoelectron spectroscopy. As the amount of fuel increased during the synthesis, the $LaFeO_3$ powders became amorphous with a large plate-like shape. It was found that the O 1s spectra were composed of two types of photoelectrons by deconvolutioning the spectra. Photoelectrons with higher binding energy come from adsorbed oxygen ($O^-$) whereas those with lower energy come from lattice oxygen ($O^{2-}$). The ratio of adsorbed and lattice oxygen increased as the ratio of the fuel and nitrate (${\Phi}$) increased. The binding energy of both types of oxygen increased as ${\Phi}$ increased due to the formation of carbonates.

Ti-Al-C 합금의 고온 자전 합성 반응시 생성상에 관한 연구 (A Study on the Formation Phase of Self-propagating High-temperature Synthesis of Ti-Al-C alloys)

  • 문종태
    • 한국분말재료학회지
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    • 제2권2호
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    • pp.149-157
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    • 1995
  • In this study, an attempt was made to fabricate TiAl as well as its in situ composite via combustion synthesis. The processing variable of the combustion synthesis which include aluminum content and the heating rate were found to affect the combustion temperature. The combustion temperature measured, however, was lower than the melting temperature of TiAl and the reaction product were found to include incomplet reaction products. Carbon was added in order to increase the combustion temperature as well as to form in situ reinforcements. The reaction products showed homogeneous microstructures with carbide phases formed within indicating that the addition of carbon increased the combustion temperature above the melting temperature of TiAl.

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메탄/산소 난류 확산화염의 연소 특성에 관한 연구 (A Study on Combustion Characteristics of Turbulent Methane/Oxygen Diffusion Flames)

  • 이상민;김호근;김한석;안국영
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.118-123
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    • 2004
  • The combustion characteristics of 0.03MW turbulent methane/oxygen diffusion flames have been investigated to give basic informations for designing industrial oxyfuel combustors. NOx reduction has become one of the most determining factors in the combustor design since 3-5% nitrogen is intrinsically included from the current oxygen producing processes. Flame lengths and NOx concentrations were measured by varying flow velocities with and without installing quarls. Flame stabilities are significantly enhanced by oxyfuel combustion in contrast to air-fuel combustion. Flame length decreases with increasing fuel or oxygen velocity because of the enhancement of turbulent mixing. NOx concentration was reduced with increasing flo velocities. This can be attributed to the entrainment of inert product gases into flame decreasing flame temperature. The installation of quarl on the burners rather increased NOx concentration since the quarl blocked the entrainment above the nozzles.

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Pt/$Al_2O_3$가 코팅된 니켈폼을 이용한 수소-공기 예혼합 기체의 촉매 연소 (Catalytic combustion of $H_2$/Air mixture using Pt/$Al_2O_3$ coated nickel foam)

  • 진정근;권세진
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2007년도 제34회 KOSCO SYMPOSIUM 논문집
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    • pp.37-44
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    • 2007
  • A nickel foam, one of metal foams was seleced as a catalyst support instead of conventional ceramic materials. $Al_2O_3$ was coated on the surface of nickel foam to increase the surface area. $Al_2O_3$ coating process was based on sol-gel process. SEM image was obtained and $Al_2O_3$ coverage was confirmed. Combustion experiments were carried out using SUS combustor and $H_2$/air mixture. Temperatures were measured with different equivalence ratios and $H_2$ flow rates. $H_2$ conversion rates were calculated by the analysis of product gas using gas chromatography. Catalytic combustion of $H_2$ was complete and stable with Pt/$Al_2O_3$ coated nickel foam and influences of water vapor were confirmed during the beginning of combustion.

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