• Fibers and Polymers
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• 제5권3호
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• pp.219-224
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• 2004

The reactive printing properties of regular viscose rayon and a new regenerated cellulosic fiber (en Vix^{\textregistered}$) which was prepared from cellulose acetate fiber was investigated in a comparative manner. From the results, it was found that en Vix exhibited better printing properties than regular viscose rayon. It showed stable final color yields, irrespective of the amount of thickener, hence reproducibility of printing of en Vix is expected to be excellent. In addition, urea requirements were less for the printings on en Vix than for the corresponding printing on viscose rayon. Therefore, en Vix is also expected to reduce the amount of the urea which causes environmental problems in dyehouse effluent.

• 대한화학회지
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• 제18권6호
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• pp.415-420
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• 1974

特別한 裝置나 複雜한 操作없이 簡單하고 迅速한 brucine 法에 依한 窒酸이온의 吸光光度 定量法을 定하였다. 檢液을 brucine 試液과 30N 黃酸으로 $60^{\circ}C$<\tex>에서 30分間 反應시키면 安定하고 再現性이 좋은 發色을 얻을 수 있으며, 410nm에서 窒酸性窒素의 濃度가 0.07ppm부터 0.6ppm까지 吸光度와 直線的 關係가 있다. 또 反應系에서 吸光綜의 數는 단 하나임을 確認하였다. 妨害이온들중 亞窒酸이온은 메탄올로서 除去할 수 있다.

• 한국염색가공학회지
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• 제9권5호
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• pp.19-29
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• 1997

A natural colorant was extracted from Clove using methanol. The dyeabilities and fastness of silk fabrics dyed with Clove extract were investigated. The results obtained were as follows; 1. The colorant extracted with methanol was higher in concentration than that with boiling water and was represented high reproducibility. 2. The optimum dyeing temperature and dyeing time were 6$0^{\circ}C$ and 60min, respectively. 3. The color depths were observed to be decreased as follows; pre-mordant > after-mordant repeat dyeing > after-mordant > simultaneous-mordant 4. Clove extract dyed brownish black on the Fe-mordanted silk. In case of the other mordants, silk fabrics dyed yellow. 5. The dyed silks had poor light-fastness but good wet-fastness.

• Journal of Microbiology and Biotechnology
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• 제18권9호
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• pp.1550-1554
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• 2008

A hydrogen sulfide $(H_2S)$ detecting tube was developed for the quantitative determination of $H_2S$ produced by yeast during laboratory scale wine fermentations. The detecting tube consisted of a small transparent plastic tube packed with an $H_2S$-sensitive color-indicating medium. The packed medium changed color, with the color change progressing upward from the bottom of the tube, upon exposure to $H_2S$ produced by yeast during fermentation. A calibration study using a standard $H_2S$ gas showed that the length of the portion that darkened was directly related to the quantity of $H_2S$ (${\mu}g$) with a high correlation coefficient ($r^2$=0.9997). The reproducibility of the $H_2S$ detecting tubes was determined with five repetitive measurements using a standard $H_2S$ solution [5.6${\mu}g$/200 ml (28 ppb)], which resulted in a coefficient of variation of 3.6% at this level of $H_2S$. With the sulfide detecting tubes, the production of $H_2S$ was continuously monitored and quantified from laboratory scale wine fermentations with different yeast strains and with the addition of different levels of elemental sulfur to the grape juice. This sulfide detecting tube technology may allow winemakers to quantitatively measure $H_2S$ produced under different fermentation conditions, which will eventually lead winemakers to better understand the specific factors and conditions for the excessive production of $H_2S$ during wine fermentation in a large production scale.

• 생약학회지
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• 제1권3호
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• pp.93-99
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• 1970

There have been reported by several workers for the isolation and determination of the amine derivatives as Metbylephedrine Hydrochloride and Ephedrine Hydrochloride adopting neutralization method, steam distillation method, non-aqous titration method, ion-exchange resin method, titration method after acetylation, colorimetric method, gravimetric method, iodine titration method and gas chromatography. Those methods mentioned in above, can be practically applied for the sample which is not mixed one mith the other amine compounds. Presently, it has not shown on the isolative determination of the mixed sample of amine derivatives. In this paper, it is discussed on the isolative determination of Methylephedrine Hydrochloride as the tertiary amine compound and Ephedrine Hydrochloride as the secondary amine compound. According to the results of the experiment, it could be summarized as follows: 1. There is no time-variation on the color reaction of Methylephedrine Hydrochloride and Ephedrine Hydrochloride with the color reagent, bromcresolgreen. And Methylephedrine Hydrochloride and Ephedrine Hydrochloride, respectively, can be determined spectrophotometrically by means oft his color reaction. 2. For the isolation of Methylephedrine Hydrochloride and Ephedrine Hydrochloride from the mixed sample, Methylephedrine Hydrochloride can be eluted by chloroform, while Ephedrine Hydrochloride by the mixed solvent of chloroform and ethylalcohol (2:1), from the celite column adsorbed at pH6.4 followed by extraction with ether undersodium hydroxide alkali re action. 3. When the sample is mixed with quinine hydrochloride, dihydrocodeine bitartate, and noscapine, these mixed compounds can be eliminated by means of stram distillation. 4. When the sample is mixed with chlorpheniramine maleate, dextromethorphan hydrobromide and diphenhydramine hydrochloride, the mixed compounds can be eliminated by means of steam distillation and celite adsorption column chromatography, In conclusion, the isolative determination method for Methylephedrine Hydrochloride and Ephedrine Hydrochloride studied in this paper, indicates with the excellent reproducibility and accuracy.

• 보존과학회지
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• 제25권4호
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• pp.431-438
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• 2009

풍납토성에서 출토된 한성백제시대 토기를 중심으로 다양한 경도측정 방법을 적용하여 토기의 굳기에 따른 적절한 측정방법 및 조건을 연구하였다. 연구를 위한 토기시료는 육안관찰과 모스경도계를 이용하여 굳기의 서열별로 선정하였으며, 표면 경도측정에는 초음파 및 에코팁 경도측정법을 적용하였고, 단면에는 로크웰 표충경도(로크웰 슈퍼피셜)와 마이크로비커스 경도측정법을 적용하였다. 그 결과, 표면 경도에서는 두 방법 모두 정밀한 측정에 많은 어려움이 있었으며 육안 및 모스경도에 따른 분류와 일치하는 경향성을 관찰할 수 없었다. 단면 경도측정 결과에서는, 로크웰 표충경도 측정법의 경우, 연질 토기의 측정에 보다 유리한 것으로 나타났으며, 1/16" 강구 압입자를 사용하여 15kgf의 시험하중으로 측정할 경우 가장 재현성이 좋은 측정값을 얻을 수 있음을 확인하였다. 반면, 마이크로비커스 측정법의 경우, 경질 토기의 측정에 보다 유리한 특성을 보였으며, 시험하중 100gf에서 가장 재현성과 정밀도가 높은 측정값을 얻을 수 있었다. 또한, 로크웰 표충경도법과 마이크로비커스 측정법은 모두 그 측정값이 고고학적 견해에 따른 육안분류와 거의 일치하는 경향성을 나타내었다. 이러한 결과는 향후 토기에 대한 고고학적 견해의 객관성을 뒷받침할 수 있는 매우 유용한 도구로써 기계적 경도측정값이 이용될 수 있음을 보여주는 것으로, 향후 이를 이용한 활발한 연구가 가능해 질 것으로 판단된다.

• 대한치과보철학회지
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• 제43권5호
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• pp.587-598
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• 2005

Statement of problem: Ceramic restorations should be made of porcelain layers of different opacity, shade, and thickness in order to provide a natural appearance. Lithium disilicate glass-ceramic system has superior color reproducibility, because it uses the ceramic ingot which is similar to teeth shade and uses the staining technique and layering technique. However, staining technique has a fault of discoloration. Also, porcelain is divided core and dentin layer, it is not enough to study about the influence of porcelain layer thickness and shade on the shade of ceramic restorations. Purpose: The purpose of this study was to evaluate the influence of porcelain layer thickness and color on the final shade of ceramic restorations. Materials and method: The CIE $L^*a^*b^*$(CIELAB) values of 72 assembled specimens, each consisting of 3 discs (enamel porcelain 0.2 mm/dentin porcelain -1.2, 0.9, 0.7, 0.5 or 0.3 mm/ceramic core -0.3, 0.5, 0.7, 0.9 or 1.2 mm, diameter is 1.0 mm) were evaluated with a spectrophotometer (Model Chromaview 300, Spectron Tech Co, Korea) for the shade A1, A2, A3 and A4. Distilled water (refractive index: 1.7) was used to attain optical contact between the layers. White, white gray, and white brown backgrounds were used to assess the influence of the background on the final shade. And the mean color difference value$({\Delta}E)$ was calculated. Results and conclusion: The results obtained from this study were as follows. 1. There was a significant correlation between the thickness ratio of the ceramic core/dentin porcelain system and $L^*,\;a^*\;and\;b^*$ values when the total thickness of specimen combination was smaller than 1.4 mm(P<0.05). 2. The specimen which the ceramic core thickness was more than 0.7 mm had the best masking effect against background colors. 3. The mean color difference value$({\Delta}E)$ is smaller than 2 $({\Delta}E<2)$ when the ceramic core thickness was larger than 0.7 mm and the total thickness of specimen was more than 1.4 mm.

• 펄프종이기술
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• 제37권1호
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• pp.73-81
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• 2005

Stockigt sizing test, which is readily affected by individual tester's bias as well as testing conditions in recognizing red coloration, had to be modified to improve its reliability and reproducibility. The novel testing system with the automatic recognizing program of red coloration was developed with the auxiliary equipments including an automatic liquid dispenser and a specimen shifter. The analysis program used a hue value of a droplet image in recognizing a point of time on red coloration instead of RGB values that are not similar to human perception of color. Hue was more sensitive in recognizing the red coloration of a droplet than the other two factors, Saturation and Value. During the test, the program records the time consumed up to a specific hue value of a droplet on a specimen. Differently from the conventional test, the automatic test could obtain a reliable and reproducible sizing degree with a minor error. Furthermore, the Stockigt sizing degree measured by the automatic system showed great correlations with contact angle and Hercules sizing degree. It means that such great correlations will contribute to the development of an integrated measuring system capable of predicting contact angle, surface tension, surface energy and Hercules sizing degree of paper and paperboards through the Stbckigt sizing test. It was meaningful to note that the automatic system for Stbckigt sizing test might be able to used to predict contact angle, Hercules and Cobb sizing degree, based upon the high correlation coefficients.

• 분석과학
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• 제34권3호
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• pp.128-133
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• 2021

적정 화학반응에는 화학종의 전위차 변화뿐만 아니라 지시약의 색깔 변화도 포함된다. 전위차 적정에서는 종말점에서 전위의 급격한 변화를 측정하여 적정 곡선을 얻는다. 산-염기 적정은 일반적으로 지시약의 색 변화를 관찰하여 종말점을 결정함으로써 수행된다. 전위차를 측정하여 종말점을 결정하는 방법은 잘 확립 되어 상용화되어 있지만 색의 변화를 관찰하여 종말점을 얻는 장치는 많지 않은 실정이다. 적외선 광원과 감지기로 적정액 방울을 계수하고, 백색광원과 광 검출기로 종말점의 변색을 감지하여 아날로그-디지털 변환기인 아두이노 (Arduino)가 적용된 간단하고 정밀한 스펙트럼 종말점 검출 기구를 제작하였다. Spectrator는 지시약으로 티몰 블루를 사용한 산-염기 적정에서 재현성 측면에서 우수한 결과를 보였다. Spectrator 제작 과정과 이를 사용한 실험결과를 공유한다.

• 한국미생물·생명공학회지
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• 제19권4호
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• pp.372-379
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• 1991

E.coli ATCC 21990의 aminoglycoside-3'-phosphotransferase(APH(3'))의 신속하고 간편한 정량적 방법을 TLC densitometry를 이용하여 확립하였다. APH(3') 반응생산물인 3' 위치에 인산화된 kanamycin B(3'PKMB)는 silica gel plate에서 cnloroform-methanol-method-ammonia water (3:4:3) 전개용매로 반응물에서 분리되었고, 3'PKMB의 양은 ninhydrin으로 발색 후 densitometry로 측정하였다. APH(3')의 densitometric TLC assay는 좋은 정량적 결과와 재현성을 보였고, 3'-PKMB에 대한 감도는 1.56nmol이었으며 많은 시료의 분석이 한번의 실시로 가능하였다. 이 방법은 aminoglycoside 항생제의 불활화 효소 분석에 응용이 가능하리라 여겨진다.