• Journal of the Korean Ceramic Society
• /
• v.53 no.4
• /
• pp.435-443
• /
• 2016

Coal ash, a material generated from coal-fired power plants, can be classified as fly ash and bottom ash. The amount of domestic fly ash generation is almost 6.84 million tons per year, while the amount of bottom ash generation is 1.51 million tons. The fly ash is commonly used as a concrete admixture and a subsidiary raw material in cement fabrication process. And some amount of bottom ash is used as a material for embankment and block. However, the recyclable amount of the ash is limited since it could cause deterioration of physical properties. In Korea, the ashes are simply mixed and used as a replacement material for cement. In this study, an attempt was made to mechanically activate the ash by grinding process in order to increase recycling rates of the fly ash. Activated fly ash was prepared by controlling the mill types and the milling times and characteristics of the mortar containing the activated fly ash was analyzed. When the ash was ground by using a vibratory mill, physical properties of the mortar mixed with such fly ash were higher than the mortar mixed with fly ash ground by a planetary mill.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2001.05a
• /
• pp.275-280
• /
• 2001

Recycling of coal combustion by-product(Ash) are becoming more improtant in the utilization business as a result of the increased use of NOx reduction technologies at coal-fired power plants. current disposal methods of these by-products create not only a loss of profit for the power industry, but also environmental concerns that breed negative public opinion. Since inherent characteristics make these by-product suitable for building materials, several types of artificial aggregates and construction bricks are manufactured and tested to verify the engineering properties.

• Advances in concrete construction
• /
• v.5 no.3
• /
• pp.289-301
• /
• 2017

The synergistic interactions of supplementary cementitious materials (SCMs) with ordinary portland cement (OPC) in multi-blended systems could enhance the mechanical and durability properties of concrete and increase the amount of cement that can be replaced. In this study, the characteristics of the hydration products as well as paste microstructure of blended cement containing 20% coal fly ash, 10% rice hull ash and 10% sugar mill lime sludge in quaternary blended system was investigated. Portlandite content, hydration products, compressive strength, pore size distribution and microstructural architecture of hydrated blended cement pastes were examined. The quaternary blended cement paste showed lower compressive strength, reduced amount of Portlandite phases, and higher porosity compared to plain hardened cement paste. The interaction of SCMs with OPC influenced the hydration products, resulting to the formation of ettringite and monocarboaluminate phases. The blended cement paste also showed extensive calcium silicate hydrates and calcium aluminate silicate hydrates but unrefined compared to plain cement paste. In overall, the expected synergistic reaction was significantly hindered due to the low quality of supplementary cementitious materials used. Hence, pre-treatments of SCMs must be considered to enhance their reactivity as good quality SCMs can become limited in the future.

• Journal of the Korean Ceramic Society
• /
• v.45 no.7
• /
• pp.395-400
• /
• 2008

This paper indicates the investigation about the development of ET (Environmental Technology) industrial geopolymeric materials from mixture silica mine waste, coal fly ash and alkali activator solution (sodium silicate) by the geopolymer technique at ambient temperature. The results showed that higher compressive strength of geopolymeric mortar increased with a reduce of L/S ratio and increased along with an increase of coal fly ash content. The compressive strengths of geopolymer mortar on low silica of C Silica Mine and K Silica Mine are 18.7 MPa, 20.4 MPa, respectively. Compressive strength of geopolymeric mortar depends on L/S ratio and coal fly ash content added.. Additionally, scanning electron microscope (SEM) techniques are used to characterize the microstructure of the geopolymeric mortars. SEM observation shows that it is possible to have amorphous aluminosilicate gel within mortar. XRD patterns indicate the fact that geopolymeric mortar is composed of amorphous aluminosilicate phase, calcite and quartz.

• Journal of the Architectural Institute of Korea Structure & Construction
• /
• v.36 no.1
• /
• pp.155-162
• /
• 2020

The aim of the research is to investigate the fundamental properties and heat of hydration reducing performance of the fly ash incorporated concrete mixture when the coal gas slag (CGS) from integrated gasification combined cycle (IGCC) is used as fine aggregate. From the results of the experiment, the workability was generally increased and the air content was decreased up to one to four percent with increasing the replacing ratio of CGS to fine aggregate. The compressive strength was similar or increased within five percent to the Plain mixture when the CGS was used as a fine aggregate. When the CGS and fly ash were used same time, the heat of hydration reducing performance was improved than single using cases either CGS or fly ash. Based on the results, for the concrete mixture using CSG as a portion of the combined fine aggregate, the general properties were improved and heat of hydration was decreased approximately 16 % when the fly ash was replaced 30 % to cement and the CGS was replaced less than 50 % to fine aggregate.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.7 no.1
• /
• pp.43-52
• /
• 1999

This study was carried out to investigate how much coal fly ash could be substituted for sawdust as a bulking agent for livestock waste composting. The mixtures of coal fly ash and sawdust in the weight ratio of 8 to 2, 7 to 3, 6 to 4, 5 to 5, 4 to 6, 3 to 7 and 2 to 8 were added to livestock waste as the bulking agent. The same amount of the bulking agents and livestock waste was mixed and composted during 21 days. Following effects were analyzed during composting experiment : the variation of temperature, pH and various compound contents. The results were summarized as follows: The more the sawdust was added, the higher the maximum temperature in slurry type livestock farm but faster it reached in scrapper type. Water content was maintained under good condition by adding the bulking agent mixed of the same amount of coal fly ash and sawdust. pH was in the range of 7~10 by adding the bulking agent mixed of the same amount of coal fly ash and sawdust. The more the sawdust was added, the higher organic matter content was measured. Nitrogen content with increasing the amount of sawdust added but it was higher did not showed any tendency Organic matter/Nitrogen ratio reduced during the composting period in scrapper type but it showed contrary tendency in slurry type with that of scrapper type.

• Clean Technology
• /
• v.19 no.4
• /
• pp.423-429
• /
• 2013

This study aimed to develop flowable backfill material using oyster shell, coal ash, and surplus soil. The high temperature (> $800^{\circ}C$) reaction was required to convert $CaCO_3$ to CaO. The solid specimens formed by pozzlanic reaction between CaO and coal ash showed low unconfined compressive strength. The effect of kaolin and blast furnace slag was also examined. It was found that CaO and coal ash could not be utilized due to high cost and low performance. The use of oyster shell without calcination ($CaCO_3$) was evaluated. The specimens composing of oyster shell and cement showed the higher unconfined compressive strength than that composing of coal ash and cement. However, use of oyster shell is limited in mortar due to the presence of salt. Addition of soil into oyster shell-coal ash-cement mixture satisfied the specification of flowable backfill material by optimizing their ratio.

• Korean Journal of Environmental Agriculture
• /
• v.24 no.1
• /
• pp.12-16
• /
• 2005

As a silicate source to rice, a coal ash was selected and mixed with phosphor-gypsum (50:50, wt $wt^{-1}$) to reduce the potential of boron toxicity and to supply calcium element. We expected that high con tent of calcium in this mixture might convert water-soluble phosphorus to less soluble forms and then reduce the release of soil phosphorus to surface runoff. The mixture was applied with the rate of 0, 20, 40, and 60 Mg $ha^{-1}$ in paddy soil (Nagdong series, a somewhat excessively drained loamy fine sand) in Daegok, Jinju, Korea The mixture reduced significantly water-soluble phosphorus (W-P) in the surface soils by shifting from W-P and Fe-P to Ca-P and Al-P during whole rice cultivation. In contrast with W-P, plant available phosphorus increased significantly with the mixture application due to high content of phosphorus and silicate in the mixture. The mixture of coal ash and phosphor-gypsum (50:50, wt $wt^{-l}$) would be a good alternative to reduce a phosphorus export in rice paddy soil together with increasing rice yields.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.10 no.1
• /
• pp.125-134
• /
• 1990

In order to utilize coal ash, which we go to great expense to scrap, as subba se course material, this study attempts to examine the deformation characteristics of coal ash with the addition of some cement when repeated loads are applied. The material of coal ash is obtained from Young dong and Youngwol thermal power plant. The results are : Unconfined compression strength shows rectilineal increase in propotion to the cement addition ratio. Within the scope of repeated loads of experimental condition, modulus of elasticity tends to decrease while compression strength shows about 21% increase.

• Journal of Environmental Science International
• /
• v.23 no.12
• /
• pp.1987-1998
• /
• 2014

Zeolite was synthesized from power station waste, coal fly ash, as an alternative low-cost adsorbent and investigated for the removal of Sr(II) and Cs(I) ions from single- and binary metal aqueous solutions. In order to investigate the adsorption characteristics, the effects of various operating parameters such as initial concentration of metal ions, contact time, and pH of the solutions were studied in a batch adsorption technique. The Langmuir model better fitted the adsorption isotherm data than the Freundlich model. The pseudo second-order model was found more applicable to describe the kinetics of system. The adsorption capacities of Sr(II) and Cs(I) ions obtained from the Langmuir model were 1.7848 mmol/g and 0.7640 mmol/g, respectively. Although the adsorption capacities of individual Sr(II) and Cs(I) ions was less in the binary-system, the sum of the total adsorption capacity (2.3572 mmol/g) of both ions in the binary-system was higher than the adsorption capacity of individual ion in the single-system. Comparing the homogeneous film diffusion model with the homogeneous particle diffusion model, the adsorption was mainly controlled by the particle diffusion process.