• 한국자기학회지
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• 제10권5호
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• pp.237-245
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• 2000

SmFe$_2$에 해당되는 조성을 가진 비정질 합금 박막에 대하여 자기적 및 자기변형 성질이 B함량 (최대 약 10at.%) 및 열처리에 의해 변화하는 거동을 조사하였다. 묘의 첨가에 의해 낮은 자기장에서의 자기변형은 증가하였으나, 포화 자기 변형은 감소하는 경향을 보였다. B을 첨가하지 않은 박막과 B을 9.9 at.% 첨가한 박막을 예로 들면, 30 Oe의 자기장에서 자기변형은 190 ppm에서 333 ppm으로 1.6배 정도 증가하였으나, 5 kOe의 자기변형은 50 % 이상 감소되었다. 이러한 자기변형 결과는 B의 첨가에 의해 포화 자화와 같은 고유 자기적 성질은 열화되었으나, 보자력은 향상(감소)된 것에 주로 기인하는 것으로 생각된다. 자기변형 성질은 열처리에 의해 향상되었는데, 최적의 열처리 온도는 300~40$0^{\circ}C$이다. 열처리에 의한 이러한 특성 향상은 당초 기대했던 미세한 결정 상 SmFe$_2$상의 석출에 의한 것이 아니라, 응력 완화에 의한 보자력의 감소가 주된 원인으로 생각된다.

• 한국자기학회지
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• 제22권2호
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• pp.58-65
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• 2012

1983년 Nd-Fe-N계 자석이 발표된 이후 지난 20년간 많은 새로운 응용분야가 개척되었다. 모터시장과 관련해서는 자동차와 전기/전자 응용분야의 에너지절감이라는 강한 요구 때문에 그 시장이 크게 확대될 것으로 예상된다. 특히, 하이브리드/전기자동차용 영구자석 모터는 최근 크게 주목을 받고 있으며 향후 모터시장을 주도해 나갈 것이다. 하지만 이러한 친환경자동차는 약 $200^{\circ}C$ 정도의 높은 온도에서 작동한다는 심각한 문제점을 가지고 있다. 왜냐하면 Nd-Fe-B계 자석은 온도가 높으면 보자력이 급격히 감소하는 약점을 가지고 있기 때문이다. 현재로서 이러한 약점을 보완하기 위한 최선의 방법은 Dy를 첨가하는 것이다. 그렇기 때문에 Dy는 고성능 Nd-Fe-B계 자석이 높은 온도에서도 보자력을 유지할 수 있도록 해주는 필수원소가 되었다. 한편, 지구상의 희토류 자원은 지역편중이 심하고 대부분이 중국에서 생산되고 있다. 특히, Nd과 Sm 같은 경희토류에 비해 그 자원편중이 훨씬 심하고 생산량이 적어 가격이 Nd의 약 10배 정도인 Dy와 같은 중희토류의 사용량을 줄이는 기술이 관련산업에서 크게 요구되어지고 있다. 이 글에서는 이러한 희토류 자원문제 해결을 위한 영구자석 연구개발 동향에 대해 살펴보았다.

• 공업화학
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• 제17권3호
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• pp.267-273
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• 2006

Melt-blown 방사법으로 Ba-ferrite 포함하는 PP 복합수지를 방사하여 부직포 섬유를 제조하는 공정에서 방사공정인자와 부직포 특성과의 상관관계를 조사하였다. PP 수지와 Ba-ferrite 분말을 혼합한 후 단축 압출 성형기를 이용하여 펠렛 형태로 제조하고 Melt-blown 섬유 방사기를 이용하여 screw turning force (rpm)와 DCD (die-to-collector distance)를 변화시켜 Ba-ferrite 분말이 부직포 섬유의 기계적, 열적, 결정학적 및 자성 특성에 미치는 영향을 조사하였다. SEM 관찰을 통하여 방사 거리가 증가할수록 혹은 screw turning force가 감소할수록 부직포 섬유의 연신율이 증가하고, 섬유의 직경 및 인장강도가 감소하는 것을 알 수 있었고, XRD 측정 결과로부터 방사거리의 증가는 섬유의 결정성을 높이는 것으로 관찰되었다. 복합 부직포에서는 입자가 고분자와 분리되어 고분자와 입자간의 결합력이 떨어져 순수한 PP대비 인장강도가 감소하였다. Ba-ferrite 분말에 의한 부직포의 자성적 성질을 보면 방사거리에 따라 보자력, 최대 자화, 잔류 자화 값은 감소하였다. TGA 측정을 통한 부직포 섬유의 내열성 시험 결과는 방사거리의 감소에 따라 내열성이 증가하였으며 난연성은 Ba-ferrite 분말의 함량 증가에 따라 증가하였다.

• Journal of Magnetics
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• 제2권1호
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• pp.1-6
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• 1997

The magnetic and magnetostrictive properties of melt-spun ribbons of the alloys (R0.33Fe0.67)1-xBx (R=Tb0.3Dy0.7 and 0$\leq$x$\leq$0.06) are ivestigated as a function of wheel speed during melt-quenching. The saturation magnetiation of the alloys with a crystalline phase ranges from 70 to 80 emu/g and does not vary substantially with the B content. The saturation magnetization of an amorphous phase, which is formed at the condition of thigh wheel speed and high B content, is reduced significantly, however. The coercive force is minimum at x= 0.02 and increases monotonously with the further increase of B content when the microstructure mainly consists of a crystalline phase, but again it is reduced significantly by the formation of an amorphous phase. The low field sensitivity of magnetostriction with magnetic field is found to be good for the alloys with x$\leq$0.04 over a wide range of wheel speed. This magnetostrictive behavior is in contrast with that observed previously for Dy-Fe and Tb-Fe based alloys and is thought to be due to low intrinsic magnetocrystalline anisotropy of the compound.

• 한국표면공학회지
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• 제50권3호
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• pp.212-218
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• 2017

$Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrite powders were prepared by self-propagating high temperature synthesis followed by classifying with an ultrasonic wet-magnetic separation unit to get high pure nano-sized particles. The $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrites were well formed by using several powders like iron, nickel oxide, zinc oxide and magnesium oxide at 0.1 MPa of oxygen pressure. The ultrasonic wet-magnetic separation of pre-mechanical milled ferrite powders resulted in producing the powders with average size of 800 nm. The addition of a surfactant during the wet-magnetic separation process improved productivity more than twice. The coercive force, maximum magnetization and residual magnetization of the $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ nano-powders with 800 nm size were 3651 A/m, $53.92Am^2/kg$ and $4.0Am^2/kg$, respectively.

• Advances in materials Research
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• 제3권4호
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• pp.233-242
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• 2014

Magnetic and conducting aniline sulfide resin cross-linked (ASC-Fe3O4) nanocomposite has been prepared in the presence of aniline sulfide resin (ASR), aniline, $Fe_3O_4$ coated by polyethylene glycol (PEG) and initiator. The magnetic properties of the resulting composites showed ferromagnetic behavior, such as high-saturated magnetization (Ms= 41 emu/g), and coercive force (Hc=1.5 Oe). The saturated magnetization was increased by increasing of $Fe_3O_4$ content and decreased by increasing aniline ratio. The transmission electron micrograph (TEM) and X-ray diffraction proved that nanometer-sized about 20-30 nm $Fe_3O_4$ in the composite. The average size of ASC-$Fe_3O_4$ nanocomposite with core-shell structure was about 50-60 nm, and polydisperse. This approach may also be extended to the synthesis and modification of other polymers. Electrical conductivity of aniline sulfide resin cross-linked (ASC) nanocomposite has been studied by four-point probe method and produced $3.3{\times}10^{-4}S/cm$ conductivity for it. The conductivity of the composites at room temperature depended on the $Fe_3O_4$, aniline ratio and doping degree. The thermogravimetry analysis (TGA) results showed that this resin is thermal resistance near of $500^{\circ}C$. So, It can be used for resistance thermal coating for military applications. $Fe_3O_4$-PASC nanocomposite has been flexible structure with electrical and magnetic properties.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
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• pp.239-239
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• 2003

As a result of the recent miniaturization and enhancement in the performance of thin film inductors and thin film transformers, there are increased demands for the thin films with a high magnetic permeability in the high frequency range, a high saturation magnetization, a high electrical resistivity, and a low coercive force. In order to improve high frequency properties, we will investigate anisotropy field by shape and size of pattern. The Fe-Al-O thin films of 16mm diameter and 1$\mu\textrm{m}$ thickness were deposited on Si wafer, using RE magnetron reactive sputtering technique with the mixture of argon and oxygen gases. The fabricating conditions are obtained in the working partial pressure of 2m Torr, O$_2$ partial Pressure of 5%, Input power of 400w, and Al pellets on an Fe disk with purity of 99.9%. For continuous thin film is the 4Ms of 19.4kG, H$\sub$c/ of 0.6Oe, H$\sub$k/ of 6.0Oe and effective permeability of 2500 up to 100MHz. In this work, we expect to enhanced effect of magnetic anisotropy on patterned of Fe-Al-O thin films.

• 한국전기전자재료학회논문지
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• 제23권12호
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• pp.988-995
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• 2010

In this study the (Alnico, Sm-Co) bonded magnets were fabricated by mixing the Sm-Co added alnico alloy powders with epoxy resin and binder, appropriately. Also, the hybrid ring magnets of (Alnico, Sm-Co)/Sr-ferrite were fabricated by coupling the Sr-ferrite composite layer with an (Alnico, Sm-Co) magnet. The magnetic properties of (Alnico, Sm-Co) ring magnets were varied with the amount of Sm-Co powders. The addition of Sm-Co powders increased a remanent induction($B_r$) and coercive force($_BH_C$), while decreasing a surface flux density and repulsive distance. The surface flux density and repulsive distance for the (Alnico, Sm-Co) ring magnet increased with a magnetizing voltage up to about 160 V and reached an apparent saturation point. Also, the measurements of temperature and moisture characteristics showed that the surface flux densities of N-S poles and repulsive distance decreased a little within 4% after 10 days passed.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 D
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• pp.1447-1449
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• 1998

The c-axis orientation plays a very important role in controlling the main parameters of the perpendicular magnetic recording media, such as perepndicular magnetic anisotropy field $H_{K{\bot}}$, the ratio of coercive force $H_{C{\bot}}/H_{C//}$, the recording density $D_{50}$, and the dispersion of the c-axis orientation $\Delta\theta_{50}$, which is quite important for the performance as perpendicular recording media, as well as the magnetic properties of the film. In this study, the essential process requirement for preparing the Co-Cr films with the superior c-axis orientation, the dependence of $\Delta\theta_{50}$ and the magnetic properties on the film thickness $\delta$, and the effect of underlayer on the dispersion of c-axis orientation have been investigated for both the FTS and DCM system.

• 대한화학회지
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• 제56권5호
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• pp.609-616
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• 2012

Ba-ferrite ($BaFe_{12}O_{19}$) nanoparticles were synthesized by chemical coprecipitation method in an aqueous solution. The particle size and the crystallization temperature of the Ba-ferrite nanoparticles were controlled varying the precipitation temperature. The precipitate that was prepared at $0^{\circ}C$ showed the crystal structure of Ba-ferrite in X-ray diffraction when it was calcined at the temperature above $580^{\circ}C$, whereas what was prepared at $50^{\circ}C$ showed the crystallinity when it was calcined at the temperature higher than about $700^{\circ}C$. The particle sizes of the synthesized Ba-ferrite were in a range of about 20-30 nm when it was prepared by being precipitated at $0^{\circ}C$ and calcined at $650^{\circ}C$. When the precipitation temperature increased, the particle size also increased even at the same calcination temperature. The magnetic properties of the Ba-ferrite nanoparticles were also controlled by the synthetic condition of precipitation and calcination temperature. The coercive force could be appreciably lowered without a loss of saturation magnetization when the Ba-ferrite nanoparticles were prepared by precipitation and calcination both at low temperatures.