• 제목/요약/키워드: Co-polymer

검색결과 1,924건 처리시간 0.024초

In vivo 상에서 탈미네랄화된 골분이 함유된 PLGA 지지체를 이용한 추간판 디스크 재생 (Regeneration of Intervertebral Disc Using Poly(lactic-co-glycolic acid) Scaffolds Included Demineralized Bone Particle In Vivo)

  • 장지은;김혜윤;송정은;이동원;권순용;정진화;강길선
    • 폴리머
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    • 제37권6호
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    • pp.669-676
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    • 2013
  • 탈미네랄화된 골분(demineralized bone particle, DBP)은 연골 형성의 유도인자로 사용되기 때문에 조직공학에서 널리 사용되는 생체재료이다. 본 연구에서는 in vivo 환경에서 디스크 재생 효과를 연구하기 위해 DBP를 poly(lactic-co-glycolic acid) (PLGA)에 첨가하여 다공성 지지체를 제조하였다. 디스크의 섬유륜 조직을 반으로 절개한 후, 수핵 조직을 제거하여 디스크 결손을 유발시켰다. 빈 공간에 PLGA, DBP/PLGA 지지체를 이식하여 in vivo 환경에서 조직공학적 디스크 재생을 관찰하였다. 1, 2 및 3개월 후 디스크를 적출하여 글리코스아미노글라이칸(glycosaminoglycan, sGAG) 및 콜라겐 합성 정도를 측정하였으며 조직학적 평가로 H&E, Safranin-O, Alcian blue 염색과 면역조직학적 평가로 제 I형 콜라겐, 제 II형 콜라겐 염색을 수행하였다. 그 결과 DBP/PLGA 지지체에서 sGAG 및 콜라겐 함량이 높은 것을 확인하였으며 추간판 디스크 재생의 가능성을 확인하였다.

기-액(氣-液) 2상유동(二相流動)시 항력(抗力)에 관(關)한 연구(硏究) (The Study on the Drag Reduction for Gas/Liquid Two Phase Flow)

  • 차경옥;오율권;김재근
    • 한국분무공학회지
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    • 제1권3호
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    • pp.20-28
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    • 1996
  • It is well known that drag reduction in single phase liquid flow is affected by polymer material, molecular weight, polymer concentration, pipe diameter, and flow velocity. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research of drag reduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction whether polymer is added in the horizontal two phase system or not. Experiment has been conducted in a test section with 24 m of the inner diameter and 1,500 mm of the length. The used polymer materials are two kinds of polyacrylamide[PAAM] and co-polymer[A611P]. The polymer concentration was varied with 50, 100 and 200 ppm under the same experimental conditions. Experimental results were shown that the drag is higher reduced by co-polymer rather than polyanylamide.

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Ink Jet Printed Full Color Polymer LED Displays

  • Rhee, Jung-Soo;Lee, Dong-Won;Chung, Jin-Koo;Wang, Jian-Pu;Hong, Sang-Mi;Cha, Soon-Wook;Choi, Beom-Rak;Jung, Jae-Hoon;Kim, Nam-Deog;Chung, Kyu-Ha;Gregory, Haydn;Lyon, Peter;Creighton, Colin;Bale, Mark;Carter, Julian
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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    • pp.1046-1049
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    • 2005
  • We have developed polymer LED displays using ink jet printing without visible swathe marks which can be observed during display operation. In addition, we have also developed a single-pass printing technology for hole-conduction layer deposition to significantly reduce the complexity of interlacing printing across the panel which is known as an alternative to remove the swathe mark.

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Integration of solution-processed polymer thin-film transistors for reflective liquid crystal applications

  • Kim, Sung-Jin;Kim, Min-Hoi;Suh, Min-Chul;Mo, Yeon-Gon;Chang, Seung-Wook;Lee, Sin-Doo
    • Journal of Information Display
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    • 제12권4호
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    • pp.205-208
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    • 2011
  • Herein, the integration of solution-processed polymer thin-film transistors (TFTs) that were fabricated using selective wettability through ultraviolet (UV) exposure into a reflective liquid crystal display is demonstrated. From the experimental results of energy-dispersive spectroscopy, the composition of carbon and fluorine enhancing the hydrophobicity in the polymer chains was found to play a critical role in the wetting selectivity upon UV exposure. The polymer TFTs fabricated through the wettability-patterning process exhibited long-term stability and reliability. This wetting-selectivity-based patterning technique will be useful for constructing different types of solution-processed electronic and optoelectronic devices.

Influence of polymer coating on SFCL recovery under load

  • Gorbunova, D.A.;Kumarov, D.R.;Scherbakov, V.I.;Sim, Kideok;Hwang, Soon
    • 한국초전도ㆍ저온공학회논문지
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    • 제21권4호
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    • pp.44-47
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    • 2019
  • This paper is a study of recovery under load process of superconducting fault current limiter (SFCL). SFCL consists of five parallel-connected high-temperature superconductor (HTS) tapes additionally stabilized by stainless tape. Previously, HTS was heated by current pulse to simulate a short circuit in a power grid. During the cooling period, the current amplitude decreased to 23% or less of HTS critical current value, which is the simulation of network re-switching. When HTS with a polymer coating is cooled, temperature gradient on thermal insulation layer occurs, that prevents a boiling crisis and improves the heat sink into liquid nitrogen. Two samples are coated with a 30 ㎛ and 50 ㎛ polylactide (PLA) layers, reference sample has no polymer coating on it. Samples with a polymer coating show 3-5 times faster cooling than the reference one.

Interaction between Poly(L-lysine) and Poly(N-isopropyl acrylamide-co-acrylic acid) in Aqueous Solution

  • Sung, Yong-Kiel;Yoo, Mi-Kyong;Cho, Chong-Su
    • Macromolecular Research
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    • 제8권1호
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    • pp.26-33
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    • 2000
  • A series of pH/temperature sensitive polymers were synthesized by copolymerizing N-isopro-pyl acrylamide(NIPAAm) and acrylic acid(AAc) . The influence of polyelectrolyte between poly(allyl amine) (PAA) and poly(L-lysine)(PLL) on the lower critical solution temperature(LCST) of pH/temperature sensitive polymer was compared in the range of pH 2∼12. The LCST of PNIPAAm/water in aqueous poly(NIPAAm-co-AAc) solution was determined by cloud point measurements. A polyelectrolyte complex was prepared by mixing poly(NIPAAm-co-AAc) with poly(allyl amine) (PAA) or poly(L-lysine) (PLL) solutions as anionic and cationic polyelectrolytes, respectively. The effect of polyelectrolyte complex formation on the conformation of PLL was studied as a function of temperature by means of circular dichroism(CD). The cloud points of PNIPAAm in the aqueous copolymers solutions were stongly affected by pH, the presence of polyelectrolyte solute, AAc content, and charge density. The polyelectrolyte complex was formed at neutral condition. The influence of more hydrophobic PLL as a polyelectrolyte on the cloud point of PNIPAAm in the aqueous copolymer solution was stronger than that of poly(allyl amine)(PAA). Although polymer-polymer complex was formed between poly(NIPAAm-co-AAc) and PLL, the conformational change of PLL did not occur due to steric hinderance of bulky N-isopropyl groups of PNIPAAm.

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Poly(ethylene-co-acrylic acid)의 분산입자 제조와 그 필름의 요소 투과특성 (Urea Diffusional Characteristics of Film from Dispersion Based on Poly(ethylene-co-acrylic acid))

  • 유동국;안정호
    • 폴리머
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    • 제25권1호
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    • pp.90-97
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    • 2001
  • Poly(ethylene-co-acrylic acid) (PEAA)를 암모늄과 나트륨의 두 가지 서로 다른 반대 이온을 사용하여 수분산 하고 이의 필름을 제조하였다. 얻어진 필름에 대한 urea 수용액의 확산계수를 측정하고 필름의 물리, 화학적 구조와의 상관관계를 조사하였다. 측정된 구조적 특징은 DSC에 의한 유리전이온도와 결정화도, WAXD에 의한 결정 및 이온성 클러스터의 구조, 그리고 FT-IR에 의한 carboxyl기의 존재 형태 등이었다. 결정성 고분자인 폴리에틸렌 이오노머의 투과특성은 반대이온의 종류나 중화도는 물론 필름형성시의 조건, 그리고 초기 입자의 크기와 같은 다양한 변수에 영향을 받음을 관찰하였다.

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무색 투명 폴리이미드 공중합체의 합성 및 물성 비교 (Syntheses of Colorless and Transparent Copolyimides and Comparison of the Properties of Their Copolyimides)

  • 주지은;장진해
    • 폴리머
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    • 제39권2호
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    • pp.275-280
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    • 2015
  • 4,4'-Biphthalic anhydride(BPA)와 2,2'-bis(trifluoromethyl) benzidine(TFB)의 구조에 서로 다른 무수물인 4,4'-(hexafluoroisopropylidene) diphthalic anhydride(6FDA)와 1,2,4,5-benzentetra carboxylic dianhydride(pyromellitic dianhydride) (PMDA)를 각각 반응시켜 열적 및 화학적 이미드화 반응을 통해 두 가지 시리즈의 폴리이미드 공중합체(copolyimide, Co-PI)를 합성하였다. 합성한 Co-PI를 각각 다른 두 가지 무수물 단량체의 조성에 따라 열적 성질 및 광학적 투명성을 서로 비교 분석하였다. 열적 성질을 증가시키기 위해서는 6FDA보다는 PMDA가 더 효과적이었으나, 광학 투명성에서는 오히려 6FDA가 더 효과적이었다.

수분저항성 및 방호성능을 가지는 선택투과막 재료의 특성평가 (Characterization of Several Selectively Permeable Membrane Materials with Water Resistance and Protective Performance)

  • 강재성;서현관;권태근;김진원;박현배;이해완
    • 한국군사과학기술학회지
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    • 제16권4호
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    • pp.553-559
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    • 2013
  • We make several membranes with multilayer structure and characterize protective performance in various ways. Multilayer membrane is composed of shell fabric, support membrane, functional polymer membrane and liner fabric. In this research, we apply cellulose acetate derivatives as base polymer in functional polymer membrane and characterize water resistance, water vapor permeation, protective performance against DMMP and aerosol. Test results show that cellulose based polymer with polyethyleneimine possess performance with good water vapor permeation and excellent protective capability against DMMP equivalent to Saratoga type's protective suits. Also, these materials possess aerosol protective performance and water resistance.