• Title/Summary/Keyword: Coated structure

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Effective Carbon Coating on $LiFePO_4$ Using Petroleum Pitch (석유 핏치를 이용한 $LiFePO_4$의 효율적인 탄소 코팅방법)

  • Lee, Jae-Won;Oh, Chi-Hoon;Park, Sun-Min
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.303-304
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    • 2007
  • A comparison study of carbon coating on $LiFePO_4$ was done with two different carbon sources-petroleum pitch and Ketjen black. Raman spectroscopy and transmission electron microscopy (TEM) analysis were applied to the carbon-coated $LiFePO_4$. $LiFePO_4$ which was carbon-coated with petroleum pitch showed more uniform carbon layer and ordered carbon structure. Such uniformity and ordered structure of carbon coating layer resulted in higher initial discharge capacity and better rate capability.

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Polybenzimidazole (PBI) Coated CFRP Composite as a Front Bumper Shield for Hypervelocity Impact Resistance in Low Earth Orbit (LEO) Environment

  • Kumar, Sarath Kumar Sathish;Ankem, Venkat Akhil;Kim, YunHo;Choi, Chunghyeon;Kim, Chun-Gon
    • Composites Research
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    • v.31 no.3
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    • pp.83-87
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    • 2018
  • An object in the Low Earth Orbit (LEO) is affected by many environmental conditions unlike earth's surface such as, Atomic oxygen (AO), Ultraviolet Radiation (UV), thermal cycling, High Vacuum and Micrometeoroids and Orbital Debris (MMOD) impacts. The effect of all these parameters have to be carefully considered when designing a space structure, as it could be very critical for a space mission. Polybenzimidazole (PBI) is a high performance thermoplastic polymer that could be a suitable material for space missions because of its excellent resistance to these environmental factors. A thin coating of PBI polymer on the carbon epoxy composite laminate (referred as CFRP) was found to improve the energy absorption capability of the laminate in event of a hypervelocity impact. However, the overall efficiency of the shield also depends on other factors like placement and orientation of the laminates, standoff distances and the number of shielding layers. This paper studies the effectiveness of using a PBI coating on the front bumper in a multi-shock shield design for enhanced hypervelocity impact resistance. A thin PBI coating of 43 micron was observed to improve the shielding efficiency of the CFRP laminate by 22.06% when exposed to LEO environment conditions in a simulation chamber. To study the effectiveness of PBI coating in a hypervelocity impact situation, experiments were conducted on the CFRP and the PBI coated CFRP laminates with projectile velocities between 2.2 to 3.2 km/s. It was observed that the mass loss of the CFRP laminates decreased 7% when coated by a thin layer of PBI. However, the study of mass loss and damage area on a witness plate showed CFRP case to have better shielding efficiency than PBI coated CFRP laminate case. Therefore, it is recommended that PBI coating on the front bumper is not so effective in improving the overall hypervelocity impact resistance of the space structure.

Improving printability by designing a multi-layered coating structure (I) - The effect of binder properties in the pre-coating layer on the characteristics of the top-coating layer - (다층도공층의 설계에 의한 인쇄적성 개선 (제1보) - 프리코팅층의 바인더 물성이 탑코팅층의 특성에 미치는 영향 -)

  • Kim, Sun-Kyung;Won, Jong Myoung;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.27-33
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    • 2016
  • This study was carried out in order to investigate the effect of binder properties in pre-coating layer on the characteristics of top-coating layer and print mottle of coated paper. Four different latices were used as a binder in pre-coating layer, and coating color prepared with a same formulation was applied for top-coating. The properties and print mottle of coated paper were evaluated. It was found that glass transition temperature (Tg) was the important factor to control the properties of pre- and top-coating layer. PPS roughness of coated paper was decreased and paper gloss was increased with applying binder which has lower Tg. Properties of top-coating layer were affected by the binder used in pre-coating layer. Print mottle of coated paper was improved with using binder which has lower Tg in pre-coating layer. These results indicate that final printability and properties of top-coating layer can be improved with using suitable binder in pre-coating layer.

Improvement of printability by the new designe of the multi-layered coating structure (II) - The effect of pigment blending in pre-coating layer on characteristics of top-coating layer - (다층도공층의 설계에 의한 인쇄적성 개선(제2보) - 프리코팅층의 안료배합이 탑코팅층의 특성에 미치는 영향 -)

  • Kim, Sun-Kyung;Won, Jong Myoung;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.61-67
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    • 2016
  • This study was carried out in order to investigate the effect of pigment properties in a pre-coating layer on the characteristics of a top-coating layer and the print mottle of the coated paper. Five different pigments were applied for this study as raw materials for the pre-coating layer. The properties and print mottle of the coated paper samples were evaluated according to the coating color formulation. Type of pigments appliied in a pre-coating layer was one of the most important factor to control the properties of pre and top coating layer. Surface properties of pre and top coated paper were improved by blending GCC which had smaller particle size, with clay. Properties of a top-coating layer was affected by the pigment properties used in the pre-coating layer. It was found that print mottle of coated paper can be improved by replacing part of GCC with smaller particle size GCC or clay in pre-coating layer.

Effect of Adding WO3 on Photocatalytic Property of TiO2 Coated Coal Fly Ash (WO3 피복 석탄회의 광촉매 특성에 미치는 TiO2의 첨가 효과)

  • Yu, Yeon-tae;Kim, Byoung-gyu
    • Korean Journal of Materials Research
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    • v.13 no.10
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    • pp.691-696
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    • 2003
  • To improve the photocatalyticactivity of $TiO_2$-coated coal fly ash, tungsten hydroxide was doped by impregnation method and was oxidized by heat treatment in temperature ranges of $WO^{\circ}C$ for 2 hrs. The changes of crystal structure and crystal size of $TiO_2$and $WO_3$on coal fly ash were investigated by X-ray diffraction analysis. The crystal structure of titanium dioxide showed only anatase type and $TiO_2$-$WO_3$ compounds appeared in the heat treatment temperature ranges of $500∼600^{\circ}C$. By adding $V_3$in $TiO_2$coated on fly ash, the growth of crystal size of anatase was restrained and the anatase phase was stabilized in temperature ranges of TEX>$500∼<800^{\circ}C$. And $WO_3$acted as a trap site of electrons excited from anatase by irradiating UV. The maximum removal efficiency of NO gas for $TiO_2$/$WO_3$-coated coal fly ash was 84% and appeared when the ammonium tungstate of $1.3${\times}$10^{-3}$ M was doped and then heated at $600^{\circ}C$ for 2 hrs.

Electron Microscopic Study on the Hemocytes of the Wolf Spider, Pardosa astrigera (별늑대거미(Pardosa astrigera L. Koch) 혈구의 전자현미경적 연구)

  • Chang, Byung-Soo;Yoe, Sung-Moon
    • Applied Microscopy
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    • v.25 no.2
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    • pp.29-38
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    • 1995
  • The fine structure of the hemocytes in Wolf spider, Pardosa astrigera, is discribed and compared with that of similar cells in other spider species and insects. Five hemocyte types are identified in the hemolymph: prohemocyte, plasmatocyte, granulocyte, spherulocyte and adipohemocyte. Prohemocytes are small with a relatively undifferentiated cytoplasm. The nucleus is comparatively large and has a perinuclear space. Plasmatocytes and granulocytes are pinocytotic function in the hemolymph of the body. The plasmatocytes have some coated pits on the plasma membrane and well developed Golgi complex, The granulocytes appear sequence of events in the formation of coated vesicle from a coated pit on its plasma membrane. Golgi complex become well expressed and give rise to small secretory vesicles which fuse to large bodies. The spherulocytes are larger in cell size than other hemocytes. Their cytoplasm is filled with spherules. The spherules contain the floccurent materials and the helical structured materials, which are 220nm in length and 80nm in width. The adipohemocytes are oval shaped and have a number of lipid droplets.

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Adsorption of Hydrophobic Organic Compounds from Aqueous Solution with CTAB Coated Silicate (CTAB가 코팅된 Silicate을 이용한 소수성 유기물질의 흡착)

  • 김학성;정영도;한훈석
    • Journal of environmental and Sanitary engineering
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    • v.10 no.3
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    • pp.78-84
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    • 1995
  • Cationic surfactants can be used to modify surface of solids to promote adsorption of hydrophobic organic compounds. This behavior is due to the surfactant forming aggregate structure on the solid surface. Partition coefficients are commonly used to quantify the distribution of organic pollutants between the aqueous and particulate phases of aquatic system Partitioning of hydrophobic compounds to cetyltrimethylammonium bromide ( CTAB ) coated silicate has been investigated as a function of surfactant surface coverage at I=0 and 0.1 ionic strength. Toluene, Xylene, TCI sorption experiments demonstrated that the CTAB coated silicate was able to remove these hydrophobic organic compounds from solution The hydrophobic organic compound with the higher Kow had higher removals than lowest Kow hydrophobic organic compound.

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Thermo-Mechanica1 Stress Analyses of Part with Coated Layer under Contact Load Using Partial Model (부분 모델을 이용한 접촉하중을 받는 코팅층이 있는 부재의 열적/기계적 응력해석)

  • 권영두;김석삼;신세현;추상우
    • Tribology and Lubricants
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    • v.18 no.3
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    • pp.228-234
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    • 2002
  • Generally, space structures are subjected to severe situations, such as, sublimation, strong evaporation of lubricants, thermal stresses, high temperature gradients, irradiation, impacts by microscopic meteorites, and other factors. Recent]y, various kinds of coatings are applied to the parts under heavy contact stresses, in order to insure long wear-free lives and/or reduce friction coefficients. In space structures, molybdenum disulfide is using frequently. Moreover TiN, Al$_2$O$_3$, PTFE(Poly Tetra Fluor Ethylene) are introduced recently for space structure. In this part we are going to apply the partial model method, developed in reference[11] to analyze part with coated layer. In referencer[l1], we compute the reasonable size of partial model and aspect ratio. Using these data, we analyze the structures coated with TiN, Al$_2$O$_3$, PTFE under contact load, temperature and crack model . Beside, we consider the stress analysis under time dependent load and transient thermal effect.

Photocatalytic Reactivity of Titanium Dioxide in the Removal of Benzene from Air (공기중의 벤젠제거에 대한 산화티타늄 광촉매 반응특성)

  • 박달근
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.4
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    • pp.389-398
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    • 2000
  • Photocatalytic removal of benzene from air was examined using titanium dioxide photocatalyst films prepared on soda lime glass(50$\times$50$\times$2 mm) by spin coating and chemical vapor deposition. For the measurement of photocatalytic reactivity titanium dioxide coated glass was placed into a batch reactor and concentration of benzene in the reactor was set to abuot 100 ppm, and then illuminated with UV. It was found that catalytic reactivity of titanium dioxide films increased with the increase of titanium dioxide film thickness and then level off beyond a certain film thickness. UV absorption by the films showed the similar trend. The formation of stoichiometric amount of carbon dioxide was confirmed by measurement of carbon dioxide concentration in the reactor. In general spin coated films revealed better photocatalytic reactivity than chemically deposited one within the experimental ranges covered in this study. Morphology and crystal structure of prepared films were investigated by XRD and SEM and they showed significant difference between spin coated films and CVD films. Highest quantum efficiency of prepared titanium dioxide photocatalyst was close to 50%.

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Surface Protection Technique for Durability Improvement of Concrete Structure (내구성 증진을 위한 콘크리트 구조물의 표면보강 방법)

  • Jin, Nan-Ji;Yeon, Kyu-Seok;Joo, Myung-Ki;Baek, Jong-Man;Lee, Youn-Su
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2002.10a
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    • pp.169-172
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    • 2002
  • In this study, the effects of the number of coat and immersion period on strength properties, waterproofness and chemical resistance of painted and immersed cement mortars using two admixture were examined. Test results showed that the flexural and the compressive strengths of the coated and immersed cement mortars increase with increasing number of coat and immersion period. The water absorption of the coated and immersed cement mortars tended to decrease with increasing number of coated and immersion period. In the case of the change of weight and the immersion period for the solutions, a decreasing tendency was shown as the immersion period increases regardless of solution, with a little variation.

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