• Journal of the Korean Ceramic Society
• /
• v.31 no.11
• /
• pp.1249-1258
• /
• 1994

Titanium carbide was synthesized by reacting the prepared titanium powder and carbon black using SHS method sustains the reaction spontaneously, utilizing heat generated by the exothermic reaction itself. In this process, the effect of the particle size of titanium powder on combustion temperature and combustion wave velocity was investigated. By controlling combustion temperature and combustion wave velocity via mixing Ti and C powder with TiC, the reaction kinetics of TiC formation by SHS method was considered. Without reference to the change of combustion temperature and combustion wave velocity, TiC was easily synthesized by combustion reaction. As the particle size of titanium powder was bigger, or, as the amount of added diluent(TiC) increased, combustion temperature and combustion wave velocity were found to be decreased. The formation of TiC by combustion reaction in the Ti-C system seems to occur via two different mechanisms. At the beginning of the reaction, when the combustion temperatures were higher than 2551 K, the reaction was considered to be controlled by the rate of dissolution of carbon into a titanium melt with an apparent activation energy of 148 kJ/mol. For combustion temperatures less than 2551 K, it was considered to be controlled by the atomic diffusion rate of carbon through a TiC layer with an apparent activation energy of 355 kJ/mol. The average particle size of the synthesized titanium carbide was smaller than that of the starting material(Ti).

• Bulletin of the Korean Chemical Society
• /
• v.33 no.3
• /
• pp.1009-1014
• /
• 2012

The influence of magnetic fields on chemical processes has long been the subject of interest to researchers. For this time numerous investigations show that commonly the effect of a magnetic field on chemical reactions is insignificant with impact less than 10 percent. However, there are some papers that point to the observation of external magnetic field effect on chemical and biochemical systems actually having a significant impact on the reactions. Thus, of great interest is an active search for rather simple but realistic models, that are based on physically explicit assumptions and able to account for a strong effect of low magnetic fields. The present work theoretically deals with two models explaining how an applied weak magnetic field might influence the steady state of a non-equilibrium chemical system. It is assumed that external magnetic field can have effect on the rates of radical reactions occurring in a system. This, in turn, leads to bifurcation of the nonequilibrium stationary state and, thus, to a drastic change in the properties of chemical systems (temperature and reagent concentration).

• Journal of the Korean Society of Combustion
• /
• v.5 no.2
• /
• pp.37-50
• /
• 2000

In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of $NO-NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propylene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $HO_2$ etc.) successively are produced by hydrocarbon decomposition form the primary path of $NO-NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propylene to have higher affinity with O radical under all conditions, thereby both of these hydrocarbons show very fast and efficient $NO-NO_2$ oxidation. It was also shown that propylene is superior to ethylene in the aspect of NOx removal.

• Journal of the Korean Society of Combustion
• /
• v.9 no.4
• /
• pp.35-46
• /
• 2004

Activation energy asymptotics (AEA) for Linan#s premixed-flame regime is revisited in this paper. First, the detailed AEA procedure for the premixed-flame regime is demonstrated, so that the practitioners of AEA could easily apply the method to their own problems. In addition, the controversies surrounding the premixed-flame regime, namely the closure controversy and fast-time instability paradox, are explained. Finally, the limitation of AEA, mainly arising from the wrong prediction of fuel leakage through the reaction zone, is examined and the Zel#dovich-Linan kinetics is introduced as an alternative to meet the needs of modern combustion analysis, where the detailed chemical structure of flame is demanded.

• Journal of the Korean Society of Combustion
• /
• v.9 no.4
• /
• pp.22-27
• /
• 2004

Lean premix combustion is a best method in low $NO_x$ gas turbine combustor and we must know the characteristics of NO emission in high temperature and pressure condition in premix flame. Numerical analysis was performed to investigate the NO emission characteristics by adopting a counterflow as a model problem using detailed chemical kinetics. Methane $(CH_4)$ was used as a test fuel which is the main fuel of natural gas. The tested parameters were stretch rate, equivalence ratio, initial temperature, and pressure in premix flame. Results showed that NO emission was high in low stretch rate, near stoichiometric equivalence ratio, high initial temperature, and high pressure. Also, the pressure effect was sensitive in high temperature condition.

• Journal of the korean Society of Automotive Engineers
• /
• v.8 no.2
• /
• pp.31-42
• /
• 1986

The prediction of performance, exhaust emissions and EGR effect is made by the SI engine cycle simulation. In this simulation several models are employed - two zome, thermodynamic combustion, mass fraction burned, heat transfer, chemical equilibrium, chemical kinetics for NOx, laminar flame speed for ignition delay. The chemical species in burned gas considered are 13 species-CO$_{2}$, CO, $O_{2}$, H$_{2}$O, H$_{2}$,OH, H, O, N$_{2}$, NO$_{2}$, N, Ar - and the cylinder pressure, burned and unburned zone temperature and composition of gas are calculated at each crank angle through the compression, ignition delay, combustion and expansion process. To check the validity of the model, experimental study is done for measuring emissions, combustion pressure and engine output. The predicted values for pressure and emissions show qualitative agreement with the measured data and the EGR effect also shows similar tendency.

• Journal of the Korea Safety Management & Science
• /
• v.10 no.4
• /
• pp.111-120
• /
• 2008

The combustion reaction of polypropylene was investigated using a thermogravimetric technique under an air atmosphere condition at several heating rates from 10 to $50^{\circ}C/min$. To obtain information on the kinetic parameters, the dynamic thermogravimetric analysis curve and its derivative were analyzed by a variety of analytical methods such as Kissinger, Friedman, Freeman-Carroll, Chatterjee-Conrad, Ozawa and Coats-Redfern methods. The comparative works for the kinetic results obtained from various methods should be performed to determine the kinetic parameters, because there are tremendous differences in the calculated kinetic parameters depending upon the mathematical method taken in the analysis.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.1 no.1
• /
• pp.64-72
• /
• 1997

An analytical study has been performed to investigate the unsteady ignition characteristics of pulse combustion. In many combustion applications, strain rate of the flow can significantly affect the combustion features; ignition, extinction, and reignition. In the pulse combustion, two jets (hot combustion gases and fresh mixtures) coming from the opposite side of the combustor will collide in the combustor forming a stagnation region where the chemical reaction is suppressed by the strain rate until this becomes below the critical value. In this research, the method of large activation energy asymptotic is adopted with one step irreversible kinetics to examine the ignition response to the periodic variation of the strain rate of flow. The results show the variation of the maximum value of strain rate can determine whether the ignition or extinction occur.

• Journal of the Korea Safety Management & Science
• /
• v.11 no.3
• /
• pp.217-226
• /
• 2009

The combustion reaction of polyvinylchloride(PVC) was investigated using a thermogravimetric technique under an air atmosphere condition at several heating rates from 10 to $50^{\circ}C$/min. To obtain information on the kinetic parameters, the dynamic thermogravimetric analysis curve and its derivative were analyzed by a variety of analytical methods such as Kissinger, Friedman, Chatterjee-Conrad, Ozawa and Coats-Redfern methods. The combustion reaction of PVC proceeded in two steps; the first step was caused by the dehydrochlorination process in PVC, and the second step by the combustion of polyene. The comparative works for the kinetic results obtained from various methods should be performed to determine the kinetic parameters, because there are tremendous differences in the calculated kinetic parameters depending upon the mathematical method taken in the analysis.

• Transactions of the Korean hydrogen and new energy society
• /
• v.21 no.2
• /
• pp.123-128
• /
• 2010

Hydriding combustion synthesis (HCS) can produce full hydrides of alloys and in a short time. The conventional process based on ingot metallurgy cannot produce Mg-based alloy easily with the desired composition and the cast product needs a ling activation process for the practical use of hydrogen storage. In this study, the hydriding properties of Mg-xNi (x=5, 13.5, 54.7wt.%) alloys prepared by hydriding combustion synthesis were evaluated. The hydrogen storage capacity and kinetics of HCS Mg-xNi alloys were strongly dependent on the content of Ni. The HCS Mg-13.5wt.%Ni alloy shows the hydriding behavior to reach the maximum capacity within 30 min. and the reversible $H_2$ storage of 5.3wt.% at 623 K.