• Bulletin of the Korean Chemical Society
• /
• v.15 no.9
• /
• pp.762-765
• /
• 1994

Picosecond time-resolved resonance Raman spectroscopy has been used to study the photochemistry of Cr(CO$)_6$ in cyclohexane following photoexcitation at 266 nm. Photodissociative loss of CO is found to occur within our pulse width of ${\leq}$5 ps by probing the 533 c$m^{-1}$ vibrational mode of ground state Cr(CO$)_6$. The subsequent dynamics after photodissociation are interpreted in terms of solvation, vibrational and electronic relaxations. The vibrational relaxation time of 100 ps and 83 ps are observed by monitoring v=O and v=l of the 381 c$m^{-1}$ transient mode, respectively. No evidence was found for solvation and electronic relaxation occurring on a time scale of ${\leq}$5 ps.

• Polymer(Korea)
• /
• v.33 no.3
• /
• pp.198-202
• /
• 2009

Oligo(ethylene terephthalate)(OET), oligo(ethylene succinate-co-terephthalate)(OEST) and oligo(butylene succinate-co-terephthalate)(OBST), which are part of the poly(ethylene terephthalate)(PET) oligomer, were synthesized. Degradation test of oligomers carried out by the presence of lipase PS. There were two objectives in the experiment: first, to measure the weight remaining of the PET oligomer as increasing degradation time, and second to examine the degradation mechanism by analyzing the resulting degraded product. In the synthesis of OEST and OBST, by controlling the feed ratio of both OEST and OBST, we were able to obtain oligomer of different composition ratios. The various composition ratios resulted in oligomer of vastly different thermal properties. We observed that both OEST and OBST were degraded using lipase PS, but as the composition of terephthalic acid was increased, the lipase PS became less effective. We confirmed that the lipase PS easily decomposed polyester of the aliphatic compound.

• Journal of Advanced Navigation Technology
• /
• v.20 no.6
• /
• pp.595-603
• /
• 2016

In the Republic of Korea, the LTE-based public safety (PS-LTE) network is being built for the 700 MHz frequency band. However, the same bands are also assigned to the LTE-based high-speed railway (LTE-R) network. Therefore, it is essential to utilize the co-channel interference management schemes for the coexistence of two LTE networks in order to increase the system throughput and to reduce the user outage probability. In this paper, we focus on the downlink (DL) system for the coexistence of PS-LTE and LTE-R networks by considering non radio access network (RAN) sharing and LTE-R RAN sharing by PS-LTE users (UEs) to analyze the UE throughput. Moreover, we also utilize the cooperative communications schemes, such as coordinated multipoint (CoMP) for the coexistence of PS-LTE and LTE-R networks in order to reduce the UE outage probability. We categorize the coexistence of PS-LTE and LTE-R networks into four different scenarios, and evaluate the performance of each scenario by the important performance indexes, such as UE average throughput and UE outage probability.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.21 no.5
• /
• pp.28-38
• /
• 2020

Semiconductor deposition equipment is an important example of Complex Products and Systems (CoPS) and requires in-depth understanding of user requirements. For this reason, we analyzed and compared users' and producers' perspectives on the quality attributes of semiconductor deposition equipment using the Kano model. The results show that the patterns of users' perspectives were different from those of producers. Out of 22 level-2 quality attributes, producers evaluated all 22 attributes as attractive qualities, but users evaluated only 6 as "attractive," 10 as "indifferent," 2 as "must have," and 4 as "other." Although all quality attributes were attractive for producers, only those related to reliability were attractive or must-have qualities, and all others were "indifferent." This result implies that the perspectives on quality attributes may be different between users and producers, and producers should revise their perspectives and strategies. In addition, the results support the characteristics of CoPS suggested by literature implying that performance is more important than economies of scale and cost reduction. It is suggested that producers of semiconductor deposition equipment strategize their approaches to users by considering the characteristics of CoPS.

• Journal of Korean Library and Information Science Society
• /
• v.47 no.4
• /
• pp.339-358
• /
• 2016

This study is to demonstrate that public libraries help community to become an active 'Community of Practice(CoP)'. In order to prove this hypothesis, 'Libraries Transforming Communities(LTC)' initiative of American Library Association is analyzed. Public libraries participating in LTC program solved problems of communities through making CoPs by librarians as a catalyst. People's recognition about public libraries is altered by the problem-solving practice. The followings are 4-level transforming relationship model of public library and community: Leadership Development for Librarian CoPs; Librarian CoPs for improving library services; Community CoPs with library for solving problems; Community as CoP.

• Knowledge Management Research
• /
• v.15 no.1
• /
• pp.1-19
• /
• 2014

Absorptive capacity is an ability to acquire, assimilate, transform, and apply external knowledge. Since the objectives of communities of practice(CoPs) are to share task-related knowledge and to apply it to operations, individual absorptive capacities of CoP members are one of the most important success factors of CoPs. The study examined the structural relationship among three groups; antecedents of absorptive capacity, absorptive capacity, and the performance of CoPs. The findings are as follows; Goal interdependence, reciprocal altruism, coordination mechanism and socialization mechanism had significant and positive effects on absorptive capacity. In addition absorptive capacity had significant and positive effects on goal attainment and knowledge application of CoP.

• Fire Science and Engineering
• /
• v.33 no.1
• /
• pp.69-75
• /
• 2019

In this study, the combustibility of five types of plastic plates, fiber reinforced plastic (FRP), polystyrene (PS), polycarbonate (PC), polypropylene (PP), and polyvinyl chloride (PVC), were tested using a cone calorimeter (ISO 5660). The PVC plate showed a $44.65kW/m^2$ lower peak heat release rate (HRR) and a $30.97kW/m^2$ lower maximum average rate of heat emission than the other four types of plastics, whereas the PS plate showed a $773.44kW/m^2$ higher peak HRR and $399.14kW/m^2$ higher maximum average rate of heat emission. The PC plate and PS plate showed the highest HRR by a maximum of 3.88 times in $CO_{mean}$ yields, while the PS pate and PP plate showed the highest HRR by a maximum 4.88 times in $CO_{2mean}$ yields. In addition, the smoke performance index (SPI) of the PS plate decreased by 74.81%~95.99%; the smoke growth index (SGI) increased to 76%~300%; the smoke intensity (SI) also increased to 917.73% ~ 9607.57%, and the danger of smoke increased. The PS plate was found to have the highest risk of life damage due to smoke on the thermal and smoke sides.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.10
• /
• pp.1470-1474
• /
• 2003

The dynamics of the tertiary conformation of myoglobin (Mb) after photolysis of carbon monoxide was investigated at 283 K solution by probing amide I and II bands using femtosecond IR absorption spectroscopy. Time-resolved spectra in the amide region evolve with 6-12 ps time scale without noticeable subpicosecond dynamics. The spectra measured at 100 ps delay after photolysis is similar to the difference FTIR spectrum at equilibrium. Time-resolved spectra of photoexcited Mb evolve modestly and their amplitudes are less than 8% of those of photolyzed MbCO, indicating that thermal contribution to the spectral evolution in the amide region is negligible. These observations suggest that the conformational relaxation ensuing photolysis of MbCO be complex and the final deoxy protein conformation have been substantially formed by 100 ps, probably with 6- 12 ps time constant.

• Bulletin of the Korean Chemical Society
• /
• v.15 no.2
• /
• pp.126-132
• /
• 1994

RhCl [P($C_6H_5)_3]_3$ complexes have been incorporated in polysulfone (PS) as a dispersion medium using cosolvent (THF). The interactions between Rh(Ⅰ) complexes and polysulfone polymer molecules are examined by infrared spectroscopy and thermal analysis. The chemical reactivity of Rh in PS films has been investigated by reacting Rh sites with CO, $H_2,\;D_2,\;O_2\;NO,\;C_2H_2\;and\;C_2H_4$ in the temperature range $25-200^{\circ}C$. Various Rh-carbonyl, -hydride and -nitrosyl species formed in PS films are characterized by their infrared spectra. Rh complexes in PS film show interesting catalytic reactivities in the reactions such as hydrogenation of $C_2H_2\;and\;C_2H_4$, oxidation of CO, and reduction of NO by CO or $H_2$ gas under relatively mild conditions.

• Fire Science and Engineering
• /
• v.32 no.3
• /
• pp.8-13
• /
• 2018

It was conceived from the realization that there was a lack of studies on the fire risk compared to utility and importance of plastic which is widely used. In this study, the fire hazard of five types of plastic products was measured by Cone Calorimeter (ISO 5660-1). As a result, the time to ignition (TTI) of polyvinyl Chloride (PVC) plate delayed TTI (196 s), and polystyrene (PS) plate had the shortest TTI of 19 s. The total heat release (THR) of PS plate was measured at 213.07 % higher than the lowest measured PVC plate. Also, the PS plate will have 1.45 to 4.21 times higher $CO_2$ than other plastics, resulting in the highest incomplete combustion and the greatest possible damage of life. Thus, assessing the risk of fire revealed that PS plate is the most dangerous and PVC is the safest.