• Title/Summary/Keyword: Co2 decomposition

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Effects of Gas Generation due to Biodegradation on Long-term Landfill Settlement (매립장의 생분해로 인한 가스발생이 장기 침하에 미치는 영향)

  • Ahn, Tae-Bong;Chin, Han-Gyu;Han, Woon-Woo
    • Journal of the Korean GEO-environmental Society
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    • v.6 no.1
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    • pp.5-13
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    • 2005
  • The conventional settlement prediction method is not appropriate to model landfill settlement because it is very complex phenomenon. Biodegradation needs to be considered for long-term settlement since landfills are comprised of various organic materials and soils. As organic materials are decomposed, they directly influences on settlement producing LFG(Landfill Gas). Therefore, mathematical settlement prediction model is proposed based on the generated gas volume. As one of stabilization methods, leachate recycling system is adopted to model tests. Two model tests; one is leachate recycled, the other is non-recycled, are componented with proposed model and analysed regarding gas generation and settlement. The proposed mathematical model requires correction coefficients of 1.4 and 1.7 for non-recycled model and recycled, respectively. The recycled model showed 22% increase of long-term settlement more than the non-recycled model.

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Preparation of Polyethylene Foam Sheets Crosslinked by Gamma-ray Irradiation (감마선 조사에 의하여 가교된 폴리에틸렌 발포 시트의 제조)

  • Lee, Dong-Hoon;Choi, Jun-Ho;Shim, Ki-Hyung;Jung, Chan-Hee;Hwang, In-Tae;Choi, Jae-Hak
    • Journal of Radiation Industry
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    • v.6 no.3
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    • pp.211-215
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    • 2012
  • In this study, crosslinked polyethylene (PE) foam sheets were prepared through gamma-ray irradiation. PE foam sheets were prepared through a foaming process using sodium bicarbonate as a blowing and foaming agent. The prepared PE foam sheets were then crosslinked through gamma-ray irradiation. The crosslinking degree was increased to 86.0% with an increase in the absorption dose. The tensile strength of the crosslinked PE foam sheets was increased with an increase in the absorption dose. However, the elongation-at-break of the crosslinked PE foam sheets was decreased. The thermal decomposition temperature of the crosslinked PE foam sheets was increased to $421.2^{\circ}C$ with an increase in the absorption dose. The SEM analysis revealed that the morphology was not changed significantly after the crosslinking through gamma-ray irradiation.

Crystallinity Changes Heat Treatment of Coal Tar Pitch and Phenol Resin used as a Binder for Bulk Graphite Manufacturing (벌크흑연 제조를 위한 결합재로 이용되는 콜타르 핏치 및 페놀수지의 열처리에 의한 결정성 변화)

  • Lee, Sang-Min;Lee, Hyun-yong;Lee, Sang-Hye;Roh, Jae-Seung
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.174-179
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    • 2021
  • The coal tar pitch and phenol resins are used as binders in artificial graphite manufacture, but there are differences in the initial carbon compound structure. According to the carbonization temperature, it can be expected that there are differences in thermal decomposition behavior, microstructure, and crystallinity change. These properties of the coal tar pitch and phenol resins were compared to each other. As the carbonization temperature of coal tar pitch and phenol resin increases, crystallinity tends to increase. The coal tar pitch went through the carbonization process through the liquid, and it was confirmed that the crystallinity changed rapidly in the temperature range of 500 and 600 ℃, where the microstructure changed quickly. These results confirmed the close correlation between microstructure and crystallinity.

Does the Agricultural Ecosystem Cause Environmental Pollution in Azerbaijan?

  • Elcin Nesirov;Mehman Karimov;Elay Zeynalli
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.617-632
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    • 2022
  • In recent years, environmental pollution and determining the main factors causing this pollution have become an important issue. This study investigates the relationship between the agricultural sector and environmental pollution in Azerbaijan for 1992-2018. The dependent variable in the study is the agricultural greenhouse gas emissions (CO2 equivalent). Eight variables were selected as explanatory variables: four agricultural inputs and four agricultural macro indicators. Unit root tests, ARDL boundary test, FMOLS, DOLS and CCR long-term estimators, Granger causality analysis, and variance decomposition analyses were used to investigate the effect of these variables on agricultural emissions. The results show that chemical fertilizer consumption, livestock number, and pesticide use positively and statistically significantly affect agricultural emissions from agricultural input variables. In contrast, agricultural energy consumption has a negative and significant effect. From agricultural macro indicator variables, it was found that the crop and animal production index had a positive and significant effect on agricultural emissions. According to the Granger causality test results, it was concluded that there are a causality relationship from chemical fertilizer consumption, livestock number, crop and livestock production index variables towards agricultural emissions. Considering all the results obtained, it is seen that the variables that have the most effect on the increase in agricultural emissions in Azerbaijan are the number of livestock, the consumption of chemical fertilizers, and the use of pesticides, respectively. The results from the research will contribute to the information on agricultural greenhouse gas emissions and will play an enlightening role for policymakers and the general public.

A grid-line suppression technique based on the nonsubsampled contourlet transform in digital radiography

  • Namwoo Kim;Taeyoung Um;Hyun Tae Leem;Bon Tack Koo;Kyuseok Kim;Kyu Bom Kim
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.655-668
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    • 2023
  • In radiography, an antiscatter grid is a well-known device for eliminating unexpected x-ray scatter. We investigate a new stationary grid artifact suppression method based on a nonsubsampled contourlet transform (NSCT) incorporated with Gaussian band-pass filtering. The proposed method has an advantage that extracts the Moiré components while minimizing the loss of image information and apply the prior information of Moiré component positions in multi-decomposition sub-band images. We implemented the proposed algorithm and performed a simulation and an experiment to demonstrate its viability. We did this experiment using an x-ray tube (M-113T, Varian, focal spot size: 0.1 mm), a flat-panel detector (ROSE-M Sensor, Aspenstate, pixel dimension: 3032 × 3800 pixels, pixel size: 0.076 mm), and carbon graphite-interspaced grids (JPI Healthcare, 18 cm × 24 cm, line density: 103 LP/inch and 150 LP/inch, ratio: 5:1, focal distance: 65 cm). Our results indicate that the proposed method successfully suppressed grid artifacts by reducing them without either reducing the spatial resolution or causing negative side effects. Consequently, we anticipate that the proposed method can improve image acquisition in a stationary grid x-ray system as well as in extended x-ray imaging.

Pyrolysis Characteristics of CCL(Copper Clad Laminate) Based Paper/Phenolic Resin Composites (종이/페놀수지가 주성분인 동박적층판(Copper Clad Laminate)의 열분해 특성)

  • Song, Jae-Hun;Kim, Seung-Do;Ahn, Hyun-Cheol;Kim, Gyung-Soo;Kim, Sang-Bum;Jung, Jae-Sung;Gong, Sung-Ho;Cho, Young-Gae
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.9
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    • pp.1013-1019
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    • 2007
  • Electronic wastes have increased tremendously. However, any reliable treatment methodologies have rarely been established. Electronic wastes have posed serious disposal problem due to their physico-chemical stability. This paper investigated the application possibility of pyrolysis for the purpose of recycling the p-CCL(phenol based Copper Clad Laminate). Thermogravimetric analysis(TGA) was used to investigate the thermal decomposition pattern of p-CCL. We elucidated the characteristics of pyrolysis by-products at operating temperatures of 280, 350 and $600^{\circ}C$. GC/MS and FT-IR were used to characterize the liquid by-products along with general characterization methods such as Ultimate Analysis, Proximate Analysis and Heating Value, whereas general characterization methods were only introduced for the solid by-products. At a heating rate of $5^{\circ}C$/min, TGA curves exhibited three decomposition stages: (1) low-temperature decomposition region$(<280^{\circ}C)$, (2) medium temperature region$(280\sim350^{\circ}C)$ and (3) high-temperature region$(>350^{\circ}C)$. The major compounds of liquid by-products at low- and medium-temperatures were accounted for by water and phenol, whereas branched phenols and furans were major compounds at high-temperatures. As the temperature increases, volatile quantities decreased but the fixed carbon increased. High heating values of solid by-products($7,400\sim7,600$ kcal/kg) would suggest that the solid by-products could be applicable as fuel. In addition, high fixed carbon but low ash content of the solid by-products offered an implication that they are capable of being upgradable for adsorbent after applying appropriate activating process.

Removal of Mixed Odor(H$_2$S/CH$_3$SH) using Char Adsorbent Made from Sewage Sludge (하수슬러지 탄화물 흡착제를 이용한 혼합 악취(H$_2$S/CH$_3$SH)의 제거)

  • Han, Young-Suk;Choi, Won-Joon;Kim, Taek-Joon;Kim, Im-Gyung;Oh, Kwang-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1132-1138
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    • 2008
  • The study was carried out to investigate adsorption characteristic on hydrogen sulfide (H$_2$S) and methylmercaptan (CH$_3$SH) odor gas using the char made by a thermal decomposition of sewage sludge. The fixed bed adsorption experiments of the optimum L/D ratio could be 1.0, and adsorption capacity and break point increased with the increase of temperature. A simultaneous adsorption characteristic of H$_2$S and CH$_3$SH increased in breakthrough time and adsorption capacity more than single adsorption experiment, and CH$_3$SH had higher effective diffusivities than H$_2$S in same condition. The adsorption capacity of CH$_3$SH increased with fast velocity. When it was compared the produced absorbent with commercial activated carbon, As to adsorbent amount, it was H$_2$S 77% and CH$_3$SH 80% of commercial activated carbon.

Effect of Lithium Bis(oxalate)borate as an Electrolyte Additive on Carbon-coated SiO Negative Electrode (탄소가 코팅된 일산화규소(SiO) 음극에서 전해질 첨가제로서 Lithium Bis(oxalato)borate의 영향)

  • Kim, Kun Woo;Lee, Jae Gil;Park, Hosang;Kim, Jongjung;Ryu, Ji Heon;Kim, Young-Ugk;Oh, Seung M.
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.49-56
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    • 2014
  • As an electrolyte additive, the effects of lithium bis(oxalate)borate (LiBOB) on the electrochemical properties of a carbon-coated silicon monoxide (C-coated SiO) negative electrode are investigated. The used electrolyte is 1.3M $LiPF_6$ that is dissolved in ethylene carbonate (EC), fluoroethylene carbonate (FEC), and diethyl carbonate (DEC) (5:25:70 v/v/v) with or without 0.5 wt. % LiBOB. In the LiBOB-free electrolyte, the film resistance is not so high in the initial period of cycling that lithiation is facilitated to generate the crystalline $Li_{15}Si_4$ phase. Due to repeated volume change that is caused by such a deep charge/discharge, cracks form in the active material to cause a resistance increase, which eventually leads to capacity fading. When LiBOB is added into the electrolyte, however, more resistive surface film is generated by decomposition of LiBOB in the initial period. The crystalline $Li_{15}Si_4$ phase does not form, such that the volume change and crack formation are greatly mitigated. Consequently, the C-coated SiO electrode exhibits a better cycle performance in the later cycles. At an elevated temperature ($45^{\circ}C$), wherein the effect of film resistance is less critical, the alloy ($Li_{15}Si_4$ phase) formation is comparable for the LiBOB-free and added cell to give a similar cycle performance.

Representation of ambiguous word in Latent Semantic Analysis (LSA모형에서 다의어 의미의 표상)

  • 이태헌;김청택
    • Korean Journal of Cognitive Science
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    • v.15 no.2
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    • pp.23-31
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    • 2004
  • Latent Semantic Analysis (LSA Landauer & Dumais, 1997) is a technique to represent the meanings of words using co-occurrence information of words appearing in he same context, which is usually a sentence or a document. In LSA, a word is represented as a point in multidimensional space where each axis represents a context, and a word's meaning is determined by its frequency in each context. The space is reduced by singular value decomposition (SVD). The present study elaborates upon LSA for use of representation of ambiguous words. The proposed LSA applies rotation of axes in the document space which makes possible to interpret the meaning of un. A simulation study was conducted to illustrate the performance of LSA in representation of ambiguous words. In the simulation, first, the texts which contain an ambiguous word were extracted and LSA with rotation was performed. By comparing loading matrix, we categorized the texts according to meanings. The first meaning of an ambiguous wold was represented by LSA with the matrix excluding the vectors for the other meaning. The other meanings were also represented in the same way. The simulation showed that this way of representation of an ambiguous word can identify the meanings of the word. This result suggest that LSA with axis rotation can be applied to representation of ambiguous words. We discussed that the use of rotation makes it possible to represent multiple meanings of ambiguous words, and this technique can be applied in the area of web searching.

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Effects of Salt and Precursor pH on Synthesizing Behavior and Grain Morphology of Mullite in Aqueous System (수용성 매체에서 뮬라이트의 합성거동 및 입자형상에 미치는 염 및 전구체 pH의 영향)

  • Jung, Yeon-Gil;Lee, Jae-Ean;Shin, Young-Ill;Kim, Jae-Won;Jo, Chang-Yong
    • Korean Journal of Materials Research
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    • v.13 no.4
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    • pp.251-258
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    • 2003
  • The effects of the salt and the precursor pH on the synthesizing behavior and the morphology of mullite have been studied. Two kinds of mullite precursor sols were prepared by the dissolution of two kinds of salt (aluminum nitrate enneahydrate, Al($NO_3$)$_3$$9H_2$O; type I and aluminum sulfate 14∼18 water, (SO$Al_4$)$_3$$\cdot$$14∼18H_2$O; type II) into the mixture of colloidal silica sol, respectively. Precursor pH of the sols was controlled to the acidic (pH= 1.5∼2) and basic (pH= 8.5∼9) conditions. The co-products with nitrate and sulfate were completely eliminated at $500^{\circ}C$ and $850^{\circ}C$, respectively, which was confirmed by TG/DTA results. The synthesizing temperature of mullite phase was found to be above $1200^{\circ}C$ for pH= 1.5∼2 and above $1300^{\circ}C$ for pH= 8.5∼9 in type I. However, in type II, the synthesizing temperature of mullite was decreased to $850^{\circ}C$ for pH= 1.5∼2 and $1100^{\circ}C$ for pH= 8.5∼9. The grain size of the mullite synthesized at pH= 8.5∼9 was larger than that at pH= 1.5∼2 in overall heat-treated temperatures, showing smaller grain size in type II. Aspect ratio of the mullite grains was more increased at pH= 1.5∼2 than pH= 8.5∼9 in type I, showing similar aspect ratio at both pH conditions in type II. It was found that the synthesizing temperature and grain size were predominantly governed by the initial precursor pH and decomposition of the salt, with minor effect on the grain morphology.