• Carbon letters
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• v.27
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• pp.81-89
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• 2018

The present study aimed to prepare a novel efficient flame retardant additive for polypropylene. The new flame retardant was prepared by chemical grafting of melamine to graphene oxide with the aid of thionyl chloride. Fourier-transform infrared spectroscopy and thermogravimetric analysis proved that melamine had been successfully grafted to the graphene oxide. The modified graphene oxide was incorporated into polypropylene via solution mixing followed by anti-solvent precipitatio. Homogeneous distribution as well as exfoliation of the nanoplatelets in the polymer matrix was observed using transmission electron microscopy. Thermogravimetric analysis showed a significant improvement in the thermo-oxidative stability of the polymer after incorporating 2 wt% of the modified graphene oxide. The modified graphene oxide also enhanced the limiting oxygen index of the polymer. However, the amount of improvement was not enough for the polymer to be ranked as a self-extinguishing material. Cone calorimetry showed that incorporating 2 wt% of the modified graphene oxide lowered total heat release and the average production rate of carbon monoxide during burning of the polymer by as much as 40 and 35%, respectively. Hence, it was concluded that the new flame retardant can retard burning of the polymer efficiently and profoundly reduce suffocation risk of exposure to burning polymer byproducts.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.295-296
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• 2015

We presented the methods calculating the reduction efficiency of nitrogen oxide for the low $NO_x$ burner as the pollution prevention facilities. The standard $NO_x$ concentration was used on the emission factor of LNG, $3.7g/m^3$. The $NO_x$ reduction efficiency based on the $NO_x$ concentration was presented and the relationships between the $NO_x$ concentration and the emission factor or the specific heat emission factor were derived. These results could be accurately reflected on calculating the amount of the nitrogen oxide emissions. In addition, according to the arrangement of the low $NO_x$ burners the methods of applying their $NO_x$ reduction efficiency were proposed. The $NO_x$ reduction efficiency for the facilities consisting of the low $NO_x$ burners and the non-low $NO_x$ burners could be estimated with information about the reduction efficiency of each low $NO_x$ burners, the fuel consumption rate, and the heating value of fuel.

• Resources Recycling
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• v.4 no.4
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• pp.70-75
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• 1995

Waste tires arc used as landifill, combustion and recycling. Rccenllg. lhc recycling of waste tires received a great attentmu fiam all industries. Thc rccgcling methods for w s l e tires are classified inla three culegoljz, a whole tirc, cmmb rubha and energy. T h ~ ssl iidy invesligvled the pruduclion ol Lhc ruhhcr block by using clumh cubbel oI wasle Ires. The process 01 manulacluring the ~uhher block was co~lsislerl ol several slepc: collecting lilts, ctuilnng and grinding hrcs, mixing crumh ruhher wlth bmder. and shaping under heat and pressure The effccl ol binder on ll~e ~uecl~ilnicaplr opcrlics o l r uhher hlock war also investigalcd. The economic feaqihility of a surface treiilmcnl and multilayas on the rubber block was dclcimincd

• Journal of Power System Engineering
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• v.10 no.1
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• pp.19-24
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• 2006

This work treats a controlled auto-ignition (CAI) single cylinder gasoline engine, focusing on the extension of operating conditions. The fuel was injected indirectly into electrically heated inlet air flow. In order to keep a homogeneous air-fuel mixing, the fuel injector was water-cooled by a specially designed coolant passage. The engine performance and emission characteristics were investigated under the wide range of operating conditions such as 40 in the air-fuel ratio, 1000 to 1800 rpm in the engine speed, 150 to $180^{\circ}C$ in the inlet-air temperature, and $60^{\circ}$ BTDC in the injection timing. The ultra lean-burn with self-ignition of gasoline fuel by heating inlet air was achieved in a controlled auto-ignition gasoline engine. It could be also achieved that the emission concentrations of carbon monoxide, hydrocarbons and nitrogen oxide significantly reduced by CAI combustion compared with conventional spark ignition engines.

• Journal of Mechanical Science and Technology
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• v.19 no.6
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• pp.1358-1365
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• 2005

Flue gas recirculation (FGR) is widely adopted to control NO emission in combustion systems. Recirculated flue gas decreases flame temperature and reaction rate, resulting in the decrease in thermal NO production. Recently, it has been demonstrated that the recirculated flue gas in fuel stream, that is, the fuel induced recirculation (FIR), could enhance much improved reduction in NO per unit mass of recirculated gas, as compared to conventional FGR in air. In the present study, the effect of dilution methods in air and fuel sides on NO reduction has been investigated numerically by using $N_2$ and $CO_2$ as diluent gases to simulate flue gases. Counterflow diffusion flames were studied in conjunction with the laminar flamelet model of turbulent flames. Results showed that $CO_2$ dilution was more effective in NO reduction because of large temperature drop due to the larger specific heat of $CO_2$ compared to $N_2$. Fuel dilution was more effective in reducing NO emission than air dilution when the same recirculation ratio of dilution gas was used by the increase in the nozzle exit velocity, thereby the stretch rate, with dilution gas added to fuel side.

• Journal of the Korean Society of Mechanical Technology
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• v.13 no.3
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• pp.39-47
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• 2011

In a bi-fuel engine using gasoline and LPG fuel, with the current ignition timing for gasoline being used, the optimum performance could not be taken in LPG fuel supply mode. The ignition timing in LPG fuel mode must be advanced much more than that of gasoline mode for the compensation of its higher ignition temperature. The purpose of this study is to investigate how the ignition spark timing conversion influences the engine performance of LPG/Gasoline Bi-Fuel engine. In order to investigate the engine performance during combustion, engine performance are sampled by data acquisition system, for example cylinder pressure, pressure rise rate and heat release rate, while change of the rpm(1500, 2000, 2500) and the ignition timing advance($5^{\circ}$, $10^{\circ}$, $15^{\circ}$, $20^{\circ}$). As the result, between 1500rpm, 2000rpm and 2500rpm, the cylinder pressure and pressure rise rate was increased when the spark ignition was advanced but pressure rise rate at $20^{\circ}$ was smaller value.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.10a
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• pp.205-209
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• 2004

The configuration and arrangement of injector in LRE gas generator and combustor have a great impact on combustion process and heat exchange because of affecting atomization, vaporization, mixing and chemical reaction. A relation between injector array and mixing distribution of propellants based on a physical approach was investigated in this study. Programming method of this relation is used to predict mixing distribution of propellants. Simplicity of physical approach and various assumptions make it reduce the accuracy and application of the results of present study. But, this method is very useful to predict the mixing distribution of full scale combustor due to difficulties in cold flow testing.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.272-278
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• 2011

In the present work, FEM analyses are carried out to investigate the fractures occurred within the structural part in the course of combustion experiment. The loss of structural integrity stems from the localized deformation and the damage induced due to a severe change in the thermal load. Moreover, the two-back stress evolution model is proposed using the Armstrong-Frederick and the Phillips' rules to depict the plastic deformation, and the continuum damage mechanics is also incorporated into the present model. It is noted that the present model is able to formulate a wide range of constitutive description with ease. The numerical results depicts that a severe strain localization and damage evolution can be obtained depending on the dominant back stress.

• Journal of the Korean institute of surface engineering
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• v.54 no.6
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• pp.331-339
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• 2021

Environmental barrier coatings(EBCs) are applied to the SiC/SiC ceramic matrix composites(CMCs) in order to protect CMCs from being corroded with water vapor by combustion gas in gas turbine engines. Ytterbium silicates, such as ytterbium monosilicate and ytterbium disilicate, are ones of the candidate materials for EBCs due to their excellent resistance to water vapor corrosion as well as thermal-expansion match with SiC. In this study, ytterbium silicates are fabricated with 2-step solid-state synthesis targeting ytterbium disilicate. After synthesizing ytterbium monosilicate, the mixtures of ytterbium monosilicate and SiO₂ are heat-treated and densified by using pressureless sintering or hot pressing with a variety of heating conditions. The phase formation, thermal expansion, and oxidation behavior are examined with fabricated specimens. The final densified bodies are found to be composites between ytterbium monosilicate and ytterbium disilicate with different ratios, which results in 4.43 to 6.72×10^-6/K range of coefficients of thermal expansion. The probability of these ytterbium silicates for EBC applications is also discussed.

• Nuclear Engineering and Technology
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• v.53 no.11
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• pp.3798-3807
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• 2021

Tritium extraction from radioactively contaminated cement mortar samples was performed using heating and liquid scintillation counting methods. Tritiated water molecules (HTO) can be present in contaminated water along with water molecules (H₂O). Water is one of the primary constituents of cement mortar dough. Therefore, if tritium is present in cement mortar, the buildings and structures using this cement mortar would be contaminated by tritium. The radioactivity level of the materials in the environment exposed to tritium contamination should be determined for their disposal in accordance with the criteria of low-level radioactive waste disposal facility. For our experiments, the cement mortar samples were heated at different temperature conditions using a high-temperature combustion furnace, and the extracted tritium was collected into a 0.1 M nitric acid solution, which was then mixed with a liquid scintillator to be analyzed in a liquid scintillation counter (LSC). The tritium extraction rate from the cement mortar sample was calculated to be 90.91% and 98.54% corresponding to 9 h of heating at temperatures of 200 ℃ and 400 ℃, respectively. The tritium extraction rate was close to 100% at 400 ℃, although the bulk of cement mortar sample was contaminated by tritium.