• Polymer(Korea)
• /
• v.24 no.3
• /
• pp.287-298
• /
• 2000

In preparing micron-sized monodisperse polystyrene beads by dispersion polymerization, the conversion, and the particle size and its distribution were affected by the reaction temperature, concentration of the monomer, solvent and initiator, molecular weight and concentration of the steric stabilizer, amount of oxygen existing in the reactor, and an appropriate combination of these starting materials. Ethanol as a dispersing agent, styrene as a monomer, PVP as a steric stabilizer, AIBN as an initiator, DVB as a cross-linking agent and toluene as a co-solvent were the basic materials for the synthesis. The reaction rate and the conversion were increased with the reaction temperature and the amount of DVB from 1 to 4%, and the conversion was saturated after 10 hours of the reaction time. The optimum reaction recipe for the preparation of the monodisperse PS beads was 25% styrene monomer, 0.5% DVB, 25% toluene, 10-15% PVP, and 2 and 4% AIBN, thereby, 3.9~4 ${\mu}{\textrm}{m}$ and 3.4~9.3 ${\mu}{\textrm}{m}$ of polystyrene beads, respectively, were successfully synthesized.

• Journal of Energy Engineering
• /
• v.28 no.3
• /
• pp.26-33
• /
• 2019

A comparison of CL 13% and 17% IBLOCA counterpart tests(CPTs) between the ATLAS and LSTF facilities was carried out and the behavior of peak cladding temperatures(PCTs) and related thermal hydraulic phenomena were investigated and discussed. There appeared quite a big difference in PCT behavior between the two CPTs and a further comparison of reactor coolant system design between the two facilities was performed. As a result, there was a difference in fuel alignment plate (FAP) design, e.g., one FAP in ATLAS, a combination of upper core plate and upper end box in LSTF, respectively. The FAP design mainly affects the reflux condensate behavior in IBLOCA tests and any difference in FAP design can be a possible reason for different PCT behavior between the two facilities. It should be a further study to find the reason of different PCT behvior between the two facilites.

• Nuclear Engineering and Technology
• /
• v.54 no.2
• /
• pp.579-588
• /
• 2022

In order to meet the needs of domestic reactor severe accident analysis program, a MIDAC (Module Invessel Degraded severe accident Analysis Code) is developed and maintained by Xi'an Jiaotong University. As the accuracy of the calculation results of the analysis program is of great significance for the formulation of severe accident mitigation measures, the article select three experiments to evaluate the updated severe accident models of MIDAC. Among them, QUENCH-06 is the international standard No.45, QUENCH-16 is a test for the analysis of air oxidation, and FROMA is an out-of-pile fuel rod melting experiment recently carried out by Xi'an Jiaotong University. The heating and melting model with lumped parameter method and the steam oxidation model with Cathcart-Pawel and Volchek-Zvonarev correlations combination in MIDAC could better meet the needs of severe accident analysis. Although the influence of nitrogen still need to be further improved, the air oxidation model with NUREG still has the ability to provide guiding significance for engineering practice.

• Nuclear Engineering and Technology
• /
• v.56 no.1
• /
• pp.78-91
• /
• 2024

Double steel plate concrete composite shear wall (SCSW) has been widely utilized in nuclear power plants and high-rise structures, and its shear connectors have a substantial impact on the seismic performance of SCSW. Therefore, in this study, the mechanical properties of SCSW with angle stiffening ribs as shear connections were parametrically examined for the reactor containment structure of nuclear power plants. The axial compression ratio of the SCSW, the spacing of the angle stiffening rib arrangement and the thickness of the angle stiffening rib steel plate were selected as the study parameters. Four finite element models were constructed by using the finite element program named ABAQUS to verify the experimental results of our team, and 13 finite element models were established to investigate the selected three parameters. Thus, the shear capacity, deformation capacity, ductility and energy dissipation capacity of SCSW were determined. The research results show that: compared with studs, using stiffened ribs as shear connectors can significantly enhance the mechanical properties of SCSW; When the axial compression ratio is 0.3-0.4, the seismic performance of SCSW can be maximized; with the lowering of stiffener gap, the shear bearing capacity is greatly enhanced, and when the gap is lowered to a specific distance, the shear bearing capacity has no major affect; in addition, increasing the thickness of stiffeners can significantly increase the shear capacity, ductility and energy dissipation capacity of SCSW. With the rise in the thickness of angle stiffening ribs, the improvement rate of each mechanical property index slows down. Finally, the shear bearing capacity calculation formula of SCSW with angle stiffening ribs as shear connectors is derived. The average error between the theoretical calculation formula and the finite element calculation results is 8% demonstrating that the theoretical formula is reliable. This study can provide reference for the design of SCSW.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.28 no.1
• /
• pp.53-64
• /
• 2020

A 2㎥/d combined wastewater treatment pilot plant containing the multi-stage vertical stacking type nitrification reactor was installed and operated for more than 1 year under the operating conditions of the short-circuit nitrogen process (pH 8, DO 1mg/L and Internal return rate 4Q from nitrification to denitrification reactor). For economically the combination treatment of food wastewater and the leachate from a landfill, the optimal combination ratio was operated by adjusting the food wastewater with the minimum oil content to 5-25% of the total throughput. The main treatment efficiency of the three-phase centrifugal separator which was introduced to effectively separate solids and oil from the food wastewater was about 52% of SS from 116,000mg/L to 55,700mg/L, and about 48% of normal hexane (NH) from 53,200mg to 27,800 mg/L. During the operational period, the average removal efficiency in the combined wastewater treatment process of BOD was 99.3%, CODcr 94.2%, CODmn 90%, SS 70.1%, T-N 85.8%, and T-P 99.2%. The average concentrations of BOD, CODcr, T-N, and T-P of the treated water were all satisfied with the discharge quality standard for landfill leachate ("Na" region), and SS was satisfied after applying the membrane process. On-site leachate had a relatively high nitrite nitrogen content in the combined wastewater due to intermittent aeration of the equalization tanks and different monthly discharges. Nevertheless nitrite nitrogen was accumulated, denitrification from nitrite nitrogen was observed rather than denitrification after complete nitrification. The average input of anti-forming chemical during the operation period is about 2L/d, which seems to be economical compared to the input of methanol required to treat the same wastewater.

• Journal of Sensor Science and Technology
• /
• v.6 no.1
• /
• pp.35-42
• /
• 1997

The optical biosensor using the electrically controlled release of reactive reagent is developed for the detection of peroxide. Rapid degradation of polymer complex of PEOx and PMAA occurs as the applied current increases and thus released amount of HPA increases. The degradation velocity of polymer and the amount of HPA released are linearly proportional to the applied current. Peroxide is reacted with the released reagent by peroxidase and then the product, a fluorescent dimer DBDA, is formed. The monochromic light from light source (150W Xe arc ramp) excites the DBDA and the excited light is transmitted through an optical fiber to be detected by a photodiode array. The change of fluorescence intensity is related to the change of peroxide concentration. The peroxidase is entrapped in Ca-alginate get on the inner surface. The biosensor has the linear signal range of 0.025mM-10.mM peroxide. By applying the step function of peroxide, reproducibility of biosensor has been investigated. The mathematical model is constructed by the combination of enzyme kinetics with reactor flow model. Good agreement is obtained between the experimental result and model prediction in the sensor signal.

• Applied Chemistry for Engineering
• /
• v.21 no.4
• /
• pp.445-451
• /
• 2010

$TiO_2$ shows considerably efficient photoreaction activity under the ultraviolet range but it has disadvantage that there is no activity in the visible light range. In this study, it was tried to find a solution for the problem of this kind of photocatalyst by utilizing transition metal, which can show electronic transition with $TiO_2$ in the visible light area. Photocatalyst was prepared, which can have photocatalytic activity in the wide wavelength range, not only ultraviolet region but also visible light area and prevent the combination of electron and hole hindering the photoreaction. For this purpose, by using the ion exchange method, $TiO_2$ precursor and transition metal precursor were dipped into H typed strong acid ion-exchange resin. And two kind photocatalysts (Ti-M-SCM) in which transition metal and titanium dioxide coexist through the carbonization/activation process was prepared. Moreover, photolytic reaction under the wavelength 254 nm and 365 nm was performed for humic acid (HA) in the continuous reactor in order to estimate the efficiency of produced Ti-M-SCM.

• Korean Journal of Environmental Agriculture
• /
• v.29 no.2
• /
• pp.197-205
• /
• 2010

This study was conducted to investigate the optimum conditions for efficient methane production through anaerobic digestion of pig waste slurry. The examined parameters were organic matter content of the pig slurry, the ratio of seed sludge to pig slurry, and stirring intensity of the digestion reactor. The effects of types of slurry produced from different purpose-based pigs fed with different feeds were also tested. The methane concentration in the produced biogas was 45% when the ratio of seed sludge to pig slurry was 50% and total solid (TS) concentration was 1%, and it increased in proportional to TS concentration increases from 3 to 7%. At 3 and 5% of TS concentration, increasing mixing velocity from 80 to 160 rpm resulted in higher biogas production amount. However, mixing amount of seed sludge did not cause any significant effect on biogas production. Overall, the most efficient biogas production was achieved at 3-5% TS concentration in combination with 50% seed sludge inoculation and mixing velocity at 120 rpm. Among pig slurry types, gestating sow waste slurry showed the highest biogas production probably due to higher the degradation rate than other types of pig waste slurry being affected by the feeds components.

• Journal of Energy Engineering
• /
• v.26 no.2
• /
• pp.1-11
• /
• 2017

While they are becoming more viable, synthetic natural gas (SNG) plants, with their high temperatures and pressures, are still heavily dependent on advancements in the state-of-the-art technologies. However, most of the current work in the literature is focused on optimizing chemical processes and process variables, with little work being done on relevant mechanical damage and maintenance engineering. In this study, a combination of pipe system stress analysis and detailed local stress analysis was implemented to prioritize the inspection locations for main pipes of SNG plant in accordance to ASME B31.3. A pipe system stress analysis was conducted for pre-selecting critical locations by considering design condition and actual operating conditions such as heat-up and cool-down. Identified critical locations were further analyzed using a finite element method to locate specific high-stress points. Resultant stress values met ASME B31.3 code standards for the gasification reactor and lower transition piece (bend Y in Fig.1); however, it is recommended that the vertical displacement of bend Y be restricted more. The results presented here provide valuable information for future risk based maintenance inspection and further safe operation considerations.

• Journal of Korean Society of Environmental Engineers
• /
• v.37 no.9
• /
• pp.499-504
• /
• 2015

The composite anodes of expanded graphite (EG) and multiwall carbon nanotube (MWCNT) for microbial fuel cells were fabricated by using coal tar pitch (CTP) binder containing nickel (Ni), and the effect of the anodes with the binders on the performance of the MFCs were examined in a batch reactor. During the start-up of the MFCs, quick increase in voltage was observed after a short lag phase time, indicating that the CTP binder is biocompatible. The biomass attatched on the anode surface was more at higher Ni content in the binder, as well as at smaller amount of CTP binder for the fabrication of the anode. The internal resistance of the MFC was smaller for the anode with more biomass. Based on the results, the ideal combination of CTP and Ni for the CTP binder for anode was 2 g and 0.2 g, respectively. The maximum power density was $731.8mW/m^2$, which was higher 23.7% than the anode with Nafion binder as control. The CTP binder containing Ni for the fabrication of anode is a good alternative in terms of performance and economics of MFCs.