• 제목/요약/키워드: Co-polymer

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전기방사에 의한 미생물 합성 생분해성 고분자 섬유의 Oil 흡수 (Oil Absorbencies of Fibers of Biodegradable and Microbial Polymers Prepared by Electrospinning Method)

  • 정의습;이원기;박찬영;민성기;장성호
    • 한국환경과학회지
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    • 제22권2호
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    • pp.243-249
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    • 2013
  • Fibers of microbial polyesters, poly(3-hydroxy butyrate) (PHB) and poly(3-hydroxy butyrate-co-3-hydroxy valerate) (HB-co-HV) were prepared by electrospinning method. The obtained fibers were evaluated by differential scanning calorimetry, scanning electron microscopy, and oil absorption. The formation of fibers was strongly dependent on a concentration of solution. At a low concentration, the fibers contained beads which is from aggregation of polymer due to short evaporation time. The fine fibers with $2-5{\mu}m$ diameter were obtained at 20 wt% concentration. The contact angle measurement showed that the fiber had higher water contact angle than the film due to the lotus-like effect. Oil absorbency showed that the fiber had higher than the film. Specially, the HB-co-HV fiber which was spinned from 20 wt% absorbed 65% oil which is much higher than that of a normal polypropylene-based oil paper.