• Journal of Energy Engineering
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• v.2 no.2
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• pp.200-207
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• 1993

A methanol reformer was designed and fabricated using a CuO-ZnO low temperature shift catalyst, and its operation characteristics have been studied for the phosphoric acid fuel cell (PAFC) power generation system. The type of reactor was annular Methanol was consumed both for heating and for reforming fuel. Contents of carbon monoxide produced from the reformer increased as the reaction temperatures increased, but decreased as the mole ratios of water to methanol(H$_2$O/CH$_3$OH) increased. At steady state operating conditional, temperature profile of the catalytic reactor of the reformer was well coincide with the model equation, and it took 50 minutes from start to the rated condition of the reformer. When the system was operated at 4/4 and 1/4 of load, thermal efficiencies of the system were 72.3% and 77%, respectively. When the PAFC system was operated with reformed gas in the range of 62 V-37.6 V and 0-147 A, the trend of I-V curve showed a typical fuel tell characteristic. At steady state condition, the flow rates of reforming and combustion methanol were 88.1 mol/h and 50.1 mol/h, respectively.

• Korean Journal of Materials Research
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• v.28 no.1
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• pp.6-11
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• 2018

There are various manufacturing processes for pure $SiO_2$ that is used as abrasives, chemicals, filters, and glasses, and in metallurgy and optical industries. In the optical fiber industry, to produce $SiO_2$ preform, $SiCl_4$ is utilized as a raw material. However, the combustion reaction of $SiCl_4$ has caused critical environmental issues, such as ozone deficiency by chlorine compounds, the greenhouse effect by carbon dioxide and corrosive gas such as hydrochloric acid. Thus, finding an alternative source that does not have those environmental issues is important for the future. Octamethylcyclotetrasiloxane (OMCTS or D4) as a chlorine free source is recently promising candidate for the $SiO_2$ preform formation. In this study, we first conducted a vaporizer design to vaporize the OMCTS. The vaporizer for the OMCTS vaporization was produced on the basis of the results of the vaporizer design. The size of the primary particle of the $SiO_2$ formed by OMCTS was less than 100 nm. X-ray diffraction patterns of the $SiO_2$ indicated an amorphous phase. Fourier-transform infrared spectroscopy analysis revealed the Si-O-Si bond without the -OH group.

• Resources Recycling
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• v.27 no.3
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• pp.58-65
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• 2018

For the recycling of coal ash from the domestic circulating fluidized bed boilers, a lime-based sorbent with 0.2~0.4 mm size was prepared by using limestone powder and CFBC fly ash. Mixing a small amount of slaked lime in the lime-based absorbent lead the formation of calcium silicate on the surface of the particle and the strength of absorbent particle was improved. As a result of comparing the desulfurization characteristics, it was found that the conversion rate was about 10% higher than that of commercially available limestone desulfurization used in the furnace, which is confirmed that it can be used as a desulfurization absorbent.

• Toxicological Research
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• v.31 no.1
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• pp.41-48
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• 2015

Owing to the increase in price of cigarettes in Korea, herbal cigarettes have received increasing attention as a non-smoking aid; however, its safety has hardly been studied. We analyzed some of the toxic components in the mainstream smoke of herbal cigarettes, performed a mutagenicity test on smoke condensates for safety assessment, and compared the results with the corresponding values of a general cigarette with the same tar content. Herbal cigarette "A" was smoked using automatic smoking machine under ISO conditions in a manner similar to general cigarette "T". The tar content measured was higher than that inscribed on the outside of a package. The mainstream smoke of herbal cigarette "A" did not contain detectable levels of tobacco-specific nitrosamines and nicotine. Carbon monoxide and benzo(${\alpha}$)pyrene contents in herbal cigarette "A" were higher than those in the general cigarette "T". The phenolic contents such as hydroquinone, resorcinol, and catechol in herbal cigarette "A" were higher than those in the general cigarette "T", but cresol contents in herbal cigarette "A" were lower than those in the general cigarette "T". The content of aromatic amines such as 4-aminobiphenyl in herbal cigarette "A" was higher than that in the general cigarette "T"; however, this difference was not statistically significant. On the other hand, 1-aminonaphthalene, 2-aminonaphthalene, and 3-aminobiphenyl contents in herbal cigarette "A" were lower than those in the general cigarette "T". The smoke condensates of herbal cigarette "A" exhibited a higher mutagenic potential than the condensates from the general cigarette "T" at the same concentration. We concluded that the mainstream smoke of herbal cigarette contains some toxic components, the smoke condensates of herbal cigarettes are mutagenic similar to general cigarette because of combustion products, and that the evaluation of the chemical and biological safety of all types of herbal cigarettes available on the market.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.3
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• pp.54-62
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• 2007

The knock characteristics in an engine were investigated under homogeneous charge compression ignition (HCCI) operation. Liquefied petroleum gas (LPG)and gasoline were used as fuels and injected at the intake port using port fuel injection equipment. Di-methyl ether (DME) was used as an ignition promoter and was injected directly into the cylinder near compression top dead center (TDC). A commercial variable valve timing device was used to control the volumetric efficiency and the amount of internal residual gas. Different intake valve timingsand fuel injection amounts were tested to verify the knock characteristics of the HCCI engine. The ringing intensity (RI) was used to define the intensity of knock according to the operating conditions. The RI of the LPG HCCI engine was lower than that of the gasoline HCCI engine at every experimental condition. The indicated mean effective pressure (IMEP) dropped when the RI was over 0.5 MW/m2and the maximum combustion pressure was over 6.5MPa. There was no significant relationship between RI and fuel type. The RI can be predicted by the crank angle degree (CAD) at 50 CA. Carbon monoxide (CO) and hydrocarbon (HC) emissions were minimized at high RI conditions. The shortest burn duration under low RI was effective in achieving low HC and CO emissions.

• Clean Technology
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• v.11 no.4
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• pp.171-179
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• 2005

Biodiesel is synthesized by transesterification of vegetable or animal oils with alcohols. Since it has similar characteristic with diesel fuel, it can be used as a fuel by mixing with diesel fuel. Moreover, it is advantageous that biodiesel can reduce air pollution emitted from fuel combustion and is produced from sustainable energy, biomass. Recently, many researchers have investigated biodiesel synthesis using supercritical methanol since it is economical due to shorter reaction time and simple separation/purification process, compared with conventional alkali- or acid-catalyzed process. By the development of biodiesel production process from waste edible oil using supercritical methanol, it can be expected to utilize potential energy resources, reduce carbon dioxide emission, and improve environmental conditions.

• Fire Science and Engineering
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• v.33 no.5
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• pp.13-18
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• 2019

In this study, the soot formation characteristics of Jet-A1 liquid fuel droplet flames were investigated by measuring the soot concentration under atmospheric conditions similar to the working environment of the Korea Space Launch Vehicle (KSLV) To obtain the desired atmospheric conditions, the oxygen concentration in the combustion chamber was maintained at 30% and the pressure was varied between 0.1 and 0.06 MPa. The full-field light extinction technique was used to measure the concentration of soot particles generated by applying the identical to 2-mm-diameter Jet-A1 fuel droplets. The soot concentration of the Jet-A1 droplet flames was the highest in the nitrogen-substituted atmosphere and the lowest in the carbon dioxide-substituted atmosphere, despite the pressure. the pressure was decreased the measured soot concentrations reduced as a function of Pⁿ.

• The KSFM Journal of Fluid Machinery
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• v.13 no.1
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• pp.9-16
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• 2010

In the power generation industry, various efforts are needed to cope with tightening regulation on carbon dioxide emission. Integrated gasification combined cycle (IGCC) is a relatively environmentally friendly power generation method using coal. Moreover, pre-combustion $CO_2$ capture is possible in the IGCC system. Therefore, much effort is being made to develop advanced IGCC systems. However, removal of $CO_2$ prior to the gas turbine may affect the system performance and operation because the fuel flow, which is supplied to the gas turbine, is reduced in comparison with normal IGCC plants. This study predicts, through a parametric analysis, system performances of both an IGCC plant using normal syngas and a plant with $CO_2$ capture. Performance characteristics are compared and influence of $CO_2$ capture is discussed. By removing $CO_2$ from the syngas, the heating value of the fuel increases, and thus the required fuel flow to the gas turbine is reduced. The resulting reduction in turbine flow lowers the compressor pressure ratio, which alleviates the compressor surge problem. The performance of the bottoming cycle is not influenced much.

• Journal of the Korean Institute of Gas
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• v.15 no.2
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• pp.21-26
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• 2011

Emissoin of heavy duty vehicle have much positioned in air pollution although its limited number of vehicles. CNG vehicles are coming to the fore as one of the solution of diesel vehicles. CNG vehicles exhaust smaller emission than diesel vehicles on PM and NOx. In this study, aftertreatment technologies are introduced on vehicles which use CNG and hydrogenmixed fuel. Withmixing hydrogen with CNG, combustion efficiency is enhanced, and harmful emission might be decreased, but methane that is main component of CNG brings green house effect. In order to remove methane and NOx in exhaust gas of CNG engine, methane oxidation catalyst and SCR technologies were respectively analyzed.

• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.752-760
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• 2018

The lowering of temperature for combustion of diesel particulate matters (or diesel soot) is one of the important tasks in automotive industry that is searching for a way to meet up "high-fuel efficiency, low-emission" standard. In this study, it was discussed how the use of ozone over platinum-based catalyst promotes a low-temperature soot oxidation occurred at $150^{\circ}C$. The use of platinum catalyst did not increase oxidation rate largely but was very effective in improving the selectivity of carbon dioxide. The pre-oxidation of NO into $NO_2$ using ozone was rather crucial in improving the oxidation rate of soot at $150^{\circ}C$.