• Economic and Environmental Geology
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• 제21권3호
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• pp.235-255
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• 1988

Talc deposit of pipe-like form occurrs in the lower part of the Hyangsanri Dolomite with a strike of N40 -50 E and a dip of 40 -50 NW which is one formation of the Ogcheon Super Croup. The pipi-like ore body plunge at about $40^{\circ}$ to the west and are parallel to the lineation developed in the area. Structural formulae of tales occurred in this deposit are close to the ieal composition $Mg_6Si_8O_{20}(OH)_4$ showing limited deviation from ideal one. Substitution of Al for Si in tetrahedral site is of little or nothing ranging 0-0.04 and octahedral occupancy is close to six ranging 5.88-5.98 atoms per unit cell. Predominant octahedaral cation is Mg and proportion of divalent cations is generally over 97percent. Calcite -dolomite thermometry is obtained by determining the mol % $MgCO_3$using of EPMA and XRD methods. The peak metamorphic temperature can be estimated at $470{\pm}30^{\circ}C$ in the area whereas carbonates occurred at near talc ore show lower temperature than $400^{\circ}C$ that the calcite solvus limit is not well established. It indicates that the talc deposit was formed at the lower temperature that the metamorphic temperature. Cosequently, the formation of talc by metamorphism is questionable and the alteratin zone developed around the talc ore is very limited. The occurrence of talc ore in the dolomite as well as mineralogy, calcite-dolomite geothermometry, chlorite geothermometry, field and microscopic evidence suggest that siliceous ascending hydrothermal solution along the fracture is responsible for the formation of talc. It was considered that the slight fracturing of dolomite was formed by deformation prior to the mineralization.

• Journal of the Korean Recycled Construction Resources Institute
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• 제7권3호
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• pp.262-270
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• 2019

Ferronickel slag, which is an industrial byproduct, is activated by mechanochemical reaction as a nonferrous metal and can be used as an admixture. Therefore, ferronickel slag is used as a substitute resource of admixture. In this study, to evaluate the effect of mixed of ferronickel slag powder and admixture, a mortar using a mixture of ferronickel slag powder, quicklime, gypsum and calcium chloride was fabricated by vibrated and rolled manufacturing method. Strength were evaluated by flexural and compressive strength tests, and durability was evaluated by performing chlorine ion penetration resistance and chemical resistance test. When the substitution ratio of ferronickel slag powder is constant, it is considered that the mixed use of quicklime, gypsum and calcium chloride as admixtures increases the performance.

• Geomechanics and Engineering
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• 제18권4호
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• pp.353-362
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• 2019

Soil-rock mixture (S-RM) is an inhomogeneous geomaterial that is widely encountered in nature. The mechanical and physical properties of S-RM are important factors contributing towards different deformation characteristics and unstable modes of the talus slope. In this paper, the equivalent substitution method was employed for the preparation of S-RM test samples, and large-scale triaxial laboratory tests were conducted to investigate their mechanical parameters by varying the water content and confining pressure. Additionally, a simplified geological model based on the finite element method was established to compare the stability of talus slopes with different strength parameters and in different excavation and support processes. The results showed that the S-RM samples exhibit slight strain softening and strain hardening under low and high water content, respectively. The water content of S-RM also had an effect on decreasing strength parameters, with the decrease in magnitude of the cohesive force and internal friction angle being mainly influenced by the low and high water content, respectively. The stability of talus slope decreased with a decrease in the cohesion force and internal friction angle, thereby creating a new shallow slip surface. Since the excavation of toe of the slope for road construction can easily cause a landslide, anti-slide piles can be used to effectively improve the slope stability, especially for shallow excavations. But the efficacy of anti-slide piles gradually decreases with increasing water content. This paper can act as a reference for the selection of strength parameters of S-RM and provide an analysis of the instability of the talus slope.

• Journal of Radiopharmaceuticals and Molecular Probes
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• 제8권2호
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• pp.63-70
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• 2022

The development of myocardial perfusion imaging (MPI) agents has been motivated because coronary artery disease has been one of the leading causes of death worldwide since the 1960s. Several positron emission tomography (PET) MPI agents were developed, and ¹⁸F-labeled phosphonium cations were reported actively among them. In this study, we synthesized novel ¹⁸F-labeled phosphonium cations, (5-[¹⁸F]fluoropentyl)diphenyl(pyridin-2-yl)phosphonium and (2-(2-[¹⁸F]fluoroethoxy)ethyl)diphenyl(pyridin-2-yl)phosphonium, and evaluated potential as MPI agents. Two labeled compounds were synthesized via nucleophilic substitution reactions of ¹⁸F-fluoride with the appropriate tosylate precursor in the presence of Kryptofix 2.2.2 and K₂CO₃. MicroPET studies were performed in normal rats to evaluate in vivo distribution of radiolabeled phosphonium cations for 60 min. The radiolabeled compounds were synthesized with 5%-10% yield. The radiochemical purity of labeled compounds was > 98% by analytical HPLC, and the specific activity was > 11.8 GBq/µmol. The result of microPET studies of these labeled compounds in rats showed intense uptake in the myocardium at 30 and 60 min. The results suggest that these ¹⁸F-labeled novel phosphonium cations would have potential as promising candidates for myocardial perfusion imaging.

• Structural Engineering and Mechanics
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• 제87권5호
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• pp.499-516
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• 2023

To defend against harmful gamma radiation, new types of materials for use in the construction of heavyweight concrete (HWC) are still needed to be developed. This research introduces new materials to be employed as a partial replacement for fine aggregate (FA) to manufacture high-performance heavyweight concrete (HPHWC). These materials include hematite, black sand, ilmenite, and magnetite, with substitution ratios of 50% and 100% of FA. In this research, the hardening and fresh characteristics of HPHWC were obtained. Concrete samples' Gamma-ray linear attenuation coefficient was evaluated utilizing a gamma source of Co-60 through the thicknesses of 2.5, 5, 7.5, 10, 12.5, and 15 cm. High temperatures were studied for HPHWC samples, which were exposed to up to 700℃ for two hours. Energy-dispersive x-rays and a scanning electron microscope carried out microstructure analyses. Magnetite as an FA attained the lowest compressive strength of 87.1 MPa, but the best radiation protection characteristics and the highest density of 3100 kg/m³ were achieved. After 28 days, the attenuation efficiency of concrete mixtures was increased by 6.5% when fine sand was replaced with black sand at a ratio of 50%. HPHWC, which contains hematite, black sand, ilmenite, and magnetite, is designed to reduce environmental and health dangers and be used in medicinal, military, and civil applications.

• Journal of Radiopharmaceuticals and Molecular Probes
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• 제6권2호
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• pp.61-68
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• 2020

Aggregated neurofibrillary tangles (NFTs) are a pathological hallmark in Alzheimer's disease (AD) and many radiopharmaceuticals targeting NFTs have been developed so far. Among these, [¹⁸F]flortaucipir (TAUVID^TM) is the first approved radiopharmaceutical in the Food and Drug Administration (FDA) to image tau pathology. In the present study, we describe the optimized radiosynthetic method for the routine production of [¹⁸F] flortaucipir using a commercialized automation module (i.e. GE TRACERlab^TM FX_FN pro). [¹⁸F]Flortaucipir was prepared by nucleophilic substitution from its N-tert-butoxycarbonyl protected nitro precursor, tertbutyl 7-(6-nitropyridin-3-yl)-5H-pyrido[4,3-b]indole-5-carboxylate, at 130℃ for 10 min in dimethyl sulfoxide. The mean radiochemical yield was 20 ± 4.3% (decay-corrected, n = 47) with the molar activity of 218 ± 32 GBq/µmol at the end of synthesis. The radiochemical purity was determined to be above 95%. The overall production time including quality control is approximately 100min. The final produced [¹⁸F]flortaucipir injection meets the USP criteria for quality control. Thus, this fully automated system is validated for clinical use.

• Analytical Science and Technology
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• 제21권2호
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• pp.109-116
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• 2008

Resins were synthesized by mixing 1-aza-18-crown-6 macrocyclic ligand into styrene(dangerous matter) divinylbenzene(DVB) copolymer with crosslink of 1%, 2%, 6% and 12% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, elemental analysis, thermogravimetric analysis, electron microscopy, and IR. The effects of pH, time, crosslink of resins and dielectric constant of solvent on adsorption of uranium ion by resin adsorbent were investigated. Uranium ion showed a great adsorption above pH 3 and adsorption equilibrium of metal ions was established in about two hours. In addition, adsorptive selectivity of resin in ethanol solvent was $UO{_2}^{2+}$ > $Zn^{2+}$ > $Lu^{3+}$ ion and adsorption of uranium ion increased with the increase of the degree of crosslinking (1%~12%) and was inversely in proportional to the order of dielectric constant of solvents.

• Advances in concrete construction
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• 제16권1호
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• pp.35-57
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• 2023

Majority of the plastic produced each year is being disposed in land after single-use, which becomes waste and takes up a lot of storage space. Therefore, there is an urgent need to find alternative solutions instead of disposal. Recycling and reusing the PET plastic waste as aggregate replacement and fiber in concrete production can be one of the eco- friendly methods as there is a great demand for concrete around the world, especially in developing countries by raising human awareness of the environment, the economy, and Carbon dioxide (CO2) emissions. Self-compacting concrete (SCC) is a key development in concrete technology that offers a number of attractive features over traditional concrete applications. Recently, in order to improve its durability and prevent such plastics from directly contacting the environment, various kinds of plastics have been added. This review article summarizes the latest evident on the performance of SCC containing recycled PET as eco-friendly aggregates and fiber. Moreover, it highlights the influence of substitution content, shape, length, and size on the fresh and properties of SCC incorporating PET plastic. Based on the findings of the articles that were reviewed for this study, it is observed that SCC made of PET plastic (PETSCC) can be employed in construction era owing to its acceptable mechanical and fresh properties. On the other hand, it is concluded that owing to the lightweight nature of plastic aggregate, Reusing PET waste in the construction application is an effective approach to reduces the earthquake risk of a building.

• The Korean Journal of Applied Statistics
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• 제37권2호
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• pp.157-176
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• 2024

Integrative analysis for better understanding of complex biological systems gains more attention. Observing subjects from various perspectives and conducting integrative analysis of those multiple datasets enables a deeper understanding of the subject. In this paper, we compared two methods that simultaneously consider two datasets gathered from the same objects, canonical correlation analysis (CCA) and co-inertia analysis (CIA). Since CCA cannot handle the case when the data exhibit high-dimensionality, two strategies were considered instead: Utilization of a ridge constant (CCA-ridge) and substitution of covariance matrices of each data to identity matrix and then applying penalized singular value decomposition (CCA-PMD). To illustrate CIA and CCA, both extensions of CCA and CIA were applied to NCI60 cell line data. It is shown that both methods yield biologically meaningful and significant results by identifying important genes that enhance our comprehension of the data. Their results shows some dissimilarities arisen from the different criteria used to measure the relationship between two sets of data in each method. Additionally, CIA exhibits variations dependent on the weight matrices employed.

• Journal of Electrochemical Science and Technology
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• 제15권1호
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• pp.67-95
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• 2024

Direct alcohol fuel cells (DAFCs) have gained much attention as promising energy conversion devices due to their ability to utilize alcohol as a fuel source. In this regard, Molybdenum-based electrocatalysts (Mo-ECs) have emerged as a substitution for expensive Pt and Ru-based co-catalyst electrode materials in DAFCs, owing to their unique electrochemical properties useful for alcohol oxidation. The catalytic activity of Mo-ECs displays an increase in alcohol oxidation current density by several folds to 1000-2000 mA mg_Pt^-1, compared to commercial Pt and PtRu catalysts of 10-100 mA mg_Pt^-1. In addition, the methanol oxidation peak and onset potential have been significantly reduced by 100-200 mV and 0.5-0.6 V, respectively. The performance of Mo-ECs in both acidic and alkaline media has shown the potential to significantly reduce the Pt loading. This review aims to provide a comprehensive overview of the bifunctional mechanism involved in the oxidation of alcohols and factors affecting the electrocatalytic oxidation of alcohol, such as synthesis method, structural properties, and catalytic support materials. Furthermore, the challenges and prospects of Mo-ECs for DAFCs anode materials are discussed. This in-depth review serves as valuable insight toward enhancing the performance and efficiency of DAFC by employing Mo-ECs.