• 제목/요약/키워드: Co-based amorphous

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MAGNETIC PROPERTIES OF NANOCRYSTALLINE (Fe,Co)-B-Al-M (M=Nb/Mo/Ta) ALLOYS

  • Kang, D.B.;Cho, W.S.;Kim, T.K.;Cho, Y.S.
    • 한국자기학회지
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    • 제5권5호
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    • pp.483-486
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    • 1995
  • Soft magnetic properties of Fe-based (Fe,Co)-B-Al-M (M=Nb, Mo or Ta) nanocrystalline alloy have been investigated. The alloy obtained directly form the rapid solidification process. Microstructure of the alloy is a mixtu re of ultrafine bcc Fe(Co) nanocrystallines and a small amount of retained amorphous phase. Heat treatment of as-prepared alloys improves soft magnetic properties in high frequency range. ${(Fe_{.85}Co_{.15})}_{70}B_{18}Al_{10}Ta_{6}$ alloy alloy annealed at $500^{\circ}C$ for 1 h shows the most improved soth magnetic properties among the alloy examined. Average grain size of the nanocystalline is about 10 nm.

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Zr기지 비정질 합금 스크랩의 비정질 형성능 및 기계적 성질에 미치는 산소함량의 영향 (The Effect of Oxygen Content on the Glass Forming Ability and Mechanical Properties of the Zr-based Amorphous Alloy Return Scrap)

  • 김성규;이병철;박흥일
    • 한국주조공학회지
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    • 제35권4호
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    • pp.75-79
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    • 2015
  • Commercial Zr-based amorphous alloy was recycled and oxygen was introduced during the recycling process. The oxygen content can have a great effect on the glass forming ability and the mechanical properties of the alloy. Therefore, it was closely examined. The initial oxygen content in the raw material was 1,244 ppm. It was increased to 3,789 ppm in the alloy after ten recycling processes. As the recycling processes were repeated, the oxygen content increased. Specifically, after four recycling processes, it increased sharply as compared to that after three recycling processes. After ten recycling processes, the glass transition temperature (Tg) increased from 613 K to 634 K and the crystallization temperature (Tx) increased from 696 K to 706 K. On the other hand, the super-cooled liquid region (${\Delta}T=Tx-Tg$) decreased slightly from 83 K to 72 K while the reduced glass transition temperature (Trg = Tg/Tm) was 0.63, remaining constant even when the oxygen content was increased. These results indicated that the increased oxygen content deteriorated the glass forming ability. The bending strength as determined in a three-point bending test showed a sharp decrease from 3,055 to 2,062 MPa as the oxygen content was increased from 1,244 ppm to 3,789 ppm; the extension was also decreased from 3.02 to 1.74 mm. These findings meant that the alloy became brittle.

Zr 기지 비정질 합금 스크랩의 비정질 형성능 및 기계적 성질에 미치는 재용해 횟수와 탄소 함량의 영향 (The Effect of Remelting Cycles and Its Carbon Content on the Glass Forming Ability and Mechanical Properties of the Zr-based Amorphous Alloy Return Scrap)

  • 이병철;김성규;박봉규;박흥일;박화순
    • 한국주조공학회지
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    • 제34권3호
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    • pp.94-99
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    • 2014
  • A commercially used Zr-based amorphous alloy was recycled and the effects of introducing carbon during recycling on the glass forming ability and mechanical properties of the alloy were investigated. The initial carbon content used in this study was 229ppm. The carbon content was gradually increased as the number of recycling iterations was increased and after the $4^{th}$ recycling it rapidly increased. As return scrap was recycled, polygonal particles precipitated, and they were identified as ZrC. The amount of the precipitates also increased with recycling. Tg, Tx and ${\Delta}T$ of the base alloy were 615 K, 696 K and 81 Kr respectively and they changed to 634 K, 706 K and 72 K after the $10^{th}$ recycling. The decrease of the ${\Delta}T$ value indicates deterioration of the glass forming ability. Hardness was not changed during three iterations of recycling but after the $4^{th}$ recycling it significantly increased. This is ascribed to an increase of amount of the hard particles, namely ZrC.

SOFT MAGNETISM OF Co-Zr AND Fe-Co FILMS WITH LARGE SATURATION MAGNETIZATION

  • Suemitsu, Katsumi;Nakagawa, Shigeki;Naoe, Masahiko
    • 한국표면공학회지
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    • 제29권6호
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    • pp.628-633
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    • 1996
  • Large saturation magnetization $4pM_s$ is essentially required for soft magnetic thin layers used in magnetic recording devices. Amorphous Co-based alloys and Fe-Co alloys may be regarded as one of the candidates for soft magnetic materials which possess large $4\piM_s$. Some preparation process to improve soft magnetism of these films were performed in this study. Addition of Ta seemed to be effective to change the magnetostriction constant $\lambda$ from positive value to negative one. The magnetoelastic energy $K_e$ is strongly dependent on $\lambda$. $(Co_{95.7}Zr_{4.3})_{100-x}Ta_x$ films with $K_e$ of negative value have sufficiently soft magnetic characteristics. $Fe_{90}Co_{10}$ alloy exhibits extremely large $4\piM_s$, of about 24 kG. Addition of N and Ta to $Fe_{90}Co_{10}$ films improved the soft magnetism of them. The $Fe_{82.0}Co_{7.6}Ta_{10.4}$:N/Ti multilayered films exhibit better soft magnetic properties and better thermal stability than Fe-Co-Ta:N singlelayer films.

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펄스형 레이저를 비정질 와이어 거대 자기교류저항전류 향상 (Enhanced Giant Magnetoimpedance in Co-based Microwire by Pluse Nd:YAG laser)

  • 이봉상;김철기;김종오;임영우;김란;김기덕;안승준;윤석수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 초전도 자성체
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    • pp.76-78
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    • 2002
  • The influence of laser annealing on gaint magnetoimpedance effect of glass-covered Co-based amorphous microwires is investigated by illuminating pulse Nd:YAG laser on the etched microwires. The maxium GMI ratio reaches maximum of around 85 % at the frequency of 5 MHz for the sample iluminated by the pulse with laser energy fo 132 mJ/pulse.

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비정질 루테늄 산화물을 사용한 수계 Supercapacitor의 전기화학적 특성 (Electrochemical Characteristics of Supercapacitor Based on Amorphous Ruthenium Oxide In Aqueous Acidic Medium)

  • 최상진;도칠훈;문성인;윤문수;육경창;김상길
    • 전기화학회지
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    • 제5권1호
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    • pp.21-26
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    • 2002
  • 비정질 루테늄 산화물을 사용한 수퍼캐패시터를 개발하였다. 삼염화루테늄 수화물$(RuCl_3{\cdot}xH_2O)$로부터 제조한 비정질의 이산화루테늄 수화물$(RuO_2{\cdot}nH_2O)$을 사용하여 수퍼캐패시터 전극을 제조하였다. 집전체로는 티타늄 및 STS 304박막에 비해 보다 넓은 전위창을 가지는 탄탈륨 박막을 사용하였다. 제조한 전극과 4.8M 황산 전해액을 사용하여 수퍼캐패시터를 제조하였다. 전극의 비정전용량은 순환전위전류분석에서 미분 최대 값으로 산화 및 환원 과정 각각 710 및 $645\;F/g-RuO_2{\cdot}nH_2O$이었으며, 평균값은 $521\;F/g-RuO_2{\cdot}nH_2O$으로 나타났다. 수퍼캐패시터를 포화카로멜기준전극에 대하여 0.5 V로 protonation level을 조정하고, 충방전 시험한 바, $151\;F/g-RuO_2{\cdot}nH_2O$의 비정전용량을 나타내었다.

New Process Development for Hybrid Silicon Thin Film Transistor

  • Cho, Sung-Haeng;Choi, Yong-Mo;Jeong, Yu-Gwang;Kim, Hyung-Jun;Yang, Sung-Hoon;Song, Jun-Ho;Jeong, Chang-Oh;Kim, Shi-Yul
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.205-207
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    • 2008
  • The new process for hybrid silicon thin film transistor (TFT) using DPSS laser has been developed for realizing both low-temperature poly-Si (LTPS) TFT and a-Si:H TFT on the same substrate as a backplane of active matrix liquid crystal display. LTPS TFTs are integrated on the peripheral area of the panel for gate driver integrated circuit and a-Si:H TFTs are used as a switching device for pixel in the active area. The technology has been developed based on the current a-Si:H TFT fabrication process without introducing ion-doping and activation process and the field effect mobility of $4{\sim}5\;cm^2/V{\cdot}s$ and $0.5\;cm^2/V{\cdot}s$ for each TFT was obtained. The low power consumption, high reliability, and low photosensitivity are realized compared with amorphous silicon gate driver circuit and are demonstrated on the 14.1 inch WXGA+ ($1440{\times}900$) LCD Panel.

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비정질 CoFeHfO 박막 재료의 마이크로파 투자율 및 감쇠상수 분석 (Analysis of Microwave Permeability and Damping Constant in Amorphous CoFeHfO Thin Film)

  • 김동영;윤석수
    • 한국자기학회지
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    • 제19권4호
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    • pp.147-151
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    • 2009
  • 전도성 저항특성이 우수한 비정질 CoFeHfO재료의 자화곡선 및 토오크 측정으로부터 포화자화량 및 일축이방성상수를 도출하였으며, 이들 결과를 Landau-Lifshitz-Gilbert(LLG) 이론에 적용하여 마이크로파대역의 복소투자율 특성을 분석하였다. LLG 분석 결과 CoFeHfO 박막 재료의 감쇠상수(damping factor)는 ${\alpha}$ = 0.014로 매우 작은 값을 보였다. 이는 CoFeHfO 재료 내에 존재하는 다양한 자성상(magnetic phase)들 중 감쇠상수가 현저히 작은 자성상들에 의하여 유발되었음을 자기장의 세기에 따른 FMR(ferromagnetic resonance) 신호의 선폭 분석을 통하여 알 수 있었다.