• 열처리공학회지
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• 제21권6호
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• pp.307-313
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• 2008

The tensile deformation and shape recovery behaviors were studied in Ni-Ti shape memory wires showing different transformation characteristics by annealing at $200{\sim}600^{\circ}C$. Both R phase ${\rightarrow}$ B19' martensitic transformation at lower temperature and B2 ${\rightarrow}$ R phase transformation at higher temperature occurred in the shape memory wires annealed at $200{\sim}500^{\circ}C$. Transformation temperature and heat flow of B19' martensite increase but those of R phase main almost constant even with increasing annealing temperature. In the case of wires annealed and then cooled to $20^{\circ}C$, plateau on stress-strain curves in tensile testing can be observed due to the collapse of R phase variants and the formation of deformation-induced B19' martensite. In the case of wires annealed and then cooled to $-196^{\circ}C$, however, plateau on stress-strain curves does not appear and stress increases steadily with increasing tensile deformation. Comparing shape recovery rate with cooling temperature after annealing, shape recovery rate of the wire cooled to $20^{\circ}C$ is higher than that of the wire cooled to $-196^{\circ}C$ after annealing, and maximum shape recovery rate of 95% appears in the wire annealed at $400^{\circ}C$ and then cooled to $20^{\circ}C$. $R_s$ and $R_f$ temperatures measured during shape recovery tests are higher than $A_s$ and $A_f$ temperatures measured by DSC tests even at the same annealing temperature.

• 전자공학회논문지A
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• 제28A권12호
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• pp.31-38
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• 1991

The current-voltage characteristics at annealed Be-Cu alloy(1.8-2 wt% Be, 0.2 wt% Co+Ni) interfaces have been studied by means of the cyclic voltammetric method. The specimens were annealed in nitrogen gas($N_{2}$) furnace at 36$0^{\circ}C$ for 1.5 hours. After annealing, the vickers hardness(HV) was increased from 210 to 385. The used solutions were distilled water(H$_{2}$O), 10$^{-3}M\;CsNO_{2},10^{-2}M\;KCl,10^{-2}M\;KOH,10^{-4}M\;H_{2}SO_{4}$ aqueous electrolytes, and ethylalcohol ($C_{2}H_{5}OH$), etc. The cyclic voltammograms showed significant current-voltage characteristics between the annealed and unannealed specimens at the same conditions. The age hardening and the related surface potential barrer and dissolution effects have been observed during the whole experimental process. The dissolution process of annealed Be-Cu alloys was effectively retarded by the age hardening phenomenon. The age hardening effect also raised the surface potential barrier of Be-Cu alloys. The interfacial phenomena of Be-Cu alloys seem to be one of good models for understanding the activation process.

• 대한치과기공학회지
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• 제42권2호
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• pp.129-137
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• 2020

Purpose: The aim of this study is to observe the compressive fracture strength of the crown according to the direction of the occlusal force of the mandibular canine and carnassial of the small dog. Methods: The abutment models of mandibular canine and carnassial were prepared, specimens of zirconia, PMMA and Ni-Cr alloy were produced. The experimental jig was fabricated with Co-Cr alloy and buried in acrylic resin after make tilt to specified angle. The specimen was attached to a jig and loaded using a universal testing machine until the specimen fractured. Results: The compressive fracture strengths of CXZ and CXP specimens were found to be 999.21 ± 31.15 N on average and 731.42 ± 59.13 N on average. And CZZ and CZP specimens were 730.48 ± 70.14 N on average and 377.65 ± 11.87 N on average. CXN and CZN specimens were not fractured. In addition, MZZ and MZP specimens were 746.46 ± 50.75 N and 258.64 ± 31.86 N on average. The MZN specimens were not fractured. Conclusion: Zirconia has compressive fracture strength that can be applied to small dog's canine and Carnassial prosthetics, while PMMA has inadequate strength to small dog's carnassial prosthesis.

• 한국주조공학회지
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• 제34권2호
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• pp.49-53
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• 2014

In commercial Zr-Nb-Cu-Ni-Al amorphous alloys, expensive element, Zr, was substituted to Sn which was cheaper one, and then, glass forming ability, compressive strength and hardness of them were estimated. Even though the Sn was added up to 1.5%, resulting phase was not changed to the crystalline form. It was confirmed by X-ray diffraction and thermal analyses. In the X-ray profiles, there were no peaks for crystalline phases and typical halo pattern for amorphous phase was appeared at the diffraction angle of $35^{\circ}{\sim}45^{\circ}$. Thermal analyses also showed that the Sn modified alloys were corresponded to the amorphous standards where ${\delta}T$(= Tx - Tg) and Trg(= Tg/Tm) affecting to the amorphous forming ability were more than 50K and 0.60 respectively. Compressive strengths were 1.77 GPa, 1.63 GPa, 1.65 GPa and 1.77 GPa for 0%Sn, 0.5%Sn, 1.0%Sn and 1.5%Sn respectively. Hardnesses of the Sn modified alloys were decreased from 752 Hv to 702 Hv in 1.0%Sn and recovered to 746 Hv in 1.5%Sn.

• 한국수소및신에너지학회논문집
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• 제18권2호
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• pp.182-188
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• 2007

[ $Zr_{50}-Ni_{27}-Nb_{18}-Co_5$ ] amorphous alloys ribbon was prepared by a single-roller melt-spinning technique. In order to improve the hydrogen kinetics Pd-coating were carried out on each side of the amorphous ribbon. Pd prevents oxidation of Zr and catalyses the dissociation of molecular hydrogen to atomic hydrogen. In this work, the hydrogen embrittlement and surface properties on Zr-based amorphous alloys were investigated. The Zr-based amorphous alloys were characterized by X-ray diffractometry(XRD) and differential scanning calorimetry(DSC). The morphology of surface and roughness was observed by using scanning electron microscopy(SEM) and atomic force microscopy (AFM). A lattice parameter of both Pd and Zr-based amorphous alloy was increased after hydrogen permeation at 473 K. After hydrogen permeation at 473 K, some cracks were observed on the surface of Pd, which was the cause for the hydrogen embrittlement. The crystallization temperature of Zr-based amorphous alloy was decreased due to the permeated hydrogen.

• 한국주조공학회지
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• 제35권6호
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• pp.170-177
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• 2015

Segregation during solidification and homogenization during thermal exposure in GTD 111 were investigated. The microstructures of as-cast, standard heat-treated, and thermally exposed specimens were observed by SEM. A compositional analysis of each specimen was conducted by EDS. The dendrite core was enriched in W and Co, though lower levels of Ti and Ta were observed. An unexpected phase, in this case like the ${\eta}$ phase, was observed due to segregation near the ${\gamma}-{\gamma}^{\prime}$ eutectic in the standard heat-treated specimen. Segregation also induced microstructural evolution near the ${\gamma}-{\gamma}^{\prime}$ eutectic during the standard heat treatment. A quantitative analysis and microstructural observations showed that the thermal exposure at a high temperature enhanced the chemical homogeneity of the alloy.

• 한국세라믹학회지
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• 제37권4호
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• pp.345-353
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• 2000

Carbon nanofibers were prepared from the decomposition of various carbon-containing gases over pure Ni, pure Fe and their alloys with Cu. They yields, properties, and structure of carbon nanofibers obtained from the various reaction conditions were analyzed. Type of reacting gas, reaction temperature and catalyst composition were changed as the reaction variable. With Ni-Cu catalysts, the maximum yields of carbon nanofibers were obtained at temperatures between 550 and 650$^{\circ}C$ according to the reacting gas mixtures of C2H2-H2, C2H4-H2 and C3H8-H2, and the surface areas of the carbon nanofibers produced were 20∼350㎡/g. In the case of CO-H2 mixture, the rapid deposition of carbon nanofibers occurred with Fe-Cu catalyst and the maximum yield were obtained around 550$^{\circ}C$ with the range of surface areas of 140∼170㎡/g. The electrical resistivity of carbon nanofiber regarded as the key property of filler for the application of electromagnetic interference shielding was very sensitive to the type of reactant gas and the catalyst composition ranging 0.07∼1.5Ωcm at a pressure of 10000 psi, and the resistivity of carbon nanofibers produced over pure nickel catalyst were lower than those over alloy catalysts. SEM observation showed that the carbon nanofibers produced had the diameters ranging 20∼300 nm and the straight structure of carbon nanofibers changed into the twisted or helical conformation by the variation of reacting gas and catalyst composition.

• Journal of Welding and Joining
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• 제32권6호
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• pp.41-46
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• 2014

In this study, cracking susceptibility of laser cladding was investigated according to the processing parameters such as laser power, scan speed and feeding rate with blended powders of stellite#6 and technolase40s (WC+NiCr). The solidification microstructure of clad was composed of Co-based dendrite structures with ${\gamma}+Cr7C3$ eutectic phases at the dendritic boundaries. The crack propagation showed transgranular fracture along dendritic boundaries due to brittle chrome carbide at the eutectic phases. From results of fractography experiments, the fracture surface was typical cleavage brittle fracture in the clad and substrate. The number of clad cracks, caused by a tensile stress after the solidification, increased with increase of laser power, scan speed and feeding rate. Increase of the laser power caused large pores by facilitating WC decarburizing reaction. And the pores affected increase of crack susceptibility. High scan speed caused increment of clad cracks due to thermal stress and WC particle fractures. Also, increase of the feeding rate accompanied an amount of WC particles causing crack initiation and decarburizing reaction.

• 대한치과보철학회지
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• 제30권1호
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• pp.125-132
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• 1992

The purpose of this study was to evaluate the effect of the metal coping design on the fracture resistance of ceramometal crown. The Ni-Cr alloy(Supranium, Krupp Co., German) and Vaccm-fired porcelain powder(Vita VMK 689, Vita Co., Germany) were used in this study. The measurement of fracture resisitance of ceramometal crown was done with Instron Universial Testing Machine(Instro Co., Model no.4201). The obained results were as fellows : 1. The fracture resistance measured at the buccal cusp tip was the highest value in the group that those position of ceramometal junction was 2mm superior to the lingual finshing margin(100.25Kg) and the fracture resistance revealed on order of the group that those position was 2mm buccal to the central groove(51.64Kg). 2. The fracture resistance measured at the central groove was higher value in the group that those position was 2mm lingual to the central groove than in the group that those position was 2mm lingual to the central groove than in the group that those position was 2mm superior to lingual finishing margin(132.48Kg). 3. In all cases, the fracture resistance at the central groove was higher than that at the buccal cusp tip.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2010년도 임시총회 및 하계학술연구발표회
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• pp.148-150
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• 2010

Two-layered ferromagnetic alloy films ($Ni_{80}Fe_{20}$, $Co_{90}Fe_{10}$) with a Conetic intermediate soft magnetic layer of different thickness were investigated to correlate the coercivity values and magnetization process with the strength of the hard saturation field. The interpretation of strong, medium and weak coupling is proposed.