• Title/Summary/Keyword: Co-bonded structure

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Microstructure and Permeability Property of Si Bonded Porous SiC with Variations in the Carbon Content (Si 결합 다공성 탄화규소의 미세구조 및 통기도 특성 -카본 함량 변화 중심)

  • Song, In-Hyuck;Park, Mi-Jung;Kim, Hai-Doo;Kim, Young-Wook;Bae, Ji-Soo
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.546-552
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    • 2010
  • The achievement of high gas permeability is a key factor in the development of porous SiC ceramics for applications of hot gas filter, vacuum chuck, and air spindle. However, few reports on the gas permeability of porous SiC ceramics can be found in the literature. In this paper, porous SiC ceramics were fabricated at temperatures ranging from $1600^{\circ}C$ to $1800^{\circ}C$ using the mixing powders of SiC, silicon, carbon and boron as starting materials. In some samples, expanded hollow microspheres as a pore former were used to make a cellular pore structure. It was possible to produce Si bonded SiC ceramics with porosities ranging from 42% to 55%. The maximum bending strength was 58MPa for the carbon content of 0.2 wt% and sintering temperature of $1700^{\circ}C$. The increase of air permeability was accelerated by addition of hollow microsphere as a pore former.

FBG Sensor Probes with Silver Epoxy for Tracing the Maximum Strain of Structures

  • Im, Jooeun;Kim, Mihyun;Choi, Ki-Sun;Hwang, Tae-Kyung;Kwon, Il-Bum
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.5
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    • pp.459-464
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    • 2013
  • Structures can be evaluated their health status by allowable loading criteria. These criteria can be determined by the maximum strain. Therefore, in order to detect this maximum strain of structures, fiber optic Bragg grating(FBG) sensor probes are newly designed and fabricated to perform the memorizing detection even if the sensor system is on-and-off. The probe is constructed with an FBG optical fiber embedded in silver epoxy. When the load is applied and removed on the structure, the residual strain remains in the silver epoxy to memorize the maximum strain effect. In this study, a commercial Al-foil bonded FBG sensor probe was tested to investigate the detection feasibility at first. FBG sensor probes with silver epoxy were fabricated as three different sizes. The detection feasibility of maximum strain was studied by doing the tensile tests of CFRP specimens bonded with these FBG sensor probes. It was investigated the sensitivity coefficient defined as the maximum strain divided by the residual strain. The highest sensitivity was 0.078 of the thin probe having the thickness of 2 mm.

Thermal Behavior of (Co0.5 Mn0.5)Fe2O4 for Hydrogen Generation by Thermochemical Cycle (열화학 사이클 H2 제조를 위한 (Co0.5 Mn0.5)Fe2O4의 열적 거동)

  • Shin, H.C.;Choi, S.C.;Kim, C.S.;Kim, J.W.;Joo, O.S.;Jung, K.D.
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.2
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    • pp.143-150
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    • 2002
  • The thermal behavior of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ prepared by a co-precipitation wasinvestigated for Hz generation by the thermochemical cycle. The reduction reaction of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ started from $480^{\circ}C$, and the weight loss was 1.6 wt% up to $1100^{\circ}C$. At this reaction, $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ was reduced by release of oxygen bonded with the $Fe^{3+}$ ion in the B site of ($CO_{0.5}$ $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$. In the $H_2O$ decomposition reaction, $H_2$ was generated by oxidationof reduced $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$. The crystal structure of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ for reduction reaction maintained spinel structure and the lattice constant of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ ($8.41\AA$) was enlarged to $8.45\AA$. But the lattice constant of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ after $H_2O$ decomposition reaction did not change to $8.45\AA$. Then, $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ is excellent material in the thermochemical cyclic reaction due to release oxygen at low temperature for the reduction reaction and produce $H_2$ maintaining crystal structure for redox reaction.

Smart Actuators Composed of Piezoelectric Ceramics and Highly Magnetostrictive films (압전세라믹 기판과 고자왜박막을 결합한 스마트액츄에이타)

  • Sin, Gwang-Ho;Arai, Ken-Ichi;Sa-Gong, Geon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.5
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    • pp.289-293
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    • 2000
  • This paper presents a study on the linear compensation of nonlinear hysteric actuators using the highly magnetostrictive film pattern as a strain sensor. Elements had a hybrid structure, in which thin soft glass substrate with the highly magnetostrictive amorphous FeCoSiB film was bonded on the PZT piezoelectric substrate. The magnetostrictive film as a strain sensor detects the deflection of an actuator, and a voltage signal from the strain sensor related to the deflection of an actuator is used for the linear control of an actuator.

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Effect of Processing Conditions on the Morphological Structure and Strength Properties of Ultrasonically Laminated Nonwovens (초음파 라미네이트 부직포의 형태구조와 강도특성에 처리조건의 영향)

  • Kang, Jeon-Young;Jeon, Woo-Jin;Joo, Chang-Whan
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.146-149
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    • 2003
  • There are three major bonding types such as chemical bonding, thermal bonding, mechanical bonding to produce nonwoven fabrics. The development of the past few years has shown that the share of thermally bonded webs is growing steadily. The viability of the thermal bonding process is rooted in the price advantage obtained by lower energy costs. However, the thermal bonding process also obtains the quality requirements of the market place. (omitted)

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Synthesis and Crystal Structure of Cyclodimetric Ag(I) Complex with 2,3-Bis(2-pyridyl)pyrazine (고리 이합체 2,3-비스(2-피리딜)피라진(트라이플루오르아세테이토)은(I) 착물의 합성 및 결정 구조)

  • Kim, Yun-Ju;Lee, Young-A;Lee, Uk;Jung, Ok-Sang
    • Korean Journal of Crystallography
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    • v.11 no.1
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    • pp.28-33
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    • 2000
  • The slow of 2,3-bis(2-pyridyl)pyarzine(bpp) with Ag(CF₃CO₂) produces crystalline product suitable for X-ray crystallography. Crystallographic characterization of the crystal (C/sub 32/H/sub 20/-F/sub 6/N/sub 8/O₄Ag₂: triclinic P1, a=8.518(5)Å, b=9.546(2)Å, c=10.632(1)Å, α=81.11(1)°, β=87.61(3)°, γ=75.66(3)°, V=827.5(5)ų, Z=1, R=0.0431) has provided that the complex is a cyclic dimer [Ag(bpp)(CF₃CO₂)]₂. Each bpp ligand connects two tetrahedral silver(I) ions in a tridentate mode (Ag-N, 2.26()-2.43(2)Å), and the trifluoroacetato anion is bonded to each silver(I) atom in a monodentate fashion (Ag-O, 2.38(1); 2.39(2) Å). The skeletal cyclic dimer is stable up to 212℃, and drastically decomposes around this temperature.

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Fabrication of Low-Shrinkage Reaction-Bonded Alumina Ceramics (저수축 반응소결 알루미나 세라믹스의 제조)

  • 박정현;이현권;정경원;염강섭
    • Journal of the Korean Ceramic Society
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    • v.29 no.6
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    • pp.419-430
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    • 1992
  • Fabrication possibility of low-shrinkage alumina without oxidation and wetting agent was presented on the basis of observation about oxidation behavior, microstructure and physical characteristics of such reaction agents free Al2O3-Al system. The composition less than Al 10w/o where Al can act as a sintering agent for Al2O3 was excluded. Under the condition of present experiments oxidation of Al2O3-Al system was dependent not on holding time but mainly on oxidation temperature. In thes case of Al powder not comminuted effectively during powder mixing of Al2O3-Al, columnar structure which would act as a hindrance to the densification during sintering developed more during oxidation with higher Al contents, and which made the fabrication of low-shrinkage Al2O3 ceramics impossible. If Al powder was comminuted effectively due to co-mixed Al2O3 characteristics, densification was improved because of no columnar structure and made the fabrication of sintered body with -2.7% dimensional change and 81% relative density possible. As a result, it is possible to fabricate dense low-shrinkage Al2O3 ceramics without oxidation and wetting agent under conditions such as smaller particle size of Al, Al contents below 50v/o, higher green density of Al2O3-Al compact and the use of Al2O3 powder used for high-density ceramics.

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Monotonic Loading Tests of RC Beam-Column Subassemblage Strengthened to Prevent Progressive Collapse

  • Kim, Jinkoo;Choi, Hyunhoon
    • International Journal of Concrete Structures and Materials
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    • v.9 no.4
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    • pp.401-413
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    • 2015
  • In this study the progressive collapse resisting capacity of a RC beam-column subassemblage with and without strengthening was investigated. Total of five specimens were tested; two unreinforced specimens, the one designed as gravity load-resisting system and the other as seismic load-resisting system, and three specimens reinforced with: (i) bonded strand, (ii) unbonded strand, and (iii) side steel plates with stud bolts. The two-span subassemblages were designed as part of an eight-story RC building. Monotonically increasing load was applied at the middle column of the specimens and the force-displacement relationships were plotted. It was observed that the gravity load-resisting specimen failed by fractures of re-bars in the beams. In the other specimens no failure was observed until the maximum displacement capacity of the actuator was reached. Highest strength was observed in the structure with unbonded strand. The test result of the specimen with side steel plates in beam-column joints showed that the force-displacement curve increased without fracture of re-bars. Based on the test results it was concluded that the progressive collapse resisting capacity of a RC frame could be significantly enhanced using unbonded strands or side plates with stud bolts.

Visualization and classification of hidden defects in triplex composites used in LNG carriers by active thermography

  • Hwang, Soonkyu;Jeon, Ikgeun;Han, Gayoung;Sohn, Hoon;Yun, Wonjun
    • Smart Structures and Systems
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    • v.24 no.6
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    • pp.803-812
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    • 2019
  • Triplex composite is an epoxy-bonded joint structure, which constitutes the secondary barrier in a liquefied natural gas (LNG) carrier. Defects in the triplex composite weaken its shear strength and may cause leakage of the LNG, thus compromising the structural integrity of the LNG carrier. This paper proposes an autonomous triplex composite inspection (ATCI) system for visualizing and classifying hidden defects in the triplex composite installed inside an LNG carrier. First, heat energy is generated on the surface of the triplex composite using halogen lamps, and the corresponding heat response is measured by an infrared (IR) camera. Next, the region of interest (ROI) is traced and noise components are removed to minimize false indications of defects. After a defect is identified, it is classified as internal void or uncured adhesive and its size and shape are quantified and visualized, respectively. The proposed ATCI system allows the fully automated and contactless detection, classification, and quantification of hidden defects inside the triplex composite. The effectiveness of the proposed ATCI system is validated using the data obtained from actual triplex composite installed in an LNG carrier membrane system.

Silver Colloidal Effects on Excited-State Structure and Intramolecular Charge Transfer of p-N,N-dimethylaminobenzoic Acid Aqueous Cyclodextrin Solutions

  • Choe, Jeong Gwan;Kim, Yang Hui;Yun, Min Jung;Lee, Seung Jun;Kim, Gwan;Jeong, Sae Chae
    • Bulletin of the Korean Chemical Society
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    • v.22 no.2
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    • pp.219-227
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    • 2001
  • The silver colloidal effects on the excited-state structure and intramolecular charge transfer (ICT) of p-N,N-dimethylaminobenzoic acid (DMABA) in aqueous cyclodextrin (CD) solutions have been investigated by UV-VIS absorption, steady-state and time-resolved fluorescence, and transient Raman spectroscopy. As the concentration of silver colloids increases, the ratio of the ICT emission to the normal emission (Ia /Ib) of DMABA in the aqueous $\alpha-CD$ solutions are greatly decreased while the Ia /Ib values in the aqueous B-CD solutions are significantly enhanced. It is also noteworthy that the ICT emission maxima are red-shifted by 15-40 nm upon addition of silver colloids, implying that DMABA encapsulated in $\alpha-CD$ or B-CD cavity is exposed to more polar environment. The transient resonance Raman spectra of DMABA in silver colloidal solutions demonstrate that DMABA in the excited-state is desorbed from silver colloidal surfaces as demonstrated by the disappearance of νs (CO2-)(1380 cm-1 ) with appearance of ν(C-OH)(1280 cm -1) band, respectively. Thus, in the aqueous B-CD solutions the carboxylic acid group of DMABA in the excited-state can be readily hydrogen-bonded with the secondary hydroxyl group of B-CD while in aqueous and $\alpha-CD$ solutions the carboxylic acid group of DMABA has the hydrogen-bonding interaction with water. Consequently, in the aqueous B-CD solutions the enhancement of the Ia /Ia value arises from the intermolecular hydrogen-bonding interaction between DMABA and the secondary hydroxyl group of B-CD as well as the lower polarity of the rim of the B-CD cavity compared to bulk water. This is also supported by the increase of the association constant for DMABA/ B-CD complex in the presence of silver colloids.