• Progress in Superconductivity and Cryogenics
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• v.21 no.1
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• pp.40-44
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• 2019

This study investigates mixtures of water and cryoprotectant agents (CPAs) to store high-grade cold energy. Although water is an ideal material for a cold thermal storage (CTS) due to its high specific heat, undesirable volume expansion may cause structural stresses during freezing. The volume expansion can be alleviated by adding the CPAs to water. However, the CPA aqueous solutions not only have different thermal properties but also transit to amorphous state different from pure water. Therefore, these characteristics should be considered when using them as material of the CTS. In experiments, glycerol and dimethyl sulfoxide (DMSO) are selected as the candidate CPA. The volume expansion of the solution is measured by an in-situ strain gauge in low temperature region. The specific heat capacity of the solution is also measured by differential scanning calorimetry (DSC). Both the amount of volume expansion and the specific heat capacity of the CPA aqueous solution decrease in the case of higher concentration of CPA. These characteristics should be contemplated to select optimal aqueous solution for CTS for liquid air energy storage system (LAES). The CPA solutions have advantages of having wide temperature range to utilize the latent heat of water and higher sensible heat of the CPA. The CPA solutions which can satisfy the allowable stress of the structure are determined. Consequently, among the CPA solutions investigated, DMSO 20% w/w solution is the most suitable for the CTS.

• Progress in Superconductivity and Cryogenics
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• v.26 no.1
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• pp.20-24
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• 2024

Over the past four years, as the COVID-19 pandemic has struck the world, cold chain of COVID-19 vaccination has become a hot topic. In order to overcome the pandemic situation, it is necessary to establish a cold chain that maintains a low-temperature environment below approximately 203K (-70℃), which is the appropriate storage temperature for vaccines, from vaccine suppliers to local hospitals. Usually, cryocoolers are used to maintain low temperatures, but it is difficult for small-scale local distribution to have cryocooler due to budget and power supply issues. Accordingly, in this paper, a cryogenic TSU (Thermal storage unit) system for vaccination cold chain is designed that can maintain low temperatures below -70℃C for a long time without using a cryocooler. The performance of the TSU system according to the energy storage material for using as TSU is experimentally evaluated. In the experiments, four types of cold storage materials were used: 20% DMSO aqueous solution, 30% DMSO aqueous solution, paraffin wax, and tofu. Prior to the experiment, the specific heat of the cold storage materials at low temperature were measured. Through this, the thermal diffusivity of the materials was calculated, and paraffin wax had the lowest value. As a result of the TSU system's low-temperature maintenance test, paraffin wax showed the best low-temperature maintenance performance. And it recorded a low-temperature maintenance time that was about 24% longer than other materials. As a result of analyzing the temperature trend by location within the TSU system, it was observed that heat intrusion from the outside was not well transmitted to the low temperature area due to the low thermal conductivity of paraffin wax. Therefore, in the TSU system for vaccine storage, it was experimentally verified that the lower the thermal diffusivity of the cold storage material, the better low temperature maintenance performance.

• Journal of Institute of Convergence Technology
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• v.2 no.1
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• pp.1-6
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• 2012

The cold chain system in South-East Asia is requiring to maintain freshness of refrigerated or frozen food. In this study, Thermal storage system using Phase change material (PCM) was developed and evaluated its performance about temperature and cold keeping time. For various application of cold chain system, we developed portable cold box, cold roll container and freezing station. Keeping time on laboratory tests of portable cold box in case of refrigeration and freezing were 6 hours and 4 hours, respectively. Cold container was developed to 2.5 ton scale. Evaluation in Indonesia, it was showed to keep the setting temperature of $-10^{\circ}C$ over 40 hours at $30^{\circ}C$ of ambient air. Freezing station using PCM was kept over 24 hours under $-20^{\circ}C$.

• Journal of Soil and Groundwater Environment
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• v.22 no.4
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• pp.9-26
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• 2017

When a warm well located downgradient is captured by cold thermal plume originated from an upgradient cold well, the warm thermal plume is pushed further downgradient in the direction of groundwater flow. If groundwater flow direction is parallel to an aquifer thermal energy storage (ATES), the warm well can no longer be utilized as a heat source during the winter season because of the reduced heat capacity of the warm groundwater. It has been found that when the specific discharge is increased by $1{\times}10^{-7}m/s$ in this situation, the performance of ATES is decreased by approximately 2.9% in the warm thermal plume, and approximately 6.5% in the cold thermal plume. An increase of the specific discharge in a permeable hydrogeothermal system with a relatively large hydraulic gradient creates serious thermal interferences between warm and cold thermal plumes. Therefore, an area comprising a permeable aquifer system with large hydraulic gradient should not be used for ATES site. In case of ATES located perpendicular to groundwater flow, when the specific discharge is increased by $1{\times}10^{-7}m/s$ in the warm thermal plume, the performance of ATES is decreased by about 2.5%. This is 13.8% less reduced performance than the parallel case, indicating that an increase of groundwater flow tends to decrease the thermal interference between cold and warm wells. The system performance of ATES that is perpendicular to groundwater flow is much better than that of parallel ATES.

• Journal of the Korean Solar Energy Society
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• v.21 no.1
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• pp.71-82
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• 2001

The heat transfer experiment in a latent heat storage tank as a solar energy storage system for the hot water supply was carried out. The latent heat storage tank was consisted of triple - tube type ; Outer shell for hot water from solar collector, PCM storage vessel in the middle of the tank and inside tube for hot water recovery. The heat storage tank has the dimension of 60 cm long and 34 cm outside diameter. Paraffin wax(m.p = 55.4C) and sodium acetate trihydrate(m.p = 58 C) were employed as the PCM this study. Experimental variables were inlet temperature and flow rate of the hot water for heat storage stage and cold water for heat recovery stage. Temperature profiles, heat transfer coefficient and the efficiency of heat storage$(Q/Q_{max})$ and heat recovery $(Q/Q_{max})$ were determined for the paraffin wax and inorganic salt respectively.

• Journal of the Korean Solar Energy Society
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• v.21 no.1
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• pp.83-91
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• 2001

The heat transfer experiment in a pilot scale latent heat storage tank as a solar energy storage system for the hot water supply was carried out. The latent heat storage tank was consisted of three parts; Outer shell for hot water from solar collector, PCM storage vessel in the middle of the tank and immersed coil in the PCM vessel for hot water recovery. The heat storage tank has the dimension of 115 cm in height and 32 cm outside diameter. Paraffin wax (m.p = 55.4C) and sodium acetate trihydrate (m.p = 58 C) were employed as the PCM this study. Experimental variables were inlet temperature and flow rate of the hot water for heat storage stage and cold water for heat recovery stage. Temperature profiles, heat transfer coefficient and the efficiency of heat storage $(Q/Q_{max})$ and heat recovery $(Q/Q_{max})$ were determined for the paraffin wax and inorganic salt respectively.

• Journal of Advanced Marine Engineering and Technology
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• v.28 no.4
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• pp.618-623
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• 2004

This paper has dealt with the heat storage characteristics of gel type micro size latent heat storage material slurry. The heat release operation to the gel type micro size latent heat storage material slurry was carried out using hot air bubbles by direct contact heat exchange. This experiment was carried out using phase change material of n-paraffin so the heat release amount is higher than cold water system. The parameters of this experiment were concentration of latent heat phase change material, height of heat release bath and inlet velocity of hot air. The main results obtained are as follows : (1) The effect of concentration of latent heat phase change material dispersed with water is very affective to the direct contact heat exchange between hot air and gel type micro size latent heat storage material slurry. (2) It is clarified that the most effective concentration of latent heat phase change material dispersed with water exists around 20mass% at this type of direct heat exchange model experiment.

• Proceedings of the SAREK Conference
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• 2007.11a
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• pp.447-452
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• 2007

Greenhouses should be heated during nights and cold days in order to fit growth conditions in greenhouses. Ground source heat pump(GSHP) or geothermal heat pump system(GHPs) is recognized to be outstanding heating and cooling system. Horizontal GSHP system is typically less expensive than vertical GSHP system but requires wide ground area to bury ground heat exchanger(GHE). In this study, a horizontal GSHP system with thermal storage tank was installed in greenhouse and investigated as performance characteristics. In the daytime, heating load of greenhouse is very small or needless because solar radiation increases inner air temperature. The results of study showed that the heating coefficient of performance of the heat pump ($COP_h$) was 2.9 and the overall heating coefficient of performance of the system($COP_{sys}$) was 2.4. Heating energy cost was saved 76% using the horizontal GSHP system with thermal storage tank.

• Proceedings of the SAREK Conference
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• 2006.06a
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• pp.1125-1130
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• 2006

An air source heat pump system producing the ice and water storage energy for cooling and heating of building has been proposed. Cycle design and simulation considering energy balance between heating and cooling capacity has been carried out. The roles of the capacity controlled compressor, refrigerant heating device and air preheating are investigated in detail. System control logic for meeting the predetermined heating capacity when the system is operated at cold climate condition is suggested. Some anticipated problems of the proposed system are also described.

• Journal of The Korean Society of Agricultural Engineers
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• v.59 no.6
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• pp.127-135
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• 2017

In this study, a cold well and a warm one with the distance of 100 m were installed in the alluvial aquifer. Groundwater used as the heat and the cold source of heat pump was designed to flow into the warm and the cold well with a diameter of 200 mm. In order to increase the heat and cold storage in aquifer, six auxiliary wells with the diameter of 50 mm and the depth of 30 m were installed at an interval of 5 m from the main well. Also, heat pump 50 RT, the thermal tank $40m^3$, and a remote control and monitoring system were installed in three single-span greenhouses ($2,100m^2$) for growing tomato in Buyeo, Chungcheongnam-do. According to the aquifer heat storage test which had been conducted from Aug. 31 to Sep. 22, 2016, warm water of $850m^3$ was found to flow into warm well. The temperature of the injected water was $30^{\circ}C$ (intake temperature : $15^{\circ}C$), and the heat of 12.8 Gcal was stored. The greenhouse heating test in winter had been conducted from Nov. 21, 2016 to Apr. 30, 2017. On Nov. 21, 2016 when heating greenhouse started, the aquifer temperature of the warm well was $18.5^{\circ}C$. The COP for heating with water source at $18.5^{\circ}C$ was 3.8. The intake water temperature of warm well was gradually lowered to the temperature of $15^{\circ}C$ on Jan. 2, 2017 and the heat pump COP was measured to be 3.2 at that time. As a result, the heat pump COP was improved by 18 %. and retrieval heat was 8 Gcal, the retrieval rate of heat stored in aquifer was estimated at 63 %.