• 한국자기학회지
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• 제16권6호
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• pp.276-278
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• 2006

스위칭 특성을 향상시키기 위하여 비정질 강자성 CoFeSiB 자유층을 갖는 자기터널접합 (MTJ)의 스위칭 특성을 연구하였다. 자기터널접합의 구조는 $Si/SiO_{2}/Ta$ 45/Ru 9.5/IrMn 10/CoFe 10/CoFe $7/AlO_{x}/CoFeSiB\;(t)/Ru\;60\;(nm)$이다. CoFeSiB는 $560\;emu/cm^{3}$의 낮은 포화자화도와 $2800\;erg/cm^{3}$의 높은 이방성 상수를 가졌다. 이러한 특성이 자기터널접합의 낮은 보자력($H_{c}$)과 높은 자장민감도를 갖게 한다. 이것은 또한 Landau-Lisfschitz-Gilbert 방정식에 근거한 미세자기 전산시뮬레이션을 통하여 submicrometersized elements에서도 확인하였다. CoFeSiB 자유층 두께를 증가함으로서 스위칭 특성은 반자화 자기장의 증가로 인하여 더욱더 나빠졌다.

• 한국자기학회지
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• 제17권1호
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• pp.14-17
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• 2007

고상 반응법을 써서 전이금속(Cr, Ti)을 치환한 란탄칼슘망간산화물, $La_{0.5}Ca_{0.5}(Mn_{0.98}TM_{0.02})O_3$의 자성특성을 연구하였다. 자성 특성은 VSM을 써서 측정하였고, 50 Oe에서 zero field cooling과 field cooling을 하면서, 자화-온도측정을 Cr과 Ti 치환한 경우에 측정하였다. $La_{0.5}Ca_{0.5}(Mn_{0.98}Cr_{0.02})O_3$는 클러스터 또는 스핀유리와 유사한 거동을 보였으며, $La_{0.5}Ca_{0.5}(Mn_{0.98}Ti_{0.02})O_3$에서는 관찰되지 않았다. 큐리온도는 전이금속이 치환된 시편의 경우 란탄칼슘망간산화물 $La_{0.5}Ca_{0.5}MnO_3$의 큐리온도 245.5K에서 감소한, 235.5 K [$La_{0.5}Ca_{0.5}(Mn_{0.98}Cr_{0.02})O_3$], 232.7 K [$La_{0.5}Ca_{0.5}(Mn_{0.98}Ti_{0.02})O_3$]로 모두 감소하였다. 자벽 고정(domain wall pinning)을 알아보기 위해 온도에 따른 보자력 측정을 하였고, 이 결과를 defect와 자벽 간의 상호작용의 관점으로 해석하였다.

• Journal of Magnetics
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• 제21권1호
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• pp.12-19
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• 2016

The <100> oriented $Fe_{83}Ga_{17}$ alloys with various contents of NbC or B were prepared by directionally solidification method at the growth rate of $720mm{\cdot}h^{-1}$. With a small amount of precipitates, the columnar grains grew with cellular mode during directional solidification process, while like-dendrite mode of grains growth was observed in the alloys with higher contents of 0.5 at% due to the dragging effect of precipitates on the boundaries. The NbC precipitates disperse both inside grains and along the boundaries of $Fe_{83}Ga_{17}$ alloys with NbC addition, and the Fe2B secondary phase particles preferentially distribute along the grain boundaries in B-doped alloys. Precipitates could affect grain growth and improved the <100> orientation during directional solidification process. Small amount of precipitate element addition slightly increased the magnetostrictive strain, and a high value of 335 ppm under pre-stress of 15 MPa was achieved in the alloys with 0.1 at% NbC. Despite the fact that the effect on magnetic induction density of small amount of precipitates could be negligible, the coercivity markedly increased with addition of precipitate element for $Fe_{83}Ga_{17}$ alloy due to the retarded domain motion resulted by precipitates.

• 한국자기학회지
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• 제12권1호
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• pp.30-33
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• 2002

초미세결정렵 Nd-Fe-B-Mo-Cu합금에서 Co 치환이 미세조직과 자기특성에 미치는 영향을 조사 하였다. 급속응고법으로 제조된 비정질 Nd-(Fe, Co)-B-Mo-Cu합금은 결정화에 의하여 $\alpha$-Fe기 초미세결정립 Nd-(Fe, Co)-B-Mo-Cu합금이 제조되었다. Co로의 Fe치환은 결정립 미세화에 기여하며, 이로 인하여 경자기특성이 개선되었다. 최적열처리된 초미세결정립 N $d_4$(F $e_{0.85}$ $Co_{0.15}$)$_{82}$ $B_{10}$M $o_3$Cul합금의 잔류자화, Curie온도는 Co가 치환되지 않은 합금에 비하여 개선된 우수한 특성을 나타내었다. 64$0^{\circ}C$, 10분 열처리된 초미세결정립 N $d_4$(F $e_{0.85}$ $Co_{0.15}$)$_{82}$ $B_{10}$M $o_3$Cu 합금의 평균결정립 크기는 약 15 nm이며, 이때 보자력, 잔류자화 및 최대에너지적은 각각 239kA/m, 1.4 T 및 103.5 kJ/ $m^3$이었다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 영호남학술대회 논문집
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• pp.13-16
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• 2000

In this study, we have fabricated nonequilibrium $Fe_{85.6}Zr_{3.3}B_{5.7}Ag_{5.4}$ thin film, which contains an additional insoluble element Ag, by using DC magnetron sputtering method. We have investigated the magnetic properties of amorphous $Fe_{85.6}Zr_{3.3}B_{5.7}Ag_{5.4}$ thin film as a function of rotational field annealing(RFA). After deposition, the amorphous $Fe_{85.6}Zr_{3.3}B_{5.7}Ag_{5.4}$ thin film annealed by rotational field annealing method at $350^{\circ}C$ for an hour was founded to have high permeability of 8680 of 100 MHz, 0.2 mOe, low coercivity of 0.86 De and very low core loss of 1.3 W/cc at 1 MHz, 0.1T.

• Journal of Magnetics
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• 제9권4호
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• pp.109-112
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• 2004

The HDDR (Hydrogenation-Disproportionation-Desorption-Recombination) process is a special method to produce anisotropic NdFeB powders for bonded magnet. The effect of the modified HDDR process on magnetic properties of $Nd_2Fe_{14}B$-based magnet with several composition $Nd_{11.2}Fe_{66.5-x}Co_{15.4}B_{6,8}Zr{0.1}Ga_x(x=0{\sim}1.0)$ and that of microelement Ga, disproportional temperature and annealing temperature on $_jH_c$, grain size were investigated in order to produce anisotropic powder with high magnetic properties. It was found that modified HDDR process is very effective to enhance magnetic properties and to fine grain size. The addition of Ga could change disproportionation character remarkably of the alloy and could improve magnetic properties of magnet powder. Increasing annealing temperature induces significant grain growth. And grain size produced by modified HDDR process is significantly smaller than those produced by conventional HDDR process.

• Journal of Magnetics
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• 제14권2호
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• pp.75-79
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• 2009

Nickel (Ni) and ferrite ($Fe_3O_4$, $NiFe_2O_4$) nanoparticles were synthesized by LGC using both wire feeding (WF) and micron powder feeding (MPF) systems. Phase evolution and magnetic properties were then investigated. The Ni nanopowder included magnetic-ordered phases. The LGC synthesis yielded spherical particles with large coercivity while the abnormal initial magnetization curve for Ni indicated a non-collinear magnetic structure between the core and surface layer of the particles. Since the XRD pattern cannot actually distinguish between magnetite ($Fe_3O_4$) and maghemite (${\gamma}-Fe_2O_3$) as they have a spinel type structure, the phase of the iron oxide in the samples was unveiled by $M{\ddot{o}}ssbauer$ spectroscopy. The synthesized Ni-ferrite consisted of single domain particles, including an unusual ionic state. The synthesized nanopowder bore an active surface due to the defects that affected abnormal magnetic properties.

• 한국분말재료학회지
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• 제6권1호
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• pp.27-35
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• 1999

A study was made on the fabrication of nanostructured Fe-Co powders by mechanical alloying and their magnetic properties. Microstrural development during the process of MA was inverstigated by means of X-ray diffraction, differential thermal analyzer, scanning electron microscopy and transmission electron microscopy. The magnetic properties of NS Fe-Co powders were evaluated through the measurements of the saturation magnetization $(M_s)$ as well as the coercivity $(H_c)$. The average grain size calculated from line braodening in XRD peak was about 10nm or less and confirmed by TEM. In this experiment, two different milling methods (cycle opertion and conventional milling) were used. Cycle operation had an advantage over the conventional milling method in that more refined powders can be obtained. Solid state alloying of the components was confirmed from both the change of the saturation magnetization and the change of lattice parameter with Co contentration. Maxium $M_s$ was obtained at the composition of 30at.%Co. Relatively high coercivities of 10~150e were obtained for the compositions investigated, and this seems to be due to the high amount of internal strain introduced during milling.

• Journal of Magnetics
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• 제8권3호
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• pp.108-112
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• 2003

We report the experimental finding that there exists a transition of magnetization reversal process with varying the applied field in Co/Pd multilayer. We have measured the wall-motion speed V and the nucleation rate R during magnetization reversal via time-resolved direct domain observation, where the magnetization reversal process of Co/Pd multilayer is found to take a transition from thermal activation process to viscous process at the critical field of about 1.87 H$\_$C/ (coercivity). In the thermal activation regime, we find that the field dependences of two activation volumes for the wall-motion process and the nucleation process are different with each other, which reveals that the wall-motion and nucleation experience completely different interactions. In the viscous regime, we find that the wall-mobility is much smaller than a typical value for the sandwiched Co films, which implies that the Co/Pd interfaces in multilayer substantially contribute to the dynamic dissipation.

• Journal of Magnetics
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• 제7권4호
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• pp.143-146
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• 2002

Mechanical milling technique is considered to be a useful way of processing the fine Nd-Fe-B-type powder with high coercivity. In the present study, phase evolution of the $Nd_{15}(Fe_{1-x}Co_{x})_{77}B_{8}$ (x=0-0.6) alloys during the high energy mechanical milling and annealing was investigated. The effect of Co-substitution on the crystallization of the mechanically milled $Nd_{15}(Fe_{1-x}Co_{x})_{77}B_{8}$ amorphous material was examined. The Nd-Fe-B-type alloys can be amorphized completely by a high-energy mechanical milling. On annealing of the amorphous material, fine $\alpha$-Fe crystallites form first from the amorphous. These fine $\alpha$-Fe crystallites reacts with the remaining amorphous afterwards, leading to crystallization to $Nd_2Fe_{14}$B phase. The Co-substitution for Fe in $Nd_{15}(Fe_{1-x}Co_{x})_{77}B_{8}$ ($\mu$x=0∼0.6) alloys lower significantly the crystallization temperature of the amorphous phase to the $Nd_2Fe_{14}$B phase. The mechanically milled and annealed $Nd_{15}Fe_{77}B_8$ alloy without Co-substitution exhibits consistently better magnetic properties with respect to the alloys with Co-substitution.