• Journal of Energy Engineering
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• v.19 no.2
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• pp.136-142
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• 2010

Combustion reactivity and thermal behavior of two imported coals used as a pulverized fuel of commercially thermal power plant were investigated by thermogravimetric analysis (TGA) and large scale test furnace of 200 kg/hr. TGA results showed that combustion efficiency of high moisture coal has lower than reference coal due to the slow combustion completion rate although it has the low ignition temperature, and activation energies of high moisture coal with 79 kJ/mol for overall combustion was higher than reference coal of 53 kJ/mol. Test furnace results ascertained that flame of black band of high moisture coal during the combustion in boiler broke out compared to reference coal and then it becomes to unburned carbon due to the less reactivity and combustion rate. But, Blending combustion of high moisture coal with design coal of high sulfur are available because sulfur content of high moisture coal was too low to generate the low SOx content in flue gas from boiler during the combustion. The ash analysis results show that it was not expected to be associated with slagging and fouling in pulverized coal fired systems due to the low alkali metal content of $Na_2O$ and $K_2O$ compared to bituminous coal.

• Fire Science and Engineering
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• v.31 no.6
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• pp.23-32
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• 2017

Foam block, popularized as the self-interior goods, is susceptible to fire since the main material is the polyethylene flammable synthetic resin. However, it is widely used in homes, offices, and multi-use facilities. In order to understand the fire characteristics of the foam block, two kinds of foam blocks sold in the market (non-fire retardant and fire retardant) were evaluated according to standard of KS F 5660-1 (Reaction to fire test). In addition, the hazard analysis of the gas generated by the combustion of the specimen was performed using the FTIR gas analyzer. The cone calorimeter test showed that the ignition and flame combustion of both two specimens were burned as soon as the radiant heat blocking device was removed, and it was confirmed that the flame could become a rapid propagation factor during the fire. The analysis of the combustion gas through the FTIR gas analyzer showed that both the carbon dioxide and carbon monoxide classified as the common combustion gases and the acrolein, ammonia, and hydrogen cyanide causing serious damage to the human body were detected substantially. This study showed that a foam block product has high ignitionability and generates toxic gases. Hence, it is urgently required to establish the standards used for properly classifying the combustion characteristics of the material on the basis of the use conditions of a foam block product and to prepare the standards on the purpose of use.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.2
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• pp.174-180
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• 2017

Recently, the world faces the environmental problem such as air pollution due to harmful gas discharged from car and abnormal climate due to the green-house gases increased by the discharge of $CO_2$. Compressed Natural Gas (CNG), one of alternative for this problem, is less harmful, compared to the existing fossil fuel, as gaseous fuel, and less carbon in fuel ingredients and carbon dioxide generation rate relatively favorable more than the existing fuel. However, CNG fuel has the weakness of slow flame propagation speed and difficult fast burn. On the other hand, hydrogen does not include carbon in fuel ingredients, and does not discharge harmful gas such as CO and HC. Moreover, it has strength of quick burning velocity and ignition is possible with small ignition energy source and it's has wide Lean Flammability Limit. If using this hydrogen with CNG fuel, the characteristics of output and discharge gas is improved by the mixer's burning velocity improved, and, at the same time, is possible to have stable lean combustion with the reduction of $CO_2$ expected. Therefore, this research tries to identify the characteristics of engine and emission gas when mixing CNG fuel and hydrogen in each portion and burning them in spark igniting engine, and grasp the lean combustion limit and emission gas characteristics according and use it as the basic data of hydrogen-CNG premixed engine.

• Transactions of the Korean hydrogen and new energy society
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• v.14 no.1
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• pp.24-34
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• 2003

For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion may yield great advantages for the savings of energy to $CO_2$ separation and suppressing the effect on environment, In chemical-looping combustor, fuel is oxidized by metal oxide medium in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. In this study, five oxygen carrier particles such as NiO/bentonite, NiO/YSZ, $(NiO+Fe_2O_3)VYSZ$, $NiO/NiAl_2O_4$, and $Co_{\chi}O_y/CoAl_2O_4$ were examined &om the viewpoints of reaction kinetics, oxygen transfer capacity, and carbon deposition characteristics. Among five oxygen particles, NiO/YSZ particle is superior in reaction rate, oxygen carrier capacity, and carbon deposition to other particles. However, at high temperature ($>900^{\circ}C$), NiO/bentonite particle also shows enough reactivity and oxygen carrier capacity to be applied in a practical system.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.4
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• pp.357-364
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• 2016

Recently, the world faces the environmental problem such as air pollution due to harmful gas discharged from car and abnormal climate due to the green-house gases increased by the discharge of $CO_2$. Compressed Natural Gas (CNG), one of alternative for this problem, is less harmful, compared to the existing fossil fuel, as gaseous fuel, and less carbon in fuel ingredients and carbon dioxide generation rate relatively favorable more than the existing fuel. However, CNG fuel has the weakness of slow flame propagation speed and difficult fast burn. On the other hand, hydrogen does not include carbon in fuel ingredients, and does not discharge harmful gas such as CO and HC. Moreover, it has strength of quick burning velocity and ignition is possible with small ignition energy source and it's has wide Lean Flammability Limit. If using this hydrogen with CNG fuel, the characteristics of output and discharge gas is improved by the mixer's burning velocity improved, and, at the same time, is possible to have stable lean combustion with the reduction of $CO_2$ expected. Therefore, this research tries to identify the characteristics of engine and emission gas when mixing CNG fuel and hydrogen in each portion and burning them in spark igniting engine, and grasp the combustion stability and emission gas characteristics according and use it as the basic data of hydrogen-CNG premixed engine.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.6
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• pp.524-534
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• 2013

Gasoline direct injection(GDI) engine has a high thermal efficiency, but it has a problem to increase carbon emissions such as soot and $CO_x$. In this study, the objective is to analyze numerically a problem for adding the hydrogen during the intake stroke so as to reduce the injected amount of gasoline in GDI engines. For selection of the base model, the cylinder pressure of simulation is matched to experimental data. The numerical analysis are carried out by a CFD model with the hydrogen addition of 2%, 3% and 4% on the volume basis. In the case of 3% hydrogen addition, the injected gasoline amount is only changed to match the maximum pressure of simulation to that of the base model for additional study. It is found that the combustion temperature and pressure increase with the hydrogen addition. And NO emission also increases because of the higher combustion temperature. $CO_x$ emissions, however, are reduced due to the decrease of injected gasoline amount. Also, as the injected gasoline amount is reduced for the same hydrogen addition ratio, the gross indicated work is no significant, But NO and $CO_x$ emissions are considerably decreased. On the order hand, $CO_x$ emissions of two cases are more decreased and their gross indicated works are higher obtained than those of the base model.

• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.3
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• pp.18-28
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• 2007

Three diesel engines were fueled with BDF 20, a blend of 80% diesel fuel and 20% biodiesel fuel by volume, and run in excess of 200 h to evaluate their combustion characteristics and durability. The engines used for this study were a 4-cylinder 2476-cc displacement IDI diesel engine(Engine 1), a 4-cylinder l732-cc displacement IDI diesel engine(Engine 2), and a single cylinder 673-cc displacement DI diesel engine(Engine 3). Engine dynamometer testing was performed on each engine at regularly scheduled intervals to monitor the performance and exhaust emissions, which were sampled at 1h intervals for analysis, The peak combustion pressure with BDF 20 increased in Engines 1 and 3 over that measured when burning pure diesel fuel, but that in Engine 2 remained constant. Combustion parameters, such as the maximum combustion pressure and corresponding crank angle, did not change over the long-term dynamometer testing. The BSFC with BDF 20 in Engine 1 was less than that measured with pure diesel fuel. The amount of smoke produced with BDF 20 was less for all engines ; the greatest reduction was observed for Engine 3. The NOx emissions were lower in the IDI engines than the DI engine. The traditional trade-off between smoke and NOx emissions was maintained for BDF 20 fuel for Engines 1 and 3. There was not a big difference in the $CO_2\;and\;O_2$ emissions for BDF 20, as compared to pure diesel fuel, but more $CO_2$ was exhausted by Engine 1 than by Engines 2 or 3 and less $O_2$ was exhausted by Engine 1 than by Engines 2 or 3. The engine parts remained clean, except for some carbon attached to the area surrounding the nozzle hole of the DI diesel engine.

• Nuclear Engineering and Technology
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• v.47 no.1
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• pp.26-32
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• 2015

During the course of a severe accident in a light water nuclear reactor, large amounts of hydrogen can be generated and released into the containment during reactor core degradation. Additional burnable gases [hydrogen ($H_2$) and carbon monoxide (CO)] may be released into the containment in the corium/concrete interaction. This could subsequently raise a combustion hazard. As the Fukushima accidents revealed, hydrogen combustion can cause high pressure spikes that could challenge the reactor buildings and lead to failure of the surrounding buildings. To prevent the gas explosion hazard, most mitigation strategies adopted by European countries are based on the implementation of passive autocatalytic recombiners (PARs). Studies of representative accident sequences indicate that, despite the installation of PARs, it is difficult to prevent at all times and locations, the formation of a combustible mixture that potentially leads to local flame acceleration. Complementary research and development (R&D) projects were recently launched to understand better the phenomena associated with the combustion hazard and to address the issues highlighted after the Fukushima Daiichi events such as explosion hazard in the venting system and the potential flammable mixture migration into spaces beyond the primary containment. The expected results will be used to improve the modeling tools and methodology for hydrogen risk assessment and severe accident management guidelines. The present paper aims to present the methodology adopted by Institut de Radioprotection et de $S{\hat{u}}ret{\acute{e}}$ $Nucl{\acute{e}}aire$ to assess hydrogen risk in nuclear power plants, in particular French nuclear power plants, the open issues, and the ongoing R&D programs related to hydrogen distribution, mitigation, and combustion.

• Journal of the Korean Institute of Gas
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• v.19 no.6
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• pp.8-14
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• 2015

Synthetic natural gas(SNG), acquired from coal, is regarded as an alternative to natural gas since a rise in natural gas due to high oil price can be coped with it. In the present study, 11-liter heavy duty compressed natural gas(CNG) engine was employed in order to examine the combustion and emission characteristics of SNG. The simulated SNG, made up 90.95% of methane, 6.05% propane and 3% hydrogen was used in the experiment. Power output, thermal efficiency, combustion stability and emission characteristics were compared to those with CNG at the same engine operating conditions. Knocking phenomenon was also analyzed at 1260 rpm, full load condition. Combustion with SNG was more stable than CNG. Nitrogen oxides emissions increased while Carbon dioxides emissions decreased. Anti-knocking characteristics were improved with SNG.

• Journal of the Korean Chemical Society
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• v.19 no.3
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• pp.186-192
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• 1975

In the course of anthracite briquet combustion, air draft is usually controlled to continue burning of definite amount of briquet in the conventional hollow clay cylinder with air inlet hole open for given time, so that a large amount of CO tends to be produced. Therefore, it is necessary to establish an improved combustion process to depress the yielding rate of CO and for this purpose, we performed a basic experiment in which combustion rate of CO was measured in the mixture of $N_2, O_2 $and CO gas with or without the presence charcoal at the various temperature. The observed results showed that the burning temperature of CO is about 680${\sim}700^{\circ}C$, further burning rate of it was increased with increasing the amount of draft. From these facts, longer combustion time and low CO generation are thus contradictory to each other and it has been long desired to make those two compatible somehow. The purpose of the present investigation lies in designing an effective new briquet stove to meet the above requirements. The essential feature of the new briquet stove consisted in the use of two hollow iron cylinders with different inside diameter. A cylindrical air jacket thus formed served as a path through which small amount of secondary air run from the bottom of the stove to the upper vent holes. Heat exchange occurred between the upgoing secondary air and the burning briquet, which lowered the combustion temperature of the briquet. The results observed were selfevident as anticipated. It was confirmed that the combustion time was increased tolerably due to the heat loss from the combustion zone and that CO in the flue gas was reoxidized at the upper portion of the stove by the upgoing hot secondary air. By this reoxidation reaction the concentration of CO in the flue gas was found to be about 1/20 of that in case the conventional clay cylinder was used as briquet jacket.