• Title/Summary/Keyword: Cobalt-60

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Phase evaluation of Fe/Co pigments coated porcelain by rietveld refinement (리트벨트 정밀화법에 의한 Fe/Co 안료가 코팅된 도자기의 상분석)

  • Nam-Heun Kim;Kyung-Nam Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.5
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    • pp.174-180
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    • 2023
  • Porcelain (white ware, celadon ware) coated with a ferrous sulfate and ferrous/cobalt sulfate was sintered at 1250℃. The specimens were investigated by HR-XRD, FE-SEM, HR-EDS, and UV-vis spectrophotometer. Through X-ray rietveld quantitative analysis, quartz and mullite were found to be the main phases for white ware, and mullite and plagioclase were found to be the main phases for celadon ware. When the pigment of ferrous/cobalt sulfate was applied, were identified as an andradite phase for celadon ware and a spinel phase for the white ware, and the amorphous phase, respectively. The L* value, which was the brightness of the specimen, was 72.01, 60.92 for white ware and celadon ware, respectively. The ferrous and ferrous/cobalt pigment coated porcelain had L* values of 44.89, 52.27 for white ware and celadon ware, respectively; with a* values of 2.12, 1.40, an d at b* values of 1.45 and 13.79. As for the color of the specimens, it was found that the L* value was greatly affected by the white ware, and the b* value differed greatly depending on the clay. It was thought to be closely related to the production of the secondary phase such as Fe2O3 and andradite phase produced in the surface layer.

Analysis of Heavy Metals Content in Distributed Children's Cosmetic Set (유통 어린이 화장품 세트의 중금속 함량에 관한 분석)

  • In-Sook Lee;Yeon-Ji Kim;Koth-Bong-Woo-Ri Kim;Pyoung-Tae Ku
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.50 no.1
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    • pp.77-84
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    • 2024
  • Four children's cosmetic sets were purchased online, labeled for use from 4 years of age, and 81 components of each were analyzed for lead, cadmium, arsenic, antimony, nickel, cobalt, copper, chromium, and mercury by inductive coupled plasma - mass spectrometry (ICP - MS). The average metal concentrations were as follows: 0.82 ㎍/g for lead, 0.03 ㎍/g for cadmium, 0.97 ㎍/g for arsenic, 0.52 ㎍/g for antimony, 2.32 ㎍/g for nickel and 0.01 ㎍/g for mercury which was lower than the acceptable standards for all products. Higher mean values of lead, antimony, cobalt, and copper were detected in imported than domestic products (p < 0.05). There was a statistically significant difference in the average values of heavy metals according to the type of cosmetics (p < 0.05), with eyeshadow showing the highest mean values of arsenic 2.47 ㎍/g, nickel 6.36 ㎍/g, and chromium 11.06 ㎍/g. and the highest mean concentrations were 1.20 ㎍/g for lead, 1.17 ㎍/g for antimony, and 23.60 ㎍/g for copper in blusher. The levels of cobalt in the 81 children's cosmetics were ND ~ 5.23 ㎍/g, copper were ND ~ 379.61 ㎍/g, and chromium were detected ND ~ 36.95 ㎍/g, respectively. Brown colored cosmetics had the highest mean concentrations of nickel and cobalt. Purple-colored cosmetics had the highest mean concentration of lead and chromium.

AN ELECTRON MICROSCOPIC STUDY ON THE EFFECTS OF IRRADIATION ON THE BUCCAL MUCOSA OF RAT (방사선조사가 백서 협점막에 미치는 영향에 관한 전자현미경적 연구)

  • Choi Syng Kyu;Lee Sang Rae
    • Journal of Korean Academy of Oral and Maxillofacial Radiology
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    • v.17 no.1
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    • pp.7-20
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    • 1987
  • The author studied the acute reaction of cobalt-60 irradiation to buccal mucosa in rats and difference of the effects of single versus fractionated exposure. 195 Sprague Dowley strain rats, weighing about 120gm, were used in this experiment. 3 rats served as controls and the remaining 192 rats were divided into six groups of 32 rats each. Experimental group Ⅰ, Ⅱ, Ⅲ were received a single dose of 15Gy, 16.5Gy, 18Gy and group Ⅳ, Ⅴ, Ⅵ were received two equal sized fractionated dose of 9Gy, 9.75Gy, 10.5Gy at 4 hour intervals, respectively. The experimental groups were irradiated with cobalt-60 teletherapy unit, Picker model 4M 60 (Field size, 12x5 cm, SSD, 50㎝, Dose rate, 222cGy/min, Depth, 1㎝). The animals were sacrificed at 1, 2, 3, 6, 12 hours, 1, 3, 7 days after irradiation and the changes of the irradiated buccal mucosa were observed by electron and light microscopy. The results were as follows: 1. A single exposure was more damaging than fractionated exposure, and as the radiation dose increased, the changes of cell organelles became faster, but the healing of radiation-induced damage in fractionated exposure was faster than in single exposure. 2. The radiation-induced changes of the basal cells were the most prominent in 18Gy-single exposure group, and the least in 18Gy-fractionated exposure group. 3. Electron-microscopically, there appeared nuclear changes, swelling of mitochondria and rough endoplasmic reticulum, decrease of free ribosome, presence of vesicles, widening of intercellular space, and loss of basal lamina. The early remarkable changes were partly loss of nuclear membrane and swelling of mitochondria. 4. Light-microscopically, derangement and pyknosis of basal cells, hydropic changes of spinous cells, enlargement of granular cells, indistinctness of basement membrane, and proliferation of epithelium were observed.

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The Determination of the Sand Drift Movement Using Radioactive Tracer at Young Il Bay (방사성 동위원소를 이용한 영일만 해역표사의 조사)

  • Yang, Kyung Rin
    • 한국해양학회지
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    • v.4 no.1
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    • pp.9-16
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    • 1969
  • The sand drift movement at Young Il Bay area was tentatively investigated using Co-60 glass sand. Grain size and specific gravity of the glass sand which has originally contained natural cobalt, Co-59, was made similar to those of the real coastal sand, and was irradiated in a beam port of the reactor Triga Mark II to make the glass sand radioactive by the reaction of 59Co(n, r)60Co. The radioactive cobalt glass sand was deposited on the preselected point of sea bed, and, after a couple of weeks, the drift of sand was traced by means of specially designed water-proof G-M detector. Net counts at each point were plotted to figure out equicount lines and consequently such aspects as the direction of sand drift movement, the scope of distribution and the relative drift velocity etc. were indicated.

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LACTIC ACID DEHYDROGRENASE IN THE COBALT$Co^{60}$ IRRADIATED RAT INCISOR PULP (백서에 $Co^{60}$ 조사시 전치 치수내 LDH isoenzyme에 관한 연구)

  • Chung, Tai-Young;Chung, Ki-Kuen;Yi, Kui-Nyung;Choi, Kuen-Bae;Kim, Dong-Soon
    • The Journal of the Korean dental association
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    • v.10 no.2
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    • pp.97-107
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    • 1972
  • 백서에 1000R의 $Co^{60}$-gamma선을 전신 조사 후 시간에 따른 LDH isoenzyme의 Pattern과 그의 활성도의 변화를 관찰한 바 다음과 같은 결론을 얻었다. 1. 조사후 72시간에 LDH-1와 LDH-4의 뚜렷한 Pattern을 나타내어, 이는 치수의 energy 대사가 염기성과 호기성 대사과정을 동시에 행함을 의미한다. 2. LDH의 총활성도는 조사후 24시간에 현저히 감소하였으나 72시간 후에는 거의 비조사군에 가까워졌다.

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A Study on the Hand drum form of Wire-Cut Electric Discharge Machining (와이어 방전가공에 의한 북현상에 관한 연구)

  • 김원일;이재명;강종표
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.9-14
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    • 1997
  • From the experimental study of wire-cut Electric Discharge Machining for alloyed steel and tungsten carbide, the characteristics such as hand drum form has been observed and evaluated for various conditions. Hand drum form can be improved when gap voltage and spark cycle become smaller, their thickness become thinner, wire tension become larger and number of cutting is done so many times. When wire-cut 60mm thickness tungsten carbide in normal condition, Hand drum form becomes larger due to the low conductivity inducing cobalt composite rising by electrolysis.

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Effects of Cobalt-60 Gamma Ray Irradiation on Blood Cells and Enzyme Activity of Albino Rats (코발트-60 감마선(線) 조사(照射)가 흰쥐의 혈액성분(血液成分) 및 수종(數種) 효소(酵素)의 활성(活性)에 미치는 영향(影響))

  • Lee, Sang-Suk
    • Journal of radiological science and technology
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    • v.8 no.2
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    • pp.47-63
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    • 1985
  • This paper was aimed to study the effects of Cobalt-60 gamma ray irradiation on Albino rat blood cells and the activity of enzymes were measured using blood cell auto analyzer (Cell-Dyn 900) and enzyme autoanalyzer (Gilford 3500) respectively. Cobalt-60 gamma rays those are grouped into 200R, 400R, 600R, 800R, 1,000R, 1,200R, 1,300R, 1,400R, 1,500R and 1,600R to the rats of male and female and measured the numeral varieties of blood corpuscles of the rats and the active varieties of enzyme of acid, alkaline phosphatase (ACP, ALP), lactic acid dehydrogenase (LDH), glutamic oxaloacetic transaminase (GOT) and glutamic pyruvic transaminase. (GPT) those came out after 1, 3, 5 or 7 days. The results are summarized as follows: 1. In both case of male and female, the numeral varieties of the erythrocytes, in the 200R group of irradiation showed the minimum value in the 3 days group and a tendency of increase in the 5 and 7 days groups, while the numeral varieties of the leucocytes in every groups of irradiation showed a tendency of a rapid decrease after a day. The numeral varieties of the blood platelet in both case of male and female didn't show generally any great change in a day and 3 days groups, but showed a rapid decreasing appearance after the 5 days. 2. In both case of male and female, the activities of ACP were on the decrease gradually after 3 days of the irradiation and the activities of ALP were on the decrease after 5 days. Similarly in both case of mate and female, the activities of LDH showed the decrease after 3 and 5 days, and the phenomenous of GOT showed an appearance of increase in a day, but decreased after 3 days. As for the GPT activities couldn't find any great change in the male rats in comparison with the control groups, but in the female rats a tendency of the increase in 600R, 800R, 1,000R groups after 3 days. 3. In the case of the irradiation of high quantity of ray more than 1,200R, all rats died after 4 days, and by the irradiation of 1,600R all rats died after 3 days, and it showed the sensitive response of a living body to the irradiation of high quantity.

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Synthesis and Formation Mechanism of Cobalt Doped Willemite Blue Pigments (Co-Doped Willemite 파란색 안료의 합성과 생성기구)

  • Hwang, Dong-Ha;Han, Kyong-Sop;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.603-607
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    • 2010
  • Turquoise blue pigment of Vanadium-zircon blue (DCMA number 14-42-2), which was already commercialized, was stable to be reproduced but insufficient to give strong blue. However, it possible to obtain more intense blue by partially substituting cobalt ions into the willemite($Zn_2SiO_4$) lattice classified into DCMA number 7-10-2 for blue ceramic pigment. By the composition of willemite $Co_xZn_{2-x}SiO_4$(X=0.01, 0.03, 0.05, 0.07, 0.09 mole), this study used reagent grade zinc oxide, cobalt oxide and silicon dioxide as starting materials, carrying out the synthesis with solid reaction method by adding $H_3BO_3$ as a mineralizer. The firing temperature was between $1200^{\circ}C$ and $1400^{\circ}C$. The characteristics of synthesized pigment were analyzed by X-ray diffraction, Raman spectroscopy and SEM and the characteristics of color tones were analyzed by UV-Vis spectroscopy and CIE-$L^*a^*b^*$ measurement. As a result, the optimal composition was $Zn_{1.95}Co_{0.05}$ with 1wt% of $H_3BO_3$ as a mineralizer and firing condition was $1350^{\circ}C$/3 h. $L^*a^*b^*$ value was 29.25, 41.03, -59.93 for on glaze pigment and 37.03, 36.41, -60.03 for under glaze pigment.

The Copper, Cobalt, Iron, Selenium and Zinc Status of Cattle in the Sanyati and Chinamhora Smallholder Grazing Areas of Zimbabwe

  • Mpofu, I.D.T.;Ndlovu, L.R.;Casey, N.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.4
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    • pp.579-584
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    • 1999
  • The trace mineral status of cattle in the smallholder grazing areas of Sanyati and Chinamhora in Zimbabwe was evaluated during the rainy and dry seasons of 1994 and 1995. The evaluation was done in terms of mineral concentration in blood plasma. Plasma copper in calves, steers and cows in the dry season was; Sanyati: 0.55, 0.59, and 0.61; Chinamhora: 0.59, 0.58, and $0.60{\mu}g/ml$, respectively versus a normal of $0.65{\mu}g/ml$. In the rainy season, copper was deficient at both sites (averaging $0.56{\mu}g/ml$ and $0.59{\mu}g/ml$ at Sanyati and Chinamhora, respectively). Plasma selenium in the dry season was 0.017, 0.025, and $0.017{\mu}g/ml$ for calves, steers and cows, respectively at Sanyati versus a normal of $0.03{\mu}g/ml$ and therefore considered to be deficient. Iron, zinc and cobalt were found to be generally high and therefore unlikely to be deficient. Copper and selenium are recommended in salt licks in these environments.

Flow Properties of Liquid Epoxy Compounds as a Function of Filler Fraction for the Underfill (Underfill용 액상 Epoxy Compound의 Filler 충진에 따른 Flow특성 연구)

  • 김원호;황영훈;배종우;정혜욱
    • Journal of the Microelectronics and Packaging Society
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    • v.7 no.2
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    • pp.21-27
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    • 2000
  • To develop the underfill materials which are required for the new process of semi-conductor industry, the properties of epoxy/anhydride/cobalt(II) catalyst system with two types of fused silica(1 $\mu\textrm{m}$, 8 $\mu\textrm{m}$) are studied as a function of filler fraction. According to the curing profile, the optimum catalyst amount was 1.0 wt% for full curing at the conditions of $160^{\circ}C$/l5 min., and we could conclude that the viscosity has superior effect on the real flaw through the relationship between surface tension and viscosity data. The underfills which were filled with 1 $\mu\textrm{m}$ fused silica did not show good flowability, but they should be useful by improving the viscosity for a future process which has small gaps. The underfills which were filled with 8 $\mu\textrm{m}$ fused silica showed good flowability when the filler contents were 55~60 vol%. The model which was referred by Matthew can predict the real flow length only when the underfill has high viscosity and low surface tension.

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