• Environmental Engineering Research
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• 제25권2호
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• pp.197-204
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• 2020

A number of different nanoscale zero-valent iron (nZVI) materials have been prepared and compared depending on the desired properties for the particular application, but different physicochemical properties of this prepared nZVI make it difficult to universally compare and standardize them to the same scale. In this study, we aimed to demonstrate a simple microplate-based colorimetric assay using 4-chlorophenol as an indicator with respect to the remediation of real treatment targets, such as trichloroethylene (TCE), 1,1,1-trichloroethane (TCA), and atrazine. Effect of nickel contents on 4-chlorophenol reduction was successfully investigated by the miniaturized colorimetric assay. In the same manner, the effect of nickel contents on dehalogenation of TCE, TCA, and atrazine was investigated and the pseudo-first-order kinetic constants were compared with the results for 4-chlorophenol. The similar pattern could be observed between 4-chlorophenol reduction obtained by colorimetric assay and TCE, TCA, atrazine reduction obtained by a traditional chromatographic method. The reaction kinetics does not match perfectly, but the degree of reaction can be estimated. Therefore, the colorimetric assay can be a useful and simple screening tool to determine nZVI reactivity toward halogenated organics before it is applied to a particular remediation site.

• 한국감성과학회:학술대회논문집
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• 한국감성과학회 2012년도 춘계학술대회
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• pp.124-125
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• 2012

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.541-544
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• 2003

Chloride diffusivity is one of the important properties of concrete affecting the durability of a structure. The diffusivity for porous materials is determined conventionally by immersion in a solution. However, this method is complicate and time-consuming, often requiring months or years to obtain results. Thus, the application of colorimetric method to estimate the apparent diffusivity of chloride ion was verified in this study. The result reveals that the apparent diffusivity of chloride ion can be predicted to use colorimetric method. Additionally the colorimetric method is capable to predict the profile of chloride ion.

• 감성과학
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• 제21권1호
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• pp.143-154
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• 2018

본 연구는 친환경적이고 감성적인 패션상품의 색채기획을 위한 자료를 제공하고자 수행되었다. 쪽과 괴화로 복합염색 후 무매염 견직물과 4종의 매염제(Al, Cu, Fe, Zn)를 처리한 견직물에 대하여 색채특성을 측정하였다. 또한 복합염색 후 매염처리된 연두색 견직물에 대하여 여대생을 대상으로 색채감성과 색채 선호도를 조사하였으며, 색채특성과 색채감성이 색채 선호도에 미치는 영향을 분석하였다. 쪽/괴화로 복합염색된(무매염) 견직물은 선 염색한 쪽 농도가 $10g/{\ell}$이면 녹색, 쪽 $20g/{\ell}$을 사용하면 청록색을 나타내었으며, 4종의 매염제를 사용하여 처리시 거의 모든 경우 연두색을 나타내었다. 연두색을 나타내는 복합염색된 견직물 10종의 색채감성을 요인분석한 결과, 유쾌성, 품위성, 편안성 요인으로 분류되었으며, 이러한 색채감성은 쪽 농도와 매염제의 종류에 따라 대부분 유의한 차이를 보였다. 또한 복합염색된 연두색 견직물의 색채특성과 색채감성요인 간에는 대부분 유의한 상관성을 보여, $L^*$값, $b^*$값, $C^*$값이 크고 $a^*$값이 작을수록 유쾌성과 편안성 감성을 더 강하게 느끼며, $L^*$값이 작고 $a^*$값이 클수록 품위성 감성을 더욱 느끼는 것으로 나타났다. 따라서 쪽과 괴화로 복합염색하고 매염처리한 연두색 견직물의 색채감성요인을 예측변수로 활용할 수 있는 색채 선호도 예측 회귀식이 제안되었다.

• 대한치과교정학회지
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• 제21권1호
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• pp.7-16
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• 1991

To estimate the possibility of the application of TiN ion-plating to the orthodontic appliance, colorimetric properties, and characteristics of ion-plated film as well as adhesive strength of TiN film to the substrate and mechanical properties of ion-plated orthodontic appliance were investigated. The obtained results were as follows: 1) TiN ion-plated film had the colorimetric properties which were the hue of about 2.5 Y, the brightness of about 6, and the chroma of about 4 by the standard color chip of JIS. 2) TiN ion-plated film was $2{\mu}m$ in thickness and its deposition pattern was rather irregular. 3) TiN phase was confirmed on the X-ray diffraction pattern. 4) Critical load for delamination of ion-plated film from stainless steel band was 10N. 5) Tensile and yield strength of ion-plated specimen was increased about 10Kg $f/mm^2$, while elongation was decreased $1\%$ compairing to the values of the non ion-plated specimen.

• Bulletin of the Korean Chemical Society
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• 제33권12호
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• pp.4280-4280
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• 2012

• 한국펄프종이공학회:학술대회논문집
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• 한국펄프종이공학회 1999년도 Pre-symposium of the 10th ISWPC Recent Advances in Paper Science and Technology
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• pp.309-314
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• 1999

With a view to seek the influence of hollow sphere pigments of latex upon the printed color on coated paper surface, the hollow sphere pigments were compared with filled ones in a variety of experimental approaches. Colloidal properties of latices were determined by measuring zeta potential and particle size distribution. For the amphoteric filled sphere pigment of latex, the polarity was reversed from the negative side to the positive side with decreasing pH. An extraordinarily high peak in the particle size distribution of the amphoteric filled evidenced aggregation between latex particles near the isoelectric point, depending on the electrolyte concentration and pH of the suspending medium. Coated papers containing the hollow sphere pigment in their coating improved optical properties like gloss and brightness. Optical parameters solely of the coating could account for this finding. An equation derived from the Kubelka-Munk equation calculated them fro twice measurements of reflectance of a coated paper over two substrates of different reflectances. This method permitted to predict brightness of coated paper of which coat weight would be different fro the actual one. The colorimetric parameters of solid-printed surfaces of the coated papers closely related to optical and structural properties of the coated papers. The color of the printed surfaces was dominated by the brightness and the smoothness of the coated papers. The hollow sphere pigments were proved to improve optical properties of coated paper and to control minutely colorimetric parameters of printed surfaces.

• Bulletin of the Korean Chemical Society
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• 제33권11호
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• pp.3696-3700
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• 2012

The colorimetric and fluorescent cyanide recognition properties of 2-[(9-ethyl-9H-carbazol-3-yl)methylene]-propanedinitrile (1) in $CH_3CN-H_2O$ (2/1, v/v, HEPES 10 mM, pH = 7.0) solution were evaluated. The optical recognition process of probe 1 exhibited high sensitivity and selectivity to cyanide ion with the detection limit of $2.04{\times}10^{-6}$ M and barely interfered by other coexisting anions. The sensing mechanism of probe 1 is speculated to undergo a nucleophilic addition of cyanide to dicyanovinyl group present in compound 1. The colorimetric and fluorescent dual-modal response to cyanide makes probe 1 has a potential utility in cyanide detection.

• Bulletin of the Korean Chemical Society
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• 제21권4호
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• pp.389-392
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• 2000

A simple and inexpensive colorimetric spectrometer for determining total cholesterol has been developed,comprising a diode laser as the light sourcoptical fibers for the light guide and a photodiode as the detector.The stabilty and performance of the new system was investigated by obtaining the calibration curve for stan-dard cholesterol solutions. The total cholesterol in humanserum was also measured by the analyzer and com-pared with the value obtained by a conventional spectrometer. The results showed that the developed spectrometer was useful for the determination of cholesterol levels. The visible diodelaser used in the study exhibited good spectroscopic and operational properties for colorimetric absorption spectrometry and could be a key component for the development of a simple and economical analyzer.

• Bulletin of the Korean Chemical Society
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• 제32권9호
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• pp.3433-3436
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• 2011

Some of metal nanoparticles have the potential for use as colorimetric assays for estimating solution properties, such as pH and temperature due to localized surface plasmon (LSP) phenomena. This report describes the use of silver nanoparticles (AgNP) conjugated with cytochrome c (Cyt c) for the colorimetric determination of solution pHs. When the pH of a solution decreases, the Cyt c immobilized on the AgNP undergoes a conformational change, leading to a decrease in the interparticle distance between Cyt c-AgNP probes and consequent red-shift in LSP. As a result, the color of the Cyt c-AgNP probe solution changes from yellow to red and finally to a grayish blue in the pH range from 11 to 3. This gradual color change can be used to determine the pH of a solution over a wide pH range, compared to other colorimetric methods that use gold nanoparticles.