• Title/Summary/Keyword: Cold Temperature

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Optimizing Graphene Growth on the Electrolytic Copper Foils by Controlling Surface Condition and Annealing Procedure (전해구리막의 표면 조건과 어닐링 과정을 통한 그래핀 성장 최적화)

  • Woo Jin Lee;Ha Eun Go;Tae Rim Koo;Jae Sung Lee;Joon Woo Lee;Soun Gi Hong;Sang-Ho Kim
    • Journal of the Korean institute of surface engineering
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    • v.56 no.3
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    • pp.192-200
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    • 2023
  • Graphene, a two-dimensional material, has shown great potential in a variety of applications including microelectronics, optoelectronics, and graphene-based batteries due to its excellent electronic conductivity. However, the production of large-area, high-quality graphene remains a challenge. In this study, we investigated graphene growth on electrolytic copper foil using thermochemical vapor deposition (TCVD) to achieve a similar level of quality to the cold-rolled copper substrate at a lower cost. The combined effects of pre-annealing time, graphenized temperature, and partial pressure of hydrogen on graphene coverage and domain size were analyzed and correlated with the roughness and crystallographic texture of the copper substrate. Our results show that controlling the crystallographic texture of copper substrates through annealing is an effective way to improve graphene growth properties, which will potentially lead to more efficient and cost-effective graphene production. At a hydrogen partial pressure that is disadvantageous in graphene growth, electrolytic copper had an average size of 8.039 ㎛2, whereas rolled copper had a size of 19.092 ㎛2, which was a large difference of 42.1% compared to rolled copper. However, at the proper hydrogen partial pressure, electrolytic copper had an average size of 30.279 ㎛2 and rolled copper had a size of 32.378 ㎛2, showing a much smaller difference of 93.5% than before. This observation suggests this potentially leads the way for more efficient and cost-effective graphene production.

A Study on Increased Properties of Cellulose-Based Biodegradable Polymer Composites (셀룰로오스 기반 생분해성 고분자 복합재의 물성 증가에 관한 연구)

  • Sangjun Hong;Ajeong Lee;Sanghyeon Ju;Youngeun Shin;Teahoon Park
    • Composites Research
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    • v.36 no.2
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    • pp.126-131
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    • 2023
  • Growing environmental concerns regarding pollution caused by conventional plastics have increased interest in biodegradable polymers as alternative materials. The purpose of this study is to develop a 100% biodegradable nanocomposite material by introducing organic nucleating agents into the biodegradable and thermoplastic resin, poly(lactic acid), to improve its properties. Accordingly, cellulose nanofibers, an eco-friendly material, were adopted as a substitute for inorganic nucleating agents. To achieve a uniform dispersion of cellulose nanofibers (CNFs) within PLA, the aqueous solution of nanofibers was lyophilized to maintain their fibrous shape. Then, they were subjected to primary mixing using a twin-screw extruder. Test specimens with double mixing were then produced by injection molding. Differential scanning calorimetry was employed to confirm the reinforced physical properties, and it was found that the addition of 1 wt% CNFs acted as a reinforcing material and nucleating agent, reducing the cold crystallization temperature by approximately 14℃ and increasing the degree of crystallization. This study provides an environmentally friendly alternative for developing plastic materials with enhanced properties, which can contribute to a sustainable future without consuming inorganic nucleating agents. It serves as a basis for developing 100% biodegradable green nanocomposites.

The Characteristics of Traditional Irrigation Farming System of Uiseong-gun (의성 전통수리 농업시스템의 특징)

  • Lee, Yoo-Jick;Lee, Seung-Hye;Lee, Da-Young;Jeong, Jae-Hyeon;Park, Jin-Wook;Gu, Jin Hyuk
    • Journal of Korean Society of Rural Planning
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    • v.29 no.1
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    • pp.69-79
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    • 2023
  • Uiseong-gun, Gyeongsangbuk-do, one of the representative small rain regions, has developed a traditional irrigation farming system while overcoming and adapting to unfavorable agricultural environments from the days of the ancient nation of Jomunguk to the present. In 2018, its value was recognized and designated as Nationally Important Agricultural Heritage System No. 10. This study was conducted with the purpose of examining the characteristics of the traditional irrigation farming system in Uiseong from the viewpoints of irrigation facilities, irrigation communities, and agricultural activities. The research results are as follows. Uiseong-gun has been expanding irrigation facilities for agriculture since long ago, and it has been investigated that a total of 6,227 irrigation facilities are currently distributed along the Wicheon water system that crosses Uiseong-gun from east to west. Irrigation facilities appear differently depending on the topography. The irrigation facility has a 'su-tong' as an irrigation passage and a corkscrew structure 'mot-tchong' as a water quantity control device, so the amount of water was adjusted as needed. Through this facility, surface water with warmer temperature is supplied to the farmland to prevent cold damage to crops. Uiseong has developed activities to organize irrigation communities in one village or several villages to secure agricultural water from an early age. Currently, this tradition continues, and a total of 213 irrigation communities manage 375 irrigation facilities (6.0% of all irrigation facilities). Through this organization, called Mong-ri-gye, water for agriculture is obtained, managed, and distributed equitably. In order to increase agricultural production, Uiseong implemented double cropping by converting rice fields and fields. In the case of Mt. Geumseong, double cropping of rice and barley was mainly carried out until the 1970s, but since the 1980s, double cropping of rice and garlic has been implemented with higher income. One of the unique features of the agricultural system of this region is the spectacular landscape that changes simultaneously from field to rice field in spring and from rice field to field in autumn.

Ex situ Conservation of the Cypripedium gutttum SW. Seedlings from Asymbiotically Germination and Adaption on High Land in Korea (멸종위기 털복주머니란 현지 외 보전 및 고랭지 적응성 검토)

  • Joung Kwan Lee;Young Hee Kwon;Yoon Sun Huh;Hee Kyu Kim;Kyung Ok Kim;Won Il Choi;Ju Hyoung Kim;Mi Jin Jeong;Sung Won Son
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2020.08a
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    • pp.11-11
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    • 2020
  • Background : The genus Cypripediums are typically adapted to the low temperature and cold climates of the high land in Korea. The species which were reported in Korean peninsula are C.japonicum, C.macranthos, C.calceolus and C.guttatum. We had already reported the successful germination of the C.macranthos and C.guttatum. The small spotted lady's slipper orchid(C.guttatum) is most endangered plants to extinction of which population was reported less than 100 in Korea. The objective of the present research is restoration of the C.guttatum in ex situ and adaptation in high land and nursery. Methods and Results : The 350 seedlings of C.guttatum were transplanted in soil at alpine area(altitude 750m) and the nursery of Korea National Arboretum(KNA) in YangPyeong city on May 2019 and 2020 in order to verify the possibility of ex situ restoration. The sprouted ratio of the seedlings were less than 10% in the alpine area and 83% in the nursery of KNA. The reasons of the diverse survival ratio are presumed as the low moisture content in the soil and heavy shade of the alpine area. The 15 cypripedium species and 29 hybrids were also effectively adapted in the KNA rare plant garden. Conclusion : These results demonstrated the difficulties of the restoration for small spotted lady's slipper orchid in the natural habitation. From the above results, we may conclude that the critical factors of the genus Cypripedium are intensive care for the fragile seedlings during the 1st year acclimatization.

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Measurement and analysis of tractor emission during plow tillage operation

  • Jun-Ho Lee;Hyeon-Ho Jeon;Seung-Min Baek;Seung-Yun Baek;Wan-Soo Kim;Yong-Joo Kim;Ryu-Gap Lim
    • Korean Journal of Agricultural Science
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    • v.50 no.3
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    • pp.383-394
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    • 2023
  • In Korea, the U.S. Tier-4 Final emission standards have been applied to agricultural machinery since 2015. This study was conducted to analyze the emission characteristics of agricultural tractors during plow tillage operations using PEMS (portable emissions measurement systems). The tractor working speed was set as M2 (5.95 km/h) and M3 (7.60 km/h), which was the most used gear stage during plow tillage operation. An engine idling test was conducted before the plow tillage operation was conducted because the level of emissions differed depending on the temperature of the engine (cold and hot states). The estimated level of emissions for the regular area (660 m2), which was the typical area of cultivation, was based on an implement width of 2.15 m and distance from the work area of 2.2 m. As a result, average emission of CO (carbon monoxide), THC (total hydrocarbons), NOx (nitric oxides), and PM (particulate matter) were approximately 6.17×10-2, 3.36×10-4, 2.01×10-4, and 6.85×10-6 g/s, respectively. Based on the regular area, the total emission of CO, THC, NOx, and PM was 2.62, 3.76×10-2, 1.63, and 2.59×10-4 g, respectively. The results of total emission during plow tillage were compared to Tier 4 emission regulation limits. Tier 4 emission regulation limits means maximum value of the emission per consumption power (g/kWh), calculated as ratio of the emission and consumption power. Therefore, the total emission was converted to the emission per power using the rated power of the tractor. The emission per power was found to be satisfied below Tier 4 emission regulation limits for each emission gas. It is necessary to measure data by applying various test modes in the future and utilize them to calculate emission because the emission depends on various variables such as measurement environment and test mode.

Research on the Operation of Safeguards Equipment in Extreme Environmental Conditions (극한 환경 내 안전조치 장비 운영에 관한 연구)

  • Jiyoung Han;Suhui Park;Jewan Park;Yongmin Kim
    • Journal of the Korean Society of Radiology
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    • v.17 no.7
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    • pp.1189-1195
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    • 2023
  • In scenarios involving inspections and verifications of nuclear facilities, ensuring the proper functioning of on-site safeguards equipment is crucial. There have been precedents in Kazakhstan where equipment failed to operate properly due to extremly cold temperatures, and the year-round minimum temperature at North Korea's Punggye-ri nuclear test site is approximately minus 30 degrees Celsius. To ensure the proper functioning of equipment in extreme environments for on-site verification of nuclear activities on the Korean Peninsula, relevant research is necessary. This includes confirming the functionality of equipment used in inspections and verifications, as well as analyzing factors that may disrupt their normal operation. This study aims to conduct a risk analysis for the normal operation of equipment in extreme environments and develop criteria and procedures for environmental-based performance testing. To achieve this, we conducted a risk analysis based on IAEA safeguards, analyzed the utilization of equipment, and performed a risk analysis associated with transportation for on-site verification considering the environmental characteristics of the Korean Peninsula. Furthermore, we provided performance testing criteria and procedures. The research results can be utilized as reference material in the verification and monitoring processes of nuclear activities.

Synthesis and Properties of Coating Agents for Automobile Parts Using Water-born Polyurethane, Polysiloxane, and UHMWPP Powder (수분산 폴리우레탄, 폴리실록산, UHMWPP 분말을 이용하여 제조한 자동차 부품용 코팅제 합성 및 물성 연구)

  • Yong-Sung Kim;Sung-Jin Park;Young-hwan Kim;Hyejin Kim;Choong-Sun Lim;Bong-kuk Seo
    • Journal of Adhesion and Interface
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    • v.24 no.4
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    • pp.124-130
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    • 2023
  • For automotive coating agents that require little change in characteristics due to changes in external temperature, changes in noise characteristics due to changes in the external environment are very important. Therefore, soft polyurethane with excellent cold resistance, weather resistance, and abrasion resistance, and polysiloxane whose -OH terminated and side chains are modified with amines, are widely used. In this study, coating agents was prepared by adding water-born polyurethane, polysiloxane, ultra high molecular weight polypropylene (UHMWPP) powder, carbon black, and a matting agent to determine the effect of each resin component on noise. To study the effect of each resin component on noise, a coating agent was prepared by adding water-born polyurethane, polysiloxane, UHMWPP powder, carbon black, and a matting agent. The hard/soft segment ratio of water-born polyurethane, the main component of the coating, was 27.1%/72.9%, and the ratio of amino siloxanes to hydroxy-terminated polysiloxane was 2:7, which produced the least noise. The difference in friction coefficient was large when the friction body moves at high speed. When UHMWPP powder replaced SiO2, noise decreased and gloss also decreased.

Oceanographic Features Around Aquaculture Areas of the Eastern Coast of Korea (동해안 연안양식장 주변해역의 해양학적 특성)

  • Jeong, Hee-Dong;Kim, Sang-Woo;Kwon, Kee-Young;Lim, Jin-Wook;Kwoun, Chul-Hui
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.19 no.4
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    • pp.334-344
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    • 2013
  • In order to understand the characteristics of oceanic environment in the coastal aquaculture waters of the East Sea, the observation of the CTD (temperature and salinity), dissolved oxygen, chlorophyll a and N/P (DIN ($NO_2$-N, $NO_3$-N, $NH_4$-N) : DIP($PO_4$-P)) ratio was carried out at Sokcho, Jukbyon and Gampo in February, April, June, August, October, December 2013. Based on T(temperature)-S(salinity) diagram analysis, the water masses in the study area were divided into 3 groups; Tsushima Surface Water (TSW: $20-28.3^{\circ}C$ temperatures and 31.04-33.75 salinities), Tsushima Middle Water (TMW: $8.1-16.3^{\circ}C$ and 33.00-34.49), and North Korean Cold Water (NKCW: $1.8-9.4^{\circ}C$ and 33.78-34.42). In winter, DO concentrations in the northern part were higher than those in southern part. In spring and fall, they were low in the surface layer, and increased in summer. Chl-a concentrations < $0.4{\mu}g/L$ dominated in February, April, October and December. Chl-a concentrations were higher in June and August. In particular, the highest Chl-a concentration > $2{\mu}g/L$ was observed in the middle layer of Gampo in August. In February, April, June and December, the N/P ratio in the most of the water masses was less than the Redfield ratio (16), indicating that nitrate did act as a limiting factor in phytoplankton growth. On the contrary, in August and October, the N/P ratio in surface and sub-surface layer was greater than the Redfield ratio, suggesting that phosphate was a limiting factor.

Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2016 (설비공학 분야의 최근 연구 동향 : 2016년 학회지 논문에 대한 종합적 고찰)

  • Lee, Dae-Young;Kim, Sa Ryang;Kim, Hyun-Jung;Kim, Dong-Seon;Park, Jun-Seok;Ihm, Pyeong Chan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.6
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    • pp.327-340
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    • 2017
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2016. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. Conclusions are as follows. (1) The research works on the thermal and fluid engineering have been reviewed as groups of flow, heat and mass transfer, the reduction of pollutant exhaust gas, cooling and heating, the renewable energy system and the flow around buildings. CFD schemes were used more for all research areas. (2) Research works on heat transfer area have been reviewed in the categories of heat transfer characteristics, pool boiling and condensing heat transfer and industrial heat exchangers. Researches on heat transfer characteristics included the results of the long-term performance variation of the plate-type enthalpy exchange element made of paper, design optimization of an extruded-type cooling structure for reducing the weight of LED street lights, and hot plate welding of thermoplastic elastomer packing. In the area of pool boiling and condensing, the heat transfer characteristics of a finned-tube heat exchanger in a PCM (phase change material) thermal energy storage system, influence of flow boiling heat transfer on fouling phenomenon in nanofluids, and PCM at the simultaneous charging and discharging condition were studied. In the area of industrial heat exchangers, one-dimensional flow network model and porous-media model, and R245fa in a plate-shell heat exchanger were studied. (3) Various studies were published in the categories of refrigeration cycle, alternative refrigeration/energy system, system control. In the refrigeration cycle category, subjects include mobile cold storage heat exchanger, compressor reliability, indirect refrigeration system with $CO_2$ as secondary fluid, heat pump for fuel-cell vehicle, heat recovery from hybrid drier and heat exchangers with two-port and flat tubes. In the alternative refrigeration/energy system category, subjects include membrane module for dehumidification refrigeration, desiccant-assisted low-temperature drying, regenerative evaporative cooler and ejector-assisted multi-stage evaporation. In the system control category, subjects include multi-refrigeration system control, emergency cooling of data center and variable-speed compressor control. (4) In building mechanical system research fields, fifteenth studies were reported for achieving effective design of the mechanical systems, and also for maximizing the energy efficiency of buildings. The topics of the studies included energy performance, HVAC system, ventilation, renewable energies, etc. Proposed designs, performance tests using numerical methods and experiments provide useful information and key data which could be help for improving the energy efficiency of the buildings. (5) The field of architectural environment was mostly focused on indoor environment and building energy. The main researches of indoor environment were related to the analyses of indoor thermal environments controlled by portable cooler, the effects of outdoor wind pressure in airflow at high-rise buildings, window air tightness related to the filling piece shapes, stack effect in core type's office building and the development of a movable drawer-type light shelf with adjustable depth of the reflector. The subjects of building energy were worked on the energy consumption analysis in office building, the prediction of exit air temperature of horizontal geothermal heat exchanger, LS-SVM based modeling of hot water supply load for district heating system, the energy saving effect of ERV system using night purge control method and the effect of strengthened insulation level to the building heating and cooling load.

Dissolved Copper and Nickel in the surface water of East Sea, Korea (동해 표층수중 용존 Cu, Ni의 분포 특성)

  • Yoon, Sang Chol;Yoon, Yi Yong;Suh, Young Sang
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.4
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    • pp.257-267
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    • 2014
  • The distributions of trace metals in the East Sea were investigated during the R/V Lavrentyev cruise (July 2009) in which four transects from Russia shore to South were conducted to collect 25 surface water samples. The total dissolved concentrations of Cu and Ni were measured using ICP-MS, DRC-e. In the coastal area, their concentrations of Russia shore (Cu, 1.51; Ni, 1.82 nM) were 1.9 times for Cu and 2.0 times for Ni lower than Korea shore (Cu, 2.87; Ni, 3.71 nM). In the subregion, their concentrations of Warm region (Cu, 3.03; Ni, 2.28 nM) were higher for Cu than Cold region (Cu, 2.04; Ni, 2.28 nM). The distributions of Cu and Ni concentrations were divided by lowest level at $10^{\circ}C$ of water temperature. In this study period, the surface water temperatures of Russia shore and Japan basin were lower than $10^{\circ}C$ and them of Ulleung basin and Sakhalin shore were higher. Below $10^{\circ}C$, Cu and Ni concentrations increased when surface water temperatures decreased. Above $10^{\circ}C$, their concentrations increased with temperature, which showed highest concentrations in the Ulleung basin, directly influenced by flux from East Korean Warm Current. By comparing with other sea areas (Western Mediterranean, Atlantic), Cu concentrations in the East Sea were a little higher and Ni concentrations were lower. Particularly as the level of Cu in the offshore in the Ulleung basin were higher than in the coastal area, We can suggest that the atmospheric flux of Cu is relatively important in this area.