• 한국지반환경공학회 논문집
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• 제8권6호
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• pp.85-95
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• 2007

탄질 셰일 파쇄대의 경우, 물리탐사의 사전조사방법으로 그 여부를 파악하기 어렵고 또한, 용수등에 노출이 안되는 경우 탄질 셰일층 강도 자체는 양호한 특성이 있다. 그러나 이러한 탄질 셰일층의 경우 용수에 접하거나 대기에 노출되는 경우 단기간내에 강도가 급격히 저하되거나 풍화가 급속히 진전되는 매우 취약한 특성이 있다. 따라서 사전 예측하기가 어렵고 붕락발생시 급작스럽게 발생하는 경우가 대부분이다. 강도감소 측면에서는 용수와 접할시, 탄층 세일 파쇄대층에 대한 점하중 강도 시험결과 12시간 경과후 강도가 56%감소하였다. 또한 본 논문에서는 탄질 셰일 파쇄구간에 대한 표준 보강단면을 제시하였다.

• 자원환경지질
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• 제30권5호
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• pp.417-431
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• 1997

Characteristics of sedimentary rocks and enrichment of toxic elements in shale and coal from the Chungnam coal field were investigated based upon geochemistry of major, trace and rare earth elements. Shale and coal of the area are interbedded along the Traissic to the Jurassic Daedong Supergroup, which can be subdivided into grey shale, black shale and coal. The coal had been mined, however all the mines are abandonded due to the economic problems. The shale and coal are characterized by relatively low contents of $SiO_2$, and $Al_2O_3$ and high levels of loss-on-ignition (LOI), CaO and $Na_2O$ in comparison with the North American Shale Composite (NASC). Light rare earth elements (La, Ce, Yb and Lu) are highly enriched with the coal. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in shale and coal range from 30.0 to 351.8 and from 4.2 to 106.8, which have partly negative correlations against $SiO_2/Al_2O_3$ (1.24 to 6.06), respectively. Those are suggested that controls of mineral compositions in shale and coal can be due to substitution and migration of those elements by diagenesis and metamorphism. Shale and coal of the area may be deposited in terrestrial basin deduced from high C/S (39 to 895) and variable composition of organic carbon (0.39 to 18.40 wt.%) and low contents of reduced sulfur (0.01 to 0.05 wt.%). These shale and coal were originated from the high grade metamorphic and/or igneous rocks, and the rare earth elements of those rocks are slightly influenced with diagenesis and metamorphism on the basis of $Al_2O_3$ versus La, La against Ce, Zr versus Yb, the ratios of La/Ce (0.38 to 0.85) and Th/U (3.6 to 14.6). Characteristics of trace and rare earth elements as Co/Th (0.07 to 0.86), La/Sc (0.31 to 11.05), Se/Th (0.28 to 1.06), V/Ni (1.14 to 3.97), Cr/V (1.4 to 28.3), Ni/Co (2.12 to 8.00) and Zr/Hf (22.6~45.1) in the shale and coal argue for inefficient mixing of the simple source lithologies during sedimentation. These rocks also show much variation in $La_N/Yb_N$ (1.36 to 21.68), Th/Yb (3.5 to 20.0) and La/Th (0.31 to 7.89), and their origin is explained by derivation from a mixture of mainly acidic igneous and metamorphic rocks. Average concentrations in the shale and coal are As=7.2 and 7.5, Ba=913 and 974, Cr=500 and 145, Cu=20 and 26, Ni=38 and 35, Pb=30 and 36, and Zn=77 and 92 ppm, respectively, which are similar to those in the NASC. Average enrichment indices for major elements in the shale (0.79) and coal (0.77) are lower than those in the NASC. In addition, average enrichment index for rare earth elements in coal (2.39) is enriched rather than the shale (1.55). On the basis of the NASC, concentrations of minor and/or environmental toxic elements in the shale and coal were depleted of all the elements examined, excepting Cr, Pb, Rb and Th. Average enrichment indices of trace and/or potentially toxic elements (As, Cr, Cu, Ni, Pb, U and Zn) are 1.23 to 1.24 for shale and 1.06 to 1.22 for coal, respectively.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2009년도 춘계 학술발표회
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• pp.1171-1182
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• 2009

The purpose of this case study is stability security in Talus and Coal Shale. The failure possibility of Talus area is high because of ground loss. The Coal Shale area is very week and large scale sliding possibility is high.

• 자원환경지질
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• 제8권3호
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• pp.135-146
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• 1975

The chiastolite bearing shale was known to occur in various coal fields in South Korea among which the Kangneung coal fields is the most outstanding in quality and quantity of chiastolite. The chiastolite occurs mostly in black shales of Sadong formation and little in shales of Hongjom and Kobangsan formations, and is most abundant in the footwall coaly shales of the Sadong coal seams. The chiastolite has been proved to be thermal contact product of the high aluminous shale that comes into contact with Kangneung granite. The distribution of chiastolite in the Kangneung coal field is irregular. The eastern part of the region contains more chiastolite than that of western part. It is believed that the difference of the grade is due to the intensity of metamorphism. The grade of chiastolite in the shale varies from few percent up to as high as 60 % in volume, and the minable reserve of the chiastolite is estimated about 4,700,000 tons. This reserves is rather concentrated in few localities such as in Jiam Mine, Jungrim Mine, Sir 1 Hang in the Whasung Mine, the second and third sections of Kangneung Mine and Umbuelri district. The chemical composition of chiastolite bearing coaly shale is $SiO_2$, 35.0%; $Al_2O_3$, 27.0%; $Fe_2O_3$, 0.29%.

• Journal of Astronomy and Space Sciences
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• 제15권1호
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• pp.163-174
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• 1998

To study the origin of organic matter in meteorite, terrestrial rocks which contain or-ganic compounds similar to the ones found in carbonaceous chondrites are studied and compared with Muchison meteorite. Hydrocarbon molecules were extracted by benzene and methanol from bituminous coal and oil shale and the extracts were partitioned into aliphatic, aromatic, and polar fractions by silica gel column chromatography. Carbon isotopic ratios in each fractions were analysed by GC-C-IRMS. Molec-ular compound identifications were carried by GC-MS Engine. Bituminous coal and oil shale show the organic compound composition similar to that of meteorite. Oil shale has a wide range of ${\delta}^{13}C,-20.1%_0~-54.4%_0$ compared to bituminous coal, $-25.2%_0~34.3%_0$. Delta values of several molecular compounds in two terrestrial samples are different. They show several distinct distributions in isotopic ratios compared to those of meteorite; Murchison meteorite has a range of ${\delta}^13C\;from\;-13%_0\;to\;+30%_0$. These results provide interpretation for the source and the formation condition of each rock, in particular alteration and migration processes of organic matter. Especially, they show an important clue whether some hydrocarbon molecules observed in meteorite are indigenous or not.

• Bulletin of the Korean Chemical Society
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• 제12권2호
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• pp.153-156
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• 1991

Three humic acids, two from uranium bearing coal shale and one from the neighbouring limey shale region, are extracted from soils by dissolution in 0.1 M NaOH followed by acid precipitation. After purification cycles, they are characterized for their elemental composition, contents of inorganic impurities, molecular size distribution and proton exchange capacities. The results are compared with the data of reference and aquatic humic acids characterized under the project MIRAGE Ⅱ at TUM and also with other literature data. The proton exchange capacity determined by direct titration, is found to be 3.60 and 2.01 meq/g for coal shale and limey shale humic acids, respectively.

• 한국광물학회지
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• 제28권2호
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• pp.83-93
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• 2015

본 연구는 몽골 돈디고비(Dundgobi)지역에서 채취한 오일셰일과 석탄 시료들의 유기물 기원, 광물조성 및 분광학적 특징에 대해 조사하였다. 채취한 오일셰일 및 석탄시료들은 Rock/Eval과 총유기탄소(Total organic carbon; TOC) 분석을 통해 케로젠(Kerogen) 종류, 수소 함량, 열적 성숙도, 퇴적 환경을 확인하였으며, X-선회절 분석과 분광분석을 이용하여 광물조성을 정의하였다. Rock/Eval과 TOC 분석결과, 에뎀트(Eedemt) 광상에서 채취한 샘플들은 미성숙-성숙 단계의 근원암에 해당하며, 풍부한 수소함량을 보이고, I-형, II-형 and III-형의 케로젠 종류를 가진다. 반면 샤인 어스 쿠닥(Shine Us Khudag) 광상에서 채취한 샘플들의 경우 성숙단계의 근원암으로써, I-형, II/III-형 또는 III-형의 케로젠을 함유하는 잠재성을 가진다. 또한 탄소와 황의 함량에 따르면 두 지점의 퇴적환경은 담수성의 퇴적환경인 것으로 확인되었다. X-선회절 분석으로부터 확인한 오일셰일과 석탄시료들의 광물조성은 석영, 방해석, 고회석, 일라이트, 고령토, 몬모릴로나이트, 아놀소클레이스, 조장석, 미사장석, 정장석, 방비석으로 확인되었다. 가시광선-근적외선-단파적외선 분광분석을 통해 오일셰일 시료로부터 1412 nm, 1907 nm의 점토광물 및 수산화성분에 의한 흡광특성, 2206 nm에서 고령토와 몬모릴로나이트에 의한 흡광특성, 탄산염광물인 고회석에 의한 흡광특성이 2306 nm에서 확인되었다. 그러나 오일셰일의 원격탐사적 탐사를 위해서는 유기물 함량에 따른 분광특성에 대한 연구가 수행되어야 할 것으로 사료된다.

• 한국입자에어로졸학회지
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• 제10권1호
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• pp.19-25
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• 2014

In line with the expected price reduction of natural gas associated with the introduction of shale gas, it is expected that the optimal power mix for the electric power generation be changed. In this study, the reconfigured power mix is estimated with the varying natural gas price by using the Screening Curve Method (SCM). It is found that about 3% and 9% coal in the overall power mix is replaced with natural gas if the natural gas price falls 20% and 40% of the current price, respectively. It is also found that the reconfigured power mixes would provide the reduction of the emissions of air pollutants which are equivalent to 369 and 807 MUS$.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2002년도 추계학술발표회
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• pp.195-199
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• 2002

This study is for know chemistry of the representative soils from Keumsan, its relationships with dissolved compositions, and its absorption relationships within the flora. It has been done for two comparisons: 1) phyllite, shale and granite(PSG), and 2) granite and coal bearing shale(GC). Among the soil leachate of the PSG, cations are mainly low in the phyllite area while anions are mainly low in the granite area. In the soil compositions, Ca and Mg of the beans are high and Na is high in the granite area while Ca and Na of the perilla are high in the granite area and Mg is high in the phyllite area. In th both species, Na for the granite area and Mg for the phyllite area are high while Ca for the shale area is low. Among the flora, shale area shows low Ca and Mg contents while granite area shows slightly high Na contents, regardless the species. Compared with beans, perilla is low in the Mg and high in the Na contents. These relationships show that the contents of the soil leachate do not reflect absorption within the flora. Among the soil leachate of the GC, shale area is high in the most of the elements. Especially, SO$_4$ is over 15 times high In the phyllite area. In the soil, granite area shows high Ca, Na and low Mg contents. In the flora, the Miscanthus sinensis shows high Ca and Mg contents in the granite area while the Artemisia vulgaris shows high Ca, Ca and Mg contents in the shale area. These relationships for contents of the flora and soil leachate suggest that the flora has a different absorption according different species.

• 자원환경지질
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• 제30권2호
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• pp.105-116
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• 1997

This study is for extent of polluted area by acid mine drainage from the Daeseong coal mine, Keumsan. Black shales of the Changri Formation containing the Daeseong coal mine are geochemically similar to those from the North America as well as Europe. Comparing with geochemical compositions and relative ratios, coal bearing and non-coal bearing soils are similar to the stream sediments influenced and not influnced by the acid mine drainage, respectively. These characteristics suggest that acidification of the soils and of the stream sediments are related to the the coal bearing black shale. Soil waters beneath the coal bearing soil have low pH and high cation contents than those beneath non-coal bearing soil, suggestive of extractions of cations with increasing oxidizations within the soils. Surface waters show that those influenced by the acid mine drainage are low pH, and have high $SO_4{^{2-}}$, $Mg^{2+}$, $Fe^{2+}$, Mn and slightly lower DO, suggesting that heavy pollutions have been progressed in these area. Geochemical comparisons between the polluted surface water and adjacent black shales suggest that pollutions of the surface water are related to the black shales.